Citation: WANG Ying, LIN Xiao-Meng, BAI Feng-Ying, ZHANG Rui, ZHANG Xiao-Xi. Syntheses, Structures and Biomimetic Catalytic Bromination of Copper-Triflusal Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1667-1677. doi: 10.11862/CJIC.2017.202 shu

Syntheses, Structures and Biomimetic Catalytic Bromination of Copper-Triflusal Complexes

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: BAI Feng-Ying, baifengying2000@163.com
Received Date: 19 April 2017
Revised Date: 14 July 2017

Figures(9)

A series of 2-hydroxy-4-trifluoromethylbenzoic acid(h₂tba)-copper complexes:[Cu(htba)₂(pz)₂] (1), [Cu(htba)(2, 2'-bipy)](htba) (2) and[Cu(htba)₂(4, 4'-bipy)] (3) (h₂tba=2-hydroxy-4-trifluoromethylbenzoic acid, pz=pyrazole, 2, 2'-bipy=2, 2'-bipyridine, 4, 4'-bipy=4, 4'-bipyridine) have been synthesized and characterized by elemental analysis, IR spectra, UV-Vis, spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermal gravimetric analysis (TG). The complexes which catalyzed phenol red bromination in the presence of H₂O₂ and bromide, exhibited high catalytic bromination activity.CCDC:1041787,1;1041788,2;1041789,3.
- copper complexes,
- triflusal,
- crystal structure,
- catalytic bromination
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