Citation: FENG Shang-Fa, HE Xin, QIN Tao, ZHANG Shun-Lin, ZHU Dun-Ru. Four Lanthanide-Organic Frameworks Built from 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2095-2102. doi: 10.11862/CJIC.2017.241 shu

Four Lanthanide-Organic Frameworks Built from 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid

  • Corresponding author: ZHU Dun-Ru, zhudr@njtech.edu.cn
  • Received Date: 6 June 2017
    Revised Date: 5 September 2017

Figures(7)

  • Four lanthanide-organic frameworks (LOFs), [LnL1.5(DMA)]n (Ln=Eu (1), Gd (2), Tb (3), Dy (4); H2L=2, 2'-dinitro-4, 4'-biphenyldicarboxylic acid, DMA=N, N-dimethylacetylamide), have been prepared by the solvo-thermal reaction of H2L and Ln(NO3)3·6H2O. Their structures have been characterized by elemental analyses, IR, TGA, single-crystal and powder X-ray diffraction (XRD) studies. Crystal structure analyses show that LOFs 1~4 crystallize in the monoclinic system with C2/c space group. LOFs 1~4 are isomorphous and possess a binodal (3, 8)-connected three-dimensional (3D) topology network. All the LOFs exhibit high thermal stabilities (Td > 322 ℃). Furthermore, 1 displays characteristic luminescence of Eu(Ⅲ) ion while 3 only shows the emission peak of the L2- ligand.
  • 加载中
    1. [1]

      (a) Roy S, Chakraborty A, Maji T K. Coord. Chem. Rev., 2014, 273-274:139-164
      (b)Fordham S, Wang X, Bosch M, et al. Struct. Bond., 2015, 163:1-27

    2. [2]

      (a) Zhen M, Tan H, Xie Z, et al. ACS Appl. Mater. Interfaces, 2013, 5:1078-1083
      (b)Li H Y, Xu H, Zang S Q, et al. Chem. Commun., 2016, 52:525-528
      (c)Zhou Y, Yan B. Chem. Commun.., 2016, 52:2265-2268
      (d)Colodrero R M P, Papathanasiou K E, Stavgianoudaki N, et al. Chem. Mater., 2012, 24:3780-3792
      (e)Cui Y, Xu H, Yue Y, et al. J. Am. Chem. Soc., 2012, 134: 3979-3982

    3. [3]

      (a) Cui P P, Zhang X D, Zhao Y, et al. Dalton Trans., 2016, 45:2591-2597
      (b)Lin Z J, Yang Z, Liu T F, et al. Inorg. Chem., 2012, 51: 1813-1820
      (c)He Y P, Tan Y X, Zhang J. Inorg. Chem., 2013, 52:12758-12762
      (d)Li G P, Liu G, Li Y Z, et al. Inorg. Chem., 2016, 55:3952-3959

    4. [4]

      (a) Wang S, Cao T, Yan H, et al. Inorg. Chem., 2016, 55:5139-5151
      (b)Zhao J, He X, Zhang Y, et al. Cryst. Growth Des., 2017, 17:5524-5532
      (c)Seth S, Savitha G, Moorthy J N. J. Mater. Chem. A, 2015, 3:22915-22922
      (d)Han Y H, Tian C B, Lin P, et al. J. Mater. Chem. A, 2015, 3:24525-24531
      (e)Dang S, Ma E, Sun Z M, et al. J. Mater. Chem., 2012, 22: 16920-16926

    5. [5]

      (a) Wang C, Li L, Bell J G, et al. Chem. Mater., 2015, 27:1502-1516
      (b)Jiang H L, Tsumori N, Xu Q. Inorg. Chem., 2010, 49: 10001-10006
      (c)Wang X, Qin T, Bao S S, et al. J. Mater. Chem. A, 2016, 4:16484-16489

    6. [6]

      (a) Tehrani A A, Ghasempour H, Morsali A, et al. Cryst. Growth Des., 2015, 15:5543-5547
      (b)Herbst A, Khutia A, Janiak C. Inorg. Chem., 2014, 53:7319-7333
      (c)Xi F G, Liu H, Yang N N, et al. Inorg. Chem., 2016, 55: 4701-4703

    7. [7]

      (a) Kathalikkattil A C, Roshan R, Tharun J, et al. Chem. Commun., 2016, 52:280-283
      (b)Sartor M, Stein T, Hoffmann F, et al. Chem. Mater., 2016, 28:519-528
      (c)Dong L, Chu W, Zhu Q, et al. Cryst. Growth Des., 2011, 11:93-99

    8. [8]

      (a) Park I H, Lee S S. CrystEngComm, 2011, 13:6520-6525
      (b)Li W X, Zheng Y S, Sun X J, et al. J. Fluoresc., 2010, 20: 235-241

    9. [9]

      (a) Liu Y, Zhang Y, Hu G H, et al. Chem. Eur. J., 2015, 21: 10391-10399
      (b)Bag P P, Wang X S, Cao R. Dalton Trans., 2015, 44:11954-11962
      (c)Tong Y, Han X, Huang C, et al. Dalton Trans., 2016, 45: 3702-3705
      (d)Liu T F, Zhang W, Sun W H, et al. Inorg. Chem., 2011, 50:5242-5248

    10. [10]

      (a) Guo H, Zhu Y, Qiu S, et al. Adv. Mater., 2010, 22:4190-4192
      (b)Li Z, Zhu G, Guo X, et al. Inorg. Chem., 2007, 46:5174-5178
      (c)Tang Q, Liu S, Liu Y, et al. Inorg. Chem., 2013, 52:2799-2801

    11. [11]

      (a) Wei Y, Sa R, Li Q, et al. Dalton Trans., 2015, 44:3067-3074
      (b)Geranmayeh S, Mohammadnezhad F, Abbasi A. J. Inorg. Organomet. Polym., 2016, 26:109-116
      (c)Hao J N, Yan B. J. Mater. Chem. C, 2014, 2:6758-6764

    12. [12]

      (a) Mu W, Huang X, Zhong R, et al. CrystEngComm, 2015, 17:1637-1645
      (b)Han Y F, Zhou X H, Zheng Y X, et al. CrystEngComm, 2008, 10:1237-1242

    13. [13]

      (a) You L, Zong W, Xiong G, et al. Appl. Catal. A, 2016, 511: 1-10
      (b)Liu K, Zhou J M, Li H M, et al. Cryst. Growth Des., 2014, 14:6409-6420
      (c)Lin X M, Ding Y J, Liang S M, et al. CrystEngComm, 2015, 17:3800-3808
      (d)Fang M, Li J J, Shi P F, et al. Dalton Trans., 2013, 42: 6553-6563

    14. [14]

      (a) Wang X Z, Zhu D R, Xu Y, et al. Cryst. Growth Des., 2010, 10:887-894
      (b)Gao T, Wang X Z, Gu H X, et al. CrystEngComm, 2012, 14:5905-5913
      (c)Zhang H J, Wang X Z, Zhu D R, et al. CrystEngComm, 2011, 13:2586-2592
      (d)XU Heng, GONG Jun, MA Jun-Han, et al. Chinese J. Inorg. Chem., 2012, 28(10):2229-2235
      (e)Liu X, Wang X, Gao T, et al. CrystEngComm, 2014, 16: 2779-2787
      (f)Wang X, Zhao J, Zhao Y, et al. Dalton Trans., 2015, 44: 9281-9288

    15. [15]

      (a) Xu H, Bao W, Xu Y, et al. CrystEngComm, 2012, 14:5720-5722
      (b)Luo R, Xu H, Gu H X, et al. CrystEngComm, 2014, 16: 784-796

    16. [16]

      Zhao J, Wang X, Zhao J, et al. CrystEngComm, 2016, 18: 863-867  doi: 10.1039/C5CE02417J

    17. [17]

      Qin T, Gong J, Ma J, et al. Chem. Commun., 2014, 50:15886-15889  doi: 10.1039/C4CC06588C

    18. [18]

      Sheldrick G M. Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, A64:112-122
       

    19. [19]

      Blatov V A. IUCr CompComm Newsletter, 2006, 7:4-38

    20. [20]

      Cui Y, Chen B, Qian G. Coord. Chem. Rev., 2013, 273-274: 76-86
       

    21. [21]

      LI Jia-Jia, SONG Shuang, MA Dou, et al. Chinese J. Inorg. Chem., 2015, 31(4): 717-724
       

  • 加载中
    1. [1]

      Xiaoling LUOPintian ZOUXiaoyan WANGZheng LIUXiangfei KONGQun TANGSheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    2. [2]

      Xiao SANGQi LIUJianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158

    3. [3]

      Jingjing QINGFan HEZhihui LIUShuaipeng HOUYa LIUYifan JIANGMengting TANLifang HEFuxing ZHANGXiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    4. [4]

      Changqing MIAOFengjiao CHENWenyu LIShujie WEIYuqing YAOKeyi WANGNi WANGXiaoyan XINMing FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    5. [5]

      Jing WUPuzhen HUIHuilin ZHENGPingchuan YUANChunfei WANGHui WANGXiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278

    6. [6]

      Xin MAYa SUNNa SUNQian KANGJiajia ZHANGRuitao ZHUXiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    7. [7]

      Yongzhi LIHan ZHANGGangding WANGYanwei SUILei HOUYaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307

    8. [8]

      Yingchun ZHANGYiwei SHIRuijie YANGXin WANGZhiguo SONGMin WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    9. [9]

      Yan Liu Yuexiang Zhu Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

    10. [10]

      Chen LUQinlong HONGHaixia ZHANGJian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407

    11. [11]

      Haitang WANGYanni LINGXiaqing MAYuxin CHENRui ZHANGKeyi WANGYing ZHANGWenmin WANG . Construction, crystal structures, and biological activities of two Ln3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    12. [12]

      Weina Wang Fengyi Liu Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

    13. [13]

      Junqiao Zhuo Xinchen Huang Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100

    14. [14]

      Wenyan Dan Weijie Li Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

    15. [15]

      Xinting XIONGZhiqiang XIONGPanlei XIAOXuliang NIEXiuying SONGXiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    16. [16]

      YanYuan Jia Rong Rong Jie Liu Jing Guo GuoYu Jiang Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035

    17. [17]

      Qin Li Kexin Yang Qinglin Yang Xiangjin Zhu Xiaole Han Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059

    18. [18]

      Zehua Zhang Haitao Yu Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042

    19. [19]

      Tianyun Chen Ruilin Xiao Xinsheng Gu Yunyi Shao Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017

    20. [20]

      Zhaoyang WANGChun YANGYaoyao SongNa HANXiaomeng LIUQinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Metrics
  • PDF Downloads(2)
  • Abstract views(877)
  • HTML views(148)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return