Citation: LÜ Ling-Zhi, WANG Xiao-Juan, JIANG Xian-Rong, FENG Yun-Long. Three Manganese(Ⅱ) Coordination Polymers Composed of Polynuclear Cluster Blocks and 3, 5-Bis-oxyacetate-benzoic Acid Linkers:Syntheses, Structures and Redox Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2169-2176. doi: 10.11862/CJIC.2017.280 shu

Three Manganese(Ⅱ) Coordination Polymers Composed of Polynuclear Cluster Blocks and 3, 5-Bis-oxyacetate-benzoic Acid Linkers:Syntheses, Structures and Redox Properties

College of Chemistry and Life Sciences, Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long, sky37@zjnu.cn
Received Date: 16 March 2017
Revised Date: 13 October 2017

Figures(10)

Three polynuclear manganese(Ⅱ) coordination polymers(CPs), {(H₃O)[Mn₄(BOABA)₂(OH)₃(H₂O)]·H₂O}_n (1), {(H₃O)₄[Mn₇(BOABA)₄(OH)₆(H₂O)₂]}_n (2) and {(H₃O)₄[Mn₇(BOABA)₄(OH)₄(Cl)₂(H₂O)₂]·2H₂O}_n (3) (H₃BOABA=3, 5-bis-oxyacetate-benzoic acid) have been synthesized under hydrothermal condition and structurally characterized by single crystal X-ray diffraction analyses, XRPD, IR spectra and thermal analyses. CP 1 can be rationalized as a binodal (5, 12)-connected 3D topology network based on tetranuclear[Mn₄(μ₃-OH)₃(COO)₁₀] clusters with point symbol of (3².4⁷.5)₂(3⁸.4²³.5¹⁴.6²¹). CPs 2 and 3 are isostructural and present binodal (3, 12)-connected 2D topology network based respectively on heptanuclear[Mn₇(OH)₆(COO)₁₆] and[Mn₇(OH)₄Cl₂(COO)₁₆] clusters with point symbol of (4³)₄(4³⁰.6²⁴.8¹²). The cyclic voltammograms of the CPs reveal that the processes of the redox are all irreversible.
- coordination polymer,
- 3, 5-bis-oxyacetate-benzoic acid,
- crystal structure,
- redox property
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