Citation: LU Ya, LÜ Tian-Xi, HU Wei-Ji, WU Xiao-Yong, ZHAO Guo-Liang. Syntheses, Structures, DNA Interaction of Ag(Ⅰ) and Cd(Ⅱ) Coordination Polymers Based on Biphenyl-2, 4, 4', 6-tetracarboxylic Acid and Imidazo-phenanthrolin-phenoxy Acetic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1869-1875. doi: 10.11862/CJIC.2017.215 shu

Syntheses, Structures, DNA Interaction of Ag(Ⅰ) and Cd(Ⅱ) Coordination Polymers Based on Biphenyl-2, 4, 4', 6-tetracarboxylic Acid and Imidazo-phenanthrolin-phenoxy Acetic Acid

LU Ya ¹ ,
LÜ Tian-Xi ² ,
HU Wei-Ji ² ,
WU Xiao-Yong ² ,
ZHAO Guo-Liang ^1,2,,

1.
Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: ZHAO Guo-Liang, sky53@zjnu.cn
Received Date: 11 May 2017
Revised Date: 19 July 2017

Figures(6)

Two novel coordination polymers[Ag₄(BPTC)]_n (1) and[Cd(PIMPHC)₂]_n (2) were synthesized under hydrothermal reactions by using biphenyl-2, 4, 4', 6-tetracarboxylic acid (H₄BPTC, C₁₆H₁₀O₈) and 2-(4-(1H-imidazo-2-[4, 5-f] [1, 10]phenanthrolinyl)phenoxy) acetic acid (HPIMPHC, C₂₁H₁₄N₄O₃). They were characterized by elemental analysis, IR spectra, TGA, single crystal X-ray diffraction. Complex 1 crystallizes in triclinic system with space group P1, the coordination numbers of Ag(Ⅰ) are four, three and two, forming distorted tetrahedron, flat triangular and V-type coordination geometry. Complex 2 crystallizes in orthorhombic system with space group Pbcn, Each Cd(Ⅱ) is bridged by the PIMPHC^- anions, forming a distorted octahedral coordination geometry. The interaction of complexes, ligands and ct-DNA were studied by EtBr fluorescence probe.
- biphenyl-2, 4, 4', 6-tetracarboxylic acid,
- 2-(4-(1H-imidazo-2-[4, 5-f]-[1, 10]phen-anthrolinyl)phenoxy) acetic acid,
- Ag(Ⅰ),
- Cd(Ⅱ),
- DNA
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