Citation: PAN Zhao-Rui, ZHENG He-Gen. Syntheses, Crystal Structures and Properties of 2-(5-Methyl-1, 3, 4-thiadiazol-2-ylthio Zinc(Ⅱ)Coordination Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1678-1684. doi: 10.11862/CJIC.2017.207 shu

Syntheses, Crystal Structures and Properties of 2-(5-Methyl-1, 3, 4-thiadiazol-2-ylthio Zinc(Ⅱ)Coordination Compounds

PAN Zhao-Rui ^1,2,, ,
ZHENG He-Gen ^1,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: PAN Zhao-Rui, pzr_2006@163.com ZHENG He-Gen, zhenghg@nju.edu.cn
Received Date: 11 May 2017
Revised Date: 19 June 2017

Figures(9)

Two coordination compounds[Zn(mtyaa)₂(H₂O)₄]·4H₂O (1) and[Zn(bpe)(mtyaa)₂(H₂O)₂]_n (2) (Hmtyaa=2-(5-methyl-1, 3, 4-thiadiazol-2-ylthio) acetic acid, bpe=1, 2-bis(4-pridyl)ethane) have been synthesized and they were structurally characterized by single-crystal X-ray diffraction, and then were characterized by elemental analysis, FTIR spectra, thermal analysis and powder X-ray diffraction. Compounds 1 and 2 crystallize in the triclinic and monoclinic, space group P1 and C2/c, respectively. Face-to-face π-π interactions and hydrogen bonds between coordinated and free water molecules with carboxylate oxygen atoms connect single molecules in compound 1 into three dimensional network. Compound 2 is connected into three dimensional structure by hydrogen bonds between coordinated water molecules and carboxylate oxygen atoms or nitrogen atoms.CCDC:653462,1;653467,2.
- 2-(5-methyl-1, 3, 4-thiadiazol-2-ylthio) acetic acid,
- crystal structure,
- π-π interaction,
- hydrogen bonds
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