Citation: YU Qi, CHEN Yao, ZHANG Zhen-Jie, CHENG Peng. Recent Progress of Crystalline and Porous Polymer-Metal Coordination Complexes: Synthesis, Characterization and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 1991-2004. doi: 10.11862/CJIC.2017.243 shu

Recent Progress of Crystalline and Porous Polymer-Metal Coordination Complexes: Synthesis, Characterization and Properties

YU Qi ¹ ,
CHEN Yao ^2,3 ,
ZHANG Zhen-Jie ^1,2,, ,
CHENG Peng ^1,,

1.
College of Chemistry, Nankai University, Tianjin 300071, China
2.
State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, China
3.
College of Pharmacy, Nankai University, Tianjin 300071, China

Corresponding author: ZHANG Zhen-Jie, zhangzhenjie@nankai.edu.cn CHENG Peng, pcheng@nankai.edu.cn
Received Date: 7 August 2017
Revised Date: 22 August 2017

Figures(18)

It is always a great challenge to synthesize crystalline and porous polymer materials due to the random configuration and flexibility of polymers. However, polymer-metal coordination complexes (PMCCs) can exhibit high porosity and crystallinity because PMCCs possess not only the properties of polymers such as flexibility and good processability but also the properties of coordination complexes such as high crystallinity and porosity. Herein, this review article summarizes the methods how to construct porous and crystalline PMCCs including photo-induced polymerization method, coordination bond induced self-assembly method, two-step synthesis method and post-synthetic modification method. Finally, we discusse the characterization methods and the potential applications of PMCCs, and list the challenges and chances in the field.
- crystallinity,
- porosity,
- polymer-metal coordination complexes,
- post-synthetic modification,
- self-assembly 0 Introduction
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