Citation: GUO Ning-Ning, WANG Yu, WANG Run-Wei, ZHANG Zong-Tao, QIU Shi-Lun. Synthesis of Sulfur Doped Porous Carbon at Room Temperature for CO₂ Adsorption[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2147-2152. doi: 10.11862/CJIC.2017.272 shu

Synthesis of Sulfur Doped Porous Carbon at Room Temperature for CO₂ Adsorption

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: WANG Run-Wei, rwwang@jlu.edu.cn
Received Date: 24 October 2017
Revised Date: 27 October 2017

Figures(5)

Sulfur doped porous carbon (S-PC) were obtained by direct carbonization of sulfur containing phenolic resins, which were synthesized through one step reaction between phloroglucinol and benzo[b]thiophenc-3-carboxaldehyde under room temperature. The material was characterized by scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and N₂ sorption-desorption experiments. The obtained porous carbons possess high surface area with abundant of micropores. What's more, ultra-high surface area of 997 m²·g^-1 along with ultra-large micropore volume of 0.44 cm³·g^-1 could be obtained after carefully regulation the concentration of reactants. Owing to these fascinating characters like high surface area and rich of micropores, both high CO₂ uptake capacity (5.13 and 3.22 mmol·g^-1 for 273 and 298 K respectively) and high selectivity was obtained, which indicating it's promising sorbents for CO₂.
- sulfur doped porous carbon,
- phenolic resin,
- CO₂ sorption
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Sulfur Doped Porous Carbon at Room Temperature for CO2 Adsorption

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Sulfur Doped Porous Carbon at Room Temperature for CO₂ Adsorption