Citation: TANG Zheng-Yao, ZHOU Wan-Hai, ZHU Ding, WU Chao-Ling, HUANG Li-Wu, LIU Kun, CHEN Yun-Gui. Effects of Al Content on Low-Temperature and High-Rate Performance of MmNi_4.0-xCo_0.7Mn_0.3Al_x Alloys[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1881-1888. doi: 10.11862/CJIC.2017.228 shu

Effects of Al Content on Low-Temperature and High-Rate Performance of MmNi_4.0-xCo_0.7Mn_0.3Al_x Alloys

1.
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China
2.
Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610065, China

Corresponding author: CHEN Yun-Gui, ygchen60@aliyun.com
Received Date: 26 May 2017
Revised Date: 4 September 2017

Figures(5)

Effects of Al content on the comprehensive electrochemical performance of Ce-rich MmNi_4-xCo_0.7Mn_0.3Al_x (x=0, 0.1, 0.2, 0.3) hydrogen storage alloys, particularly the low-temperature and high-rate capacity have been systematically investigated. At room temperature, both the discharge capacity and cycling stability of the electrode increase with the Al content increases, but the high-rate dischargeability seriously deteriorates. The discharge capacity still increases with the increase of Al content at -20℃, but gradually deteriorates when the temperature drops down to -40℃. Electrochemical kinetics results demonstrate that the high-rate capacity recession of the high-Al alloy at room temperature is contributed to the deterioration of the charge-transfer process. When the temperature drops down to -40℃, Al deteriorates both the surface catalytic ability and the bulk hydrogen diffusion ability, leading to the severe drop of discharge capacity and potential of the high-Al alloy. Based on the comprehensive electrochemical properties of the electrodes, the optimal composition of MmNi_4-xCo_0.7Mn_0.3Al_x is obtained when x=0.2.
1. [1]
  https://en.wikipedia.org/wiki/Hybrid_electric_vehicle
2. [2]
  Young K, Nei J. Materials, 2013, 6:4574-4608 doi: 10.3390/ma6104574
3. [3]
  Kong L, Chen B, Young K, et al. J. Power Sources, 2012, 213:128-139 doi: 10.1016/j.jpowsour.2012.03.099
4. [4]
  Liu Y, Pan H, Gao M, et al. J. Mater. Chem., 2011, 21:4743-4755 doi: 10.1039/C0JM01921F
5. [5]
  Young K, Wong D F, Wang L, et al. J. Power Sources, 2015, 277:426-432 doi: 10.1016/j.jpowsour.2014.10.093
6. [6]
  Sun J, Fan Y, Liu B, et al. J. Alloys Compd., 2015, 641:148-154 doi: 10.1016/j.jallcom.2015.04.058
7. [7]
  Wei X, Liu S, Dong H, et al. Electrochim. Acta, 2007, 52:2423-2428 doi: 10.1016/j.electacta.2006.08.067
8. [8]
  Young K, Ouchi T, Lin X, et al. J. Alloys Compd., 2016, 655:50-59 doi: 10.1016/j.jallcom.2015.09.157
9. [9]
  Li M H, Zhu Y F, Yang C, et al. Int. J. Hydrogen Energy, 2015, 40:13949-13956 doi: 10.1016/j.ijhydene.2015.08.076
10. [10]
  Yao Q, Zhou H, Wang Z, et al. J. Alloys Compd., 2014, 606:81-85 doi: 10.1016/j.jallcom.2014.04.026
11. [11]
  Balogun M S, Wang Z M, Zhang H G, et al. J. Alloys Compd., 2013, 579:438-443 doi: 10.1016/j.jallcom.2013.06.031
12. [12]
  Erbacher J K. J. Power Sources, 1999, 80:265-271
13. [13]
  Ye H, Xia B, Wu W, et al. J. Power Sources, 2002, 111:145-151 doi: 10.1016/S0378-7753(02)00297-5
14. [14]
  Senoh H, Hara Y, Inoue H, et al. Electrochim. Acta, 2001, 46:967-971 doi: 10.1016/S0013-4686(00)00667-8
15. [15]
  陶明大, 陈云贵, 吴朝玲, 等.稀土学报, 2004, 22:882-886
16. [16]
  张晓燕, 陈云贵, 陶明大, 等.稀土学报, 2008, 26:402-405
17. [17]
  Shen X, Chen Y G, Tao M D, et al. Electrochim. Acta, 2009, 54:2581-2587 doi: 10.1016/j.electacta.2008.10.050
18. [18]
  Ma Z W, Zhou W H, Wu C L, et al. J. Alloys Compd., 2016, 660:289-296 doi: 10.1016/j.jallcom.2015.11.078
19. [19]
  Zhou W H, Tang Z Y, Zhu D, et al. J. Alloys Compd., 2016, 692:364-374
20. [20]
  李蓉, 吴建民, 周少雄, 等.稀土学报, 2006, 24:341-345
21. [21]
  Yang H, Chen Y G, Tao M D, et al. Electrochim. Acta, 2010, 55:648-655 doi: 10.1016/j.electacta.2009.09.006
22. [22]
  Young K, Ouchi T, Reichman B, et al. J. Alloys Compd., 2011, 509:3995-4001 doi: 10.1016/j.jallcom.2010.12.205
23. [23]
  Young K, Ouchi T, Reichman B, et al. J. Alloys Compd., 2011, 509:7611-7617 doi: 10.1016/j.jallcom.2011.04.102
24. [24]
  Shen X, Chen Y G, Tao M D, et al. Int. J. Hydrogen Energy, 2009, 34:2661-2669 doi: 10.1016/j.ijhydene.2008.10.079
25. [25]
  Zhou W H, Ma Z W, Wu C L, et al. Int. J. Hydrogen Energy, 2015, 40:10200-10210 doi: 10.1016/j.ijhydene.2015.06.063
26. [26]
  Zhou W H, Ma Z W, Wu C L, et al. Int. J. Hydrogen Energy, 2016, 41:1801-1810 doi: 10.1016/j.ijhydene.2015.10.070
27. [27]
  Yang X G, Liaw B Y. J. Power Sources, 2001, 102:186-197 doi: 10.1016/S0378-7753(01)00809-6
28. [28]
  Bliznakov S, Lefterova E, Dimitrov N, et al. J. Power Sources, 2008, 176:381-386 doi: 10.1016/j.jpowsour.2007.10.028
29. [29]
  Kumar E A, Maiya M P, Murthy S S, et al. J. Alloys Compd., 2009, 470:157-162 doi: 10.1016/j.jallcom.2008.02.096
30. [30]
  Zhou W H, Zhu D, Tang Z Y, et al. J. Power Sources, 2017, 343:11-21 doi: 10.1016/j.jpowsour.2017.01.023
1. [1]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
2. [2]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
3. [3]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
4. [4]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
5. [5]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
6. [6]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
7. [7]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
8. [8]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
9. [9]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
10. [10]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2024.100212
11. [11]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
12. [12]
  Jiqing Liu , Qi Dang , Liting Wang , Dejin Wang , Liang Tang . Applications of flexible electrochemical electrodes in wastewater treatment: A review. Chinese Chemical Letters, 2024, 35(8): 109277-. doi: 10.1016/j.cclet.2023.109277
13. [13]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
14. [14]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
15. [15]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
16. [16]
  Yang Yang , Jing-Li Luo , Xian-Zhu Fu . Water-oxidation intermediates enabling electrochemical propylene epoxidation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100269-100269. doi: 10.1016/j.cjsc.2024.100269
17. [17]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
18. [18]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
19. [19]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
20. [20]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(274)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effects of Al Content on Low-Temperature and High-Rate Performance of MmNi4.0-xCo0.7Mn0.3Alx Alloys

Metrics

通讯作者: 陈斌, bchen63@163.com

Effects of Al Content on Low-Temperature and High-Rate Performance of MmNi_4.0-xCo_0.7Mn_0.3Al_x Alloys