Citation: LIU Lu, XU Chun-Ying, LI Ying, WANG Ji-Chao, ZHANG Yu-Ping, WANG Jian-Ji. Two Cd(Ⅱ) Coordination Polymers Based on Flexible Tetracarboxylic Acid Ligands:Crystal Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1817-1824. doi: 10.11862/CJIC.2017.233 shu

Two Cd(Ⅱ) Coordination Polymers Based on Flexible Tetracarboxylic Acid Ligands:Crystal Structures and Fluorescent Properties

LIU Lu ^1,, ,
XU Chun-Ying ² ,
LI Ying ¹ ,
WANG Ji-Chao ¹ ,
ZHANG Yu-Ping ^1,, ,
WANG Jian-Ji ³

1.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
2.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471934, China
3.
Henan Normal University, Xinxiang, Henan 453007, China

Corresponding author: LIU Lu, liululiulu2012@126.com ZHANG Yu-Ping, beijing2008zyp@163.com
Received Date: 19 December 2016
Revised Date: 7 September 2017

Figures(8)

Two coordination polymers, [Cd₂(L)(DMF)_1.5(H₂O)₂]_n (1) and {[Cd(L)_0.5(4, 4'-bpy)(H₂O)]·2H₂O}_n (2), have been designed and synthesized by solvothermal or hydrothermal reactions of 5, 5'-(hexane-1, 6-diyl)-bis(oxy)diisophthalic acid ligand (H₄L) with Cd(Ⅱ) metal ions in the presence/absence of N-donor ligands. The structures of 1~2 have been determined by single-crystal X-ray diffraction analyses and further characterized via infrared spectra (IR), powder X-ray diffraction (PXRD), elemental analyses and thermogravimetric (TG) analyses. Complex 1 features a (4, 4)-connected sql topology net with point symbol of {4⁴·6²}₂. Complex 2 presents a trinodal (4, 4, 4)-connected 3D 3-fold interpenetrating bbf network with a Schläfli symbol of (6⁶)(6⁴·8²). Additionally, complexes 1 and 2 present better thermal stabilities, and show different photoluminescence behaviors in the solid state.
- Cd(Ⅱ),
- crystal structure,
- topology,
- fluorescence
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