Citation: HU Zhi-Yong, XU Sha-Sha, ZHANG Qiong, LI Sheng-Li, WU Jie-Ying, TIAN Yu-Peng. Second-Harmonic Generation and Two-Photon Activity of MOFs Modified by Organic Cationic Dyes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2017-2023. doi: 10.11862/CJIC.2017.239 shu

Second-Harmonic Generation and Two-Photon Activity of MOFs Modified by Organic Cationic Dyes

1.
Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: TIAN Yu-Peng, yptian@ahu.edu.cn
Received Date: 6 July 2017
Revised Date: 19 August 2017

Figures(10)

Novel composites with nonlinear optical effect were prepared by exchanging the dimethylamine cation with DB and TM in MOFs (ZJU-28) channels. DB or TM cations with strong polar were arranged along one direction in crystal pores, leading to non-central symmetric crystal. Compared to original ZJU-28, the composite crystals, DB@ZJU-28 and TM@ZJU-28, possess strong second harmonic generation (SHG) and two-photon absorption fluorescence observed through confocal microscopy.
- metal organic framework,
- ZJU-28,
- host-guest interactions,
- second-harmonic generation,
- two-photon excitation fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142