Citation: CHENG Shu-Yan, KOU Jia-Wei, GAO Zhi-Hua, HUANG Wei. Catalytic Synthesis of Higher Alcohols Form Syngas over Composite Material of CuZnAl/Carbon Fibers[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2233-2240. doi: 10.11862/CJIC.2017.268 shu

Catalytic Synthesis of Higher Alcohols Form Syngas over Composite Material of CuZnAl/Carbon Fibers

1.
Key Laboratory of Coal Science and Technology of Ministry Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China
2.
Department of Environmental Engineering, Shanxi University, Taiyuan 030013, China

Corresponding author: HUANG Wei, huangwei19@126.com
Received Date: 13 May 2017
Revised Date: 11 September 2017

Figures(10)

In this work, CuZnAl hydrotalcite-like compounds were prepared by a co-precipitation method, and the obtained hydrotalcite-like compounds were loaded on the surface of activated carbon fibers (ACFs). The composites consisting of CuZnAl phase and ACFs were prepared by calcination of the hydrotalcite-like compounds with ACFs and then reduction. The composites were characterized by XRD, FTIR and N₂ adsorption-desorption analyses, and catalytic activity of the composites was evaluated for synthesis of higher alcohols form syngas. The results suggest that the active components of the composites are well dispersed on the surface of the ACFs. The particle size of the catalyst decreases and its specific surface area increase with addition of ACFs. The electrical conductivity of ACFs improves electron transfer during alcohol synthesis, which promotes the synthesis reaction and thus increases CO conversion (the highest conversion of 47%). In addition, ACFs enhance dispersity of ZnO and therefore promote formation of metal-oxide interface between Cu and ZnO. This facilities synthesis of higher alcohols, and therefore the selectivity for the alcohols with more than one carbon atoms reached up to 39%.
- higher alcohol,
- syngas,
- CuZnAl catalyst,
- composite
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沈阳化工大学材料科学与工程学院沈阳 110142