Citation: DENG Qing-Feng, YU Liang-Min, LI Xia. Two Lanthanide Complexes with Maleichydrazide:Syntheses, Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1561-1567. doi: 10.11862/CJIC.2017.210 shu

Two Lanthanide Complexes with Maleichydrazide:Syntheses, Structures and Fluorescence Properties

Key Laboratory of Marie Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao, Shandong 266100, China

Corresponding author: LI Xia, xiali@ouc.edu.cn
Received Date: 24 February 2017
Revised Date: 31 July 2017

Figures(6)

Two lanthanide-organic frameworks[Dy₂(MH)₆]_n·0.5DMF (1) and[Eu₂(MH)₆]_n (2) (MH=maleichydrazide and DMF=N, N-dimethylformamide) have been synthesized and characterized by X-ray single-crystal diffraction and X-ray powder diffraction. Two complexes are both Triclinic P1 space group. Ln(Ⅲ)ions adopt same coordination environments, and seven-coordinated Ln(Ⅲ)atom form feature isostructural 3D structures, topological type:tsi. The luminescence properties of 1 and 2 were investigated. Under the excitation of 375 nm, the emission spectrum of complex 2 shows five peaks at 581, 593, 616, 652 and 705 nm, corresponding to ⁵D₀→⁷F_J (J=0~4) transitions of Eu³⁺. The emission spectrum of complex 1 shows a peak at 618 nm, which plausibly arises from π^*-π transition of ligands.CCDC: 1473814, 1; 1473816, 2.
- lanthanide complex,
- fluorescence,
- coordination,
- maleichydrazide
1. [1]
  Li B, Chen B. Porous Lanthanide Metal Organic Frameworksfor Gas Storage and Separation. Berlin, Heidelberg:Springer, 2014:75-107
2. [2]
  Roy S, Chakraborty A, Maji T K. Coord. Chem. Rev., 2014, 273:139-164
3. [3]
  Pagis C, Ferbinteanu M, Rothenberg G, et al. ACS Catal., 2016, 6(9):6063-6072 doi: 10.1021/acscatal.6b01935
4. [4]
  You L, Zhu W, Wang S, et al. Polyhedron, 2016, 115:47-53 doi: 10.1016/j.poly.2016.04.032
5. [5]
  Russell S, Loiseau T, Volkringer C, et al. Inorganics, 2015, 3(4):467-481 doi: 10.3390/inorganics3040467
6. [6]
  D'Vries R F, Snejko N, Iglesias M, et al. Cryst. Growth Des., 2014, 14(5):2516-2521 doi: 10.1021/cg5002336
7. [7]
  Wu J X, Yan B. Inorg. Chem. Commun., 2016, 70:189-192 doi: 10.1016/j.inoche.2016.06.021
8. [8]
  Zhou J, Li H, Zhang H, et al. Adv. Mater., 2015, 27(44):7072-7077 doi: 10.1002/adma.201502760
9. [9]
  Hu Z, Deibert B J, Li J. Chem. Soc. Rev., 2014, 43(16):5815-5840 doi: 10.1039/C4CS00010B
10. [10]
  Biswas S, Mondal A K, Konar S. Inorg. Chem., 2016, 55(5):2085-2090 doi: 10.1021/acs.inorgchem.5b02486
11. [11]
  Zhang F, Zou X, Yan P, et al. Cryst. Growth Des., 2015, 15(3):1249-1258 doi: 10.1021/cg501644z
12. [12]
  Zou J Y, Shi W, Xu N, et al. Eur. J. Inorg. Chem., 2014(2):407-412
13. [13]
  DONG Piao-Ping, XIE Xin-Rong, LIANGFu-Yong, et al. Chin. J. Nonferrous Met. Sci. Eng., 2016, 7(3):137-150
14. [14]
  Han Y, Li X, Li L, et al. Inorg. Chem., 2010, 49(23):10781-10787 doi: 10.1021/ic902194g
15. [15]
  Zhang H, Li N, Tian C, et al. Cryst. Growth Des., 2012, 12(2):670-678 doi: 10.1021/cg2008655
16. [16]
  Binnemans K. Chem. Rev., 2009, 109(9):4283-4374 doi: 10.1021/cr8003983
17. [17]
  FAN Ting-Ting, QU Xiang-Long, LI Jia-Jia, et al. Chinese J. Inorg. Chem., 2016, 32(11):1911-1918
18. [18]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
19. [19]
  Sheldrick G M. SHELXS-97, Program for the Solution ofCrystal Structures, University of Göttingen, Germany, 1997.
20. [20]
  Sheldrick G M. SHELXL-97, Program for the Refinement ofCrystal Structures, University of Göttingen, Germany, 1997.
21. [21]
  Li J Y, Yan Z, Ni Z P, et al. Inorg. Chem., 2014, 53(8):4039-4046 doi: 10.1021/ic403069d
22. [22]
  LI Yun-Feng, WANG Chun-Yan, LI Xia. Chinese J. Inorg. Chem., 2008, 24(8):1311-1315
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