Citation: LIU Chao, LI Sha-Sha, YANG Min, BI Rong, YU Qing-Quan, ZHANG Li. Two Mononuclear Ni(Ⅱ) and Cu(Ⅱ) Complexes Containing a Bidentate Schiff Base Ligand:Syntheses, Structures and Antibacterial Activities[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1861-1868. doi: 10.11862/CJIC.2017.220 shu

Two Mononuclear Ni(Ⅱ) and Cu(Ⅱ) Complexes Containing a Bidentate Schiff Base Ligand:Syntheses, Structures and Antibacterial Activities

School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China

Corresponding author: LIU Chao, ahliuchao333@163.com
Received Date: 10 May 2017
Revised Date: 20 July 2017

Figures(4)

The title complexes, Ni(L)₂ (1) and Cu(L)₂ (2) based on HL (HL=N-(3-methylsalicylidene)tryptamine) have been synthesized under solvothermal conditions and characterized structurally by TGA, infrared spectra, elemental analysis and single-crystal X-ray diffraction. Complexes 1 and 2 both crystallize in monoclinic system, and the space groups are P2₁/n with the unit cell parameters for complex 1:a=1.481 6(7) nm, b=1.310 0(6) nm, c=1.668 7(7) nm, β=111.346(7)°, and for complex 2:a=1.479 7(2) nm, b=1.299 41(19) nm, c=1.667 6(2) nm, β=111.537(3)°. Complexes 1 and 2 possess the similar mononuclear structures, which are further extended into infinite 3D supramolecular frameworks by intramolecular C-H…O hydrogen bonds and intermolecular D-H…π hydrogen bonds, respectively. Furthermore, the complexes and the ligand have been investigated for their preliminary antibacterial activities in detail by agar diffusion method, and the results demonstrate that complexes 1 and 2 display more excellent inhibiting effects than the ligand.
- Ni(Ⅱ) complex,
- Cu(Ⅱ) complex,
- crystal structure,
- Schiff base,
- antibacterial activity
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沈阳化工大学材料科学与工程学院沈阳 110142