Citation: QIAN Bin-Bin, ZHAO Meng, CHANG Ze, BU Xian-He. Enhanced CO₂ Sorption Performance of Metal-Organic Frameworks by in-Situ Hydrolysis of Tetrazine Moiety in the Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2051-2059. doi: 10.11862/CJIC.2017.251 shu

Enhanced CO₂ Sorption Performance of Metal-Organic Frameworks by in-Situ Hydrolysis of Tetrazine Moiety in the Ligand

QIAN Bin-Bin ¹ ,
ZHAO Meng ¹ ,
CHANG Ze ^1,, ,
BU Xian-He ^1,2,,

1.
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
2.
College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: CHANG Ze, changze@nankai.edu.cn BU Xian-He, buxh@nankai.edu.cn
Received Date: 22 August 2017
Revised Date: 29 September 2017

Figures(7)

The polar acyl hydrazine groups were introduced into a "pillar-layer" MOF, [Zn₄(bpta)₂(dipytz)₂(H₂O)₂]·4DMF·H₂O (1) (H₄bpta=1, 1'-biphenyl-2, 2', 6, 6'-tetracarboxylic acid and dipytz=di-3, 6-(4-pyridyl)-1, 2, 4, 5-tetrazine), through the in-situ hydrolysis modification of the dipytz pillar ligand, and [Zn₄(bpta)₂(dipytz_hydr)(H₂O)₂]·solvent (2) (dipytz_hydr=1, 2-diisonicotinoylhydrazine) was obtained. The results of gas sorption measurement show that complex 2 has an enhanced CO₂-framework affinity (initial CO₂ adsorption enthalpies increase from 28.8 to 30.3 kJ·mol^-1) and higher CO₂/CH₄ selectivity compared with that of complex 1. The present work indicates that in-situ hydrolysis modification is highly potential for the enhancement of CO₂ adsorption performance of tetrazine functionalized MOFs.
- metal-organic frameworks,
- tetrazine,
- post-synthesis,
- property modulation,
- CO₂ sorption
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced CO2 Sorption Performance of Metal-Organic Frameworks by in-Situ Hydrolysis of Tetrazine Moiety in the Ligand

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通讯作者: 陈斌, bchen63@163.com

Enhanced CO₂ Sorption Performance of Metal-Organic Frameworks by in-Situ Hydrolysis of Tetrazine Moiety in the Ligand