Citation: LIU Qing WEI, WEI Zhen-Hong, YU Hui, HAO Yan-Huan, CAI Hu. Syntheses, Characterization and Optical Properties of Three Organic-Inorganic Hybrid Compounds Based on Metal Chlorides and Benzothiazole[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2139-2146. doi: 10.11862/CJIC.2017.258 shu

Syntheses, Characterization and Optical Properties of Three Organic-Inorganic Hybrid Compounds Based on Metal Chlorides and Benzothiazole

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WEI Zhen-Hong, weizh@ncu.edu.cn CAI Hu, caihu@ncu.edu.cn
Received Date: 9 September 2017
Revised Date: 15 October 2017

Figures(5)

The reaction of three divalent metal (Ⅱ) halides MCl₂ (M=Pb²⁺, Cd²⁺, Co²⁺) with two equivalents of benzothiazole (btz) in the concentrated acid HCl at 80 ℃ resulted in the formation of the corresponding organic-inorganic hybrid compounds: (btzH)[(PbCl₃)] (1), (btzH)₂[CdCl₄]·2H₂O (2) and (btzH)₂[CoCl₄]·2H₂O (3), in which the structures of compounds 2 and 3 are similar. All compounds have been characterized by XRD, IR, UV-Vis, EA, TG and single X-ray diffraction. Fluorescent investigation reveals that compounds 1~3 exhibit similar emission peaks at 393 nm, which are ascribed to the π…π transition of the btz ring.
- metal chloride,
- benzothiazole,
- organic-inorganic hybrid,
- crystal structure,
- fluorescent property
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