Citation: LIU Jian, ZHANG Xiao-Peng, LI Cheng-Hui. Syntheses and Ferroelectric Properties of a Couple of Chiral Europium(Ⅲ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2060-2064. doi: 10.11862/CJIC.2017.256 shu

Syntheses and Ferroelectric Properties of a Couple of Chiral Europium(Ⅲ) Complexes

1.
Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Collaborative Innovation Center of Advanced Microstructures, State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
3.
Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China

Corresponding author: LIU Jian, liu.jian@nju.edu.cn
Received Date: 20 September 2017
Revised Date: 16 October 2017

Figures(4)

A couple of pinene-containing europium(Ⅲ) complexes, Eu(TTA)₃L_1a (1a) and Eu(TTA)₃L_1b (1b) (TTA=thenoyltrifluoroacetonate, L_1a=(+)-4, 5-bis(pinene)-2, 2'-bipyridine, L_1b=(-)-4, 5-bis(pinene)-2, 2'-bipyridine), were prepared and characterized. The chiral characterization was confirmed by single crystal X-ray diffraction and distinct electronic circular dichroism (CD) signals. Complex 1a crystallizes in the polar space group P1, and a strongly distorted square-antiprism environment around the Eu(Ⅲ) ion is exhibited. Due to the non-centrosymmetric structure, distinct ferroelectric behavior of complex 1a was observed as expected.
- coordination chemistry,
- chiral europium(Ⅲ) complexes,
- crystal structure,
- ferroelectric properties
1. [1]
  Walton J W, Bourdolle A, Butler S J, et al. Chem. Commun., 2013, 49(16):1600-1602 doi: 10.1039/c2cc35247h
2. [2]
  Kotova O, Kitchen J A, Lincheneau C, et al. Chem. Eur. J., 2013, 19(48):16181-16186 doi: 10.1002/chem.v19.48
3. [3]
  Carr R, Di Bari L, Lo Piano S, et al. Dalton Trans., 2012, 41 (42):13154-13158 doi: 10.1039/c2dt30143a
4. [4]
  Li D P, Li C H, Wang J, et al. Eur. J. Inorg. Chem., 2009 (32):4844-4849
5. [5]
  Bozoklu G, Gateau C, Imbert D, et al. J. Am. Chem. Soc., 2012, 134(20):8372-8375 doi: 10.1021/ja3020814
6. [6]
  Harada T, Tsumatori H, Nishiyama K, et al. Inorg. Chem., 2012, 51(12):6476-6485 doi: 10.1021/ic202467f
7. [7]
  Li X L, Chen C L, Xiao H P, et al. Dalton Trans., 2013, 42 (43):15317-15325 doi: 10.1039/c3dt51743h
8. [8]
  Hang T, Zhang W, Ye H Y, et al. Chem. Soc. Rev., 2011, 40 (7):3577-3598 doi: 10.1039/c0cs00226g
9. [9]
  Li D P, Wang T W, Li C H, et al. Chem. Commun., 2010, 46 (17):2929-2931 doi: 10.1039/b924547b
10. [10]
  Li D P, Zhang X P, Wang T W, et al. Chem. Commun., 2011, 47(24):6867-6869 doi: 10.1039/c1cc11659b
11. [11]
  Liu J, Zhang X P, W T, et al. Inorg. Chem., 2012, 51(16): 8649-8651 doi: 10.1021/ic3012475
12. [12]
  Li X L, Chen K, Liu Y, et al. Angew. Chem. Int. Ed., 2007, 46(36):6820-6823 doi: 10.1002/(ISSN)1521-3773
13. [13]
  Liu J, Wang K, Zheng W, et al. Prog. Photovoltaics Res. Appl., 2013, 21(4):668-675
14. [14]
  SAINT-Plus, Ver. 6. 02, Bruker Analytical X-ray System, Madison, WI, 1999.
15. [15]
  Sheldrick G M. SADABS, an Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
16. [16]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
17. [17]
  Sheldrick G M. Acta Crystallogr. Sect. A: Found. Crystallogr., 2008, 64:112-122 doi: 10.1107/S0108767307043930
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
3. [3]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
6. [6]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
7. [7]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
10. [10]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
11. [11]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
12. [12]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
13. [13]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
14. [14]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
15. [15]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
16. [16]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
17. [17]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
18. [18]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
19. [19]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
20. [20]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(461)
HTML views(64)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142