Citation: FENG Shang-Fa, HE Xin, QIN Tao, ZHANG Shun-Lin, ZHU Dun-Ru. Four Lanthanide-Organic Frameworks Built from 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2095-2102. doi: 10.11862/CJIC.2017.241 shu

Four Lanthanide-Organic Frameworks Built from 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid

FENG Shang-Fa ¹ ,
HE Xin ¹ ,
QIN Tao ¹ ,
ZHANG Shun-Lin ¹ ,
ZHU Dun-Ru ^1,2,,

1.
College of Chemical Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: ZHU Dun-Ru, zhudr@njtech.edu.cn
Received Date: 6 June 2017
Revised Date: 5 September 2017

Figures(7)

Four lanthanide-organic frameworks (LOFs), [LnL_1.5(DMA)]_n (Ln=Eu (1), Gd (2), Tb (3), Dy (4); H₂L=2, 2'-dinitro-4, 4'-biphenyldicarboxylic acid, DMA=N, N-dimethylacetylamide), have been prepared by the solvo-thermal reaction of H₂L and Ln(NO₃)₃·6H₂O. Their structures have been characterized by elemental analyses, IR, TGA, single-crystal and powder X-ray diffraction (XRD) studies. Crystal structure analyses show that LOFs 1~4 crystallize in the monoclinic system with C2/c space group. LOFs 1~4 are isomorphous and possess a binodal (3, 8)-connected three-dimensional (3D) topology network. All the LOFs exhibit high thermal stabilities (T_d > 322 ℃). Furthermore, 1 displays characteristic luminescence of Eu(Ⅲ) ion while 3 only shows the emission peak of the L^2- ligand.
- lanthanide-organic frameworks,
- 2, 2'-dinitro-4, 4'-biphenyldicarboxylic acid,
- crystal structure,
- luminescence
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