Citation: YUAN Guo-Jun, LIU Guang-Xiang, SHI Chao, SHAO Dong-Sheng. Syntheses and Crystal Structures of Two Homogeneous Organic-Inorganic Compounds Based on PbI₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1855-1860. doi: 10.11862/CJIC.2017.225 shu

Syntheses and Crystal Structures of Two Homogeneous Organic-Inorganic Compounds Based on PbI₂

Department of Applied Chemistry, School of Environmental Science, Nanjing XiaoZhuang University, Nanjing 211171, China

Corresponding author: YUAN Guo-Jun, ahchljygj@163.com
Received Date: 22 April 2017
Revised Date: 2 August 2017

Figures(7)

Two homogeneous compounds, {(4-CH₃-Bz-4-Ph-Py)[PbI₃]}_n (1) (4-CH₃-Bz-4-Ph-Py=4-methylbenzyl-4-phenylpyridinium) and {(4-CF₃-Bz-4-Ph-Py)[PbI₃]}_n (2) (4-CF₃-Bz-4-Ph-Py=4-trifluoromethylbenzyl-4-phenylpyri-dinium), have been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. Compound 1 crystallizes in orthorhombic, space group P2₁2₁2, and compounds 1 and 2 are isostructural. Structure analyses reveal that iodoplumbate ion exhibits octahedron topology in compounds 1 and 2, and all these octahedron topologies form 1D polymeric chain through edge-sharing connecting modes. The organic cation fill in the gap formed by inorganic iodoplumbate polymeric chain.
- lead iodide,
- organic-inorganic hybrid compounds,
- crystal structure
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Syntheses and Crystal Structures of Two Homogeneous Organic-Inorganic Compounds Based on PbI2

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通讯作者: 陈斌, bchen63@163.com

Syntheses and Crystal Structures of Two Homogeneous Organic-Inorganic Compounds Based on PbI₂