Citation: LI Zhi-Hua, WANG Yu-Xia, QIU Dan, LI Zai-Jun, GU Zhi-Guo. AAO Assisted 1D Confined Assembly and 2D Surface Filming of Iron(Ⅱ) Triazole Nanomaterial and Spin-Crossover Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2311-2321. doi: 10.11862/CJIC.2017.200 shu

AAO Assisted 1D Confined Assembly and 2D Surface Filming of Iron(Ⅱ) Triazole Nanomaterial and Spin-Crossover Properties

LI Zhi-Hua ¹ ,
WANG Yu-Xia ¹ ,
QIU Dan ¹ ,
LI Zai-Jun ¹ ,
GU Zhi-Guo ^1,2,,

1.
School of Chemistry and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 28 May 2017
Revised Date: 16 July 2017

Figures(7)

Iron(Ⅱ) triazole (SCO1) and iron(Ⅱ) 4-amino-triazole (SCO2) spin-crossover (SCO) nanomaterials were assembled in the channel and on the surface of anodic aluminum oxide (AAO) templates simultaneously by a facile sequential multistep assembly method. The obtained SCO1-1D+2D and SCO2-1D+2D nanomaterials have been characterized by SEM, FT-IR, PXRD, and Raman spectra. SEM images show that spherical SCO NPs growing in the channel of AAO templates aggregate with time going on, and assemble as 1D nanostructure. While those growing on the surface of AAO substrates assemble as uniform and dense 2D SCO film. It is interesting that both SCO-1D+2D nanostructures present a special two-step spin-crossover behaviour with hysteresis loops (SCO1-1D+2D:T_c1↑=319 K, T_c1↓=313 K, T_c2↑=381 K, T_c2↓=340 K; SCO2-1D+2D:T_c1↑=181 K, T_c1↓=155 K, T_c2↑=246 K, T_c2↓=233 K). The magnetic measuring of SCO-1D and SCO-2D indicates that the two-step SCO behaviour results from the different assembly morphologies of SCO. The first step spin transition at lower temperature is ascribed to the properties of 2D SCO films growing on the surface of AAO templates, while the transition in the second step at higher temperature can be attributed to the 1D SCO confined assembly growing in the channel of AAO membranes.
- nanomaterials,
- anodic aluminum oxide (AAO) templates,
- self-assembly,
- two-step spin-crossover behavior
1. [1]
  (a) Brooker S. Chem. Soc. Rev. , 2015, 44: 2880-2892
  (b)Quintero C M, Félix G, Suleimanov I, et al. Beilstein J. Nanotechnol. , 2014, 5: 2230-2239
  (c)Bousseksou A, Molnár G, Salmon L, et al. Chem. Soc. Rev., 2011, 40: 3313-3335
  (d)Gütlich P, Gaspar A B, Garcia Y. Beilstein J. Org. Chem. , 2013, 9: 342-391
  (e)Gütlich P, Goodwin H A. Top. Curr. Chem. , 2004, 233: 1-47
2. [2]
  (a) Mikolasek M, Félix G, Nicolazzi W, et al. New J. Chem., 2014, 38: 1834-1839
  (b)Nagy V, Suleimanov I, Molnár G, et al. J. Mater. Chem. C, 2015, 3: 7897-7905
  (c)Giménez-Marqués M, de Larrea M L G S, Coronado E. J. Mater. Chem. C, 2015, 3: 7946-7953
  (d)Bartual-Murgui C, Natividad E, Roubeau O. J. Mater. Chem. C, 2015, 3: 7916-7924
  (e)Lapresta-Fernández A, Cuéllar M P, Herrera J M, et al. J. Mater. Chem. C, 2014, 2: 7292-7303
  (f)WANG Yu-Xia(王玉侠), QIU Dan(邱丹), XI Sai-Fei(奚赛飞), et al. Chinese J. Inorg. Chem. (无机化学学报), 2016, 32(11): 1965-1972b
3. [3]
  (a) Linares J, Codjovi E, Garcia Y. Sensors, 2012, 12: 4479-4492
  (b)Kahn O, Martinez C J. Science, 1998, 279: 44-48
  (c)Rotaru A, Dugay J, Tan R P, et al. Adv. Mater. , 2013, 25: 1745-1749
  (d)Hayami S, Holmes S M, Halcrow M A. J. Mater. Chem. C, 2015, 3: 7775-7778
  (e)Bartual-Murgui C, Akou A, Thibault C, et al. J. Mater. Chem. C, 2015, 3: 1277-1285
  (f)Molnár G, Salmon L, Nicolazzi W, et al. J. Mater. Chem. C, 2014, 2: 1360-1366
4. [4]
  (a) Martinho P N, Rajnak C, Ruben M. Spin-Crossover Mater. , 2013: 375-404
  (b)Cavallini M. Phys. Chem. Chem. Phys., 2012, 14: 11867-11876
5. [5]
  (a) Thomas L, Hayashi M, Jiang X, et al. Science, 2007, 315: 1553-1556 (b)Woltersdorf G, Back C H. Phys. Rev. Lett., 2007, 99: 227207
6. [6]
  (a) Ebels U, Radulescu A, Henry Y, et al. Phys. Rev. Lett. , 2000, 84: 983-986
  (b)Guo L M, Wang X H, Zhong C F, et al. J. Appl. Phys., 2012, 111: 026104
  (c)Reddy S M, Park J J, Na S M, et al. Adv. Funct. Mater. , 2011, 21: 4677-4683 (d)Liu M, Lagdani J, Imrane H, et al. Appl. Phys. Lett. , 2007, 90: 103105
7. [7]
  Martinho P N, Lemma T, Gildea B, et al. Angew. Chem. Int. Ed., 2012, 51:11995-11999 doi: 10.1002/anie.201205122
8. [8]
  (a) Soyer H, Mingotaud C, Boillot M L, et al. Langmuir, 1998, 14: 5890-5895
  (b)Soyer H, Dupart E, Gómez-García C J, et al. Adv. Mater., 1999, 11: 382-384
  (c)Létard J F, Nguyen O, Soyer H, et al. Inorg. Chem., 1999, 38: 3020-3021
  (d)Roubeau O, Agricole B, Clérac, et al. J. Phys. Chem. B, 2004, 108: 15110-15116
  (e)Roubeau O, Natividad E, Agricole B, et al. Langmuir, 2007, 23: 3110-3117
  (f)White N G, Feltham H L C, Gandolfi C, et al. Dalton Trans. , 2010, 39: 3751-3758
  (g)Kitchen J A, White N G, Gandolfi C, et al. Chem. Commun. , 2010, 46: 6464-6466
9. [9]
  (a) Ruben M, Rojo J, Romero-Salguero F J, et al. Angew. Chem. Int. Ed. , 2004, 43: 3644-3662
  (b)Cobo S, Molnár G, Real J A, et al. Angew. Chem. Int. Ed., 2006, 45: 5786-5789
10. [10]
  (a) Jenekhe S A. Polym. Eng. Sci. , 1983, 23: 830-834
  (b)Matsuda M, Tajima H. Chem. Lett., 2007, 36: 700-701
  (c)Matsuda M, Isozaki H, Tajima H. Thin Solid Films, 2008, 517: 1465-1467
  (d)Quintero C M, Salmon L, Molnár G, et al. J. Mater. Chem. , 2012, 22: 3745-3751
  (e)Félix G, Abdul-Kader K, Mahfoud T, et al. J. Am. Chem. Soc. , 2011, 133: 15342-15345
  (f)Tissot A, Bardeau J F, Rivière E, et al. Dalton Trans., 2010, 39: 7806-7812
11. [11]
  (a) Deegan R D, Bakajin O, Dupont T F, et al. Nature, 1997, 389: 827-829
  (b)Galyametdinov Y, Ksenofontov V, Prosvirin A, et al. Angew. Chem. Int. Ed., 2001, 40: 4269-4271
12. [12]
  (a) Agusti G, Cobo S, Gaspar A B, et al. Chem. Mater., 2008, 20: 6721-6732
  (b)Bartual-Murgui C, Salmon L, Akou A, et al. New J. Chem., 2011, 35: 2089-2094
13. [13]
  (a) Witte G, Wll C. J. Mater. Res. , 2004, 19: 1889-1916
  (b)Naggert H, Bannwarth A, Chemnitz S, et al. Dalton Trans. , 2011, 40: 6364-6366
  (c)Shi S, Schmerber G, Arabski J, et al. Appl. Phys. Lett. , 2009, 95: 043303
14. [14]
  (a) Lai P, Hu M Z, Shi D, et al. Chem. Commun. , 2008: 1338-1340
  (b)Wang Y, Qin Y, Berger A, et al. Adv. Mater. , 2009, 21: 2763-2766
  (c)Wang K, Jin S M, Xu J, et al. ACS Nano, 2016, 10: 4954-4960
15. [15]
  (a) Terekhov S N, Kachan S M, Panarin A Y, et al. Phys. Chem. Chem. Phys., 2015, 17: 31780-31789
  (b)Fang Z, Wang Y, Peng X, et al. Mater. Lett. , 2003, 57: 4187-4190
  (c)Cui M, Wang F, Miao Z, et al. RSC Adv., 2015, 5: 65627-65634
16. [16]
  (a) Roubeau O. Chem. Eur. J., 2012, 18: 15230-15244
  (b)Sugiyarto K H, Goodwin H A. Aust. J. Chem., 1994, 47: 263-277
17. [17]
  (a) Krober J, Codjovi E, Kahn O, et al. J. Am. Chem. Soc., 1993, 115: 9810-9811
  (b)Smit E, Manoun B, Waal D. J. Raman Spectrosc., 2001, 32: 339-344
  (c)Varnek V A, Lavrenova L G. J. Struct. Chem. , 1995, 36: 104-111
  (d)Chen Y, Ma J G, Zhang J J, et al. Chem. Commun., 2010, 46: 5073-5075
  (e)Kahn O, Sommier L, Codjovi E. Chem. Mater., 1997, 9: 3199-3205
18. [18]
  He M, Yao J, Low Z X, et al. RSC Adv., 2014, 4:7634-7639 doi: 10.1039/c3ra46806b
19. [19]
  Durand P, Pillet S, Bendeif E E, et al. J. Mater. Chem. C, 2013, 1:1933-1942 doi: 10.1039/c3tc00546a
20. [20]
  (a) Hetmańczyk J, Hetmańczykń, Migda-Mikuli A, et al. J. Raman Spectrosc., 2012, 43: 1118-1125
  (b)Abdollahi-Alibeik M, Sadeghi-Vasafi N, Moaddeli A, et al. Res. Chem. Intermed., 2016, 42: 2867-2881
21. [21]
  (a) Urakawa A, Van Beek W, Monrabal-Capilla M, et al. J. Phys. Chem. C, 2010, 115: 1323-1329
  (b)Grosjean A, Négrier P, Bordet P, et al. Eur. J. Inorg. Chem., 2013, 2013: 796-802
22. [22]
  Chen Y, Ma J G, Zhang J J, et al. Chem. Commun., 2010, 46:5073-5075 doi: 10.1039/b927191k
23. [23]
  Lefter C, Tricard S, Peng H, et al. J. Phys. Chem. C, 2015, 119:8522-8529 doi: 10.1021/acs.jpcc.5b01117
24. [24]
  (a) Qiu D, Gu L, Sun X L, et al. RSC Adv., 2014, 4: 61313-61319
  (b)Moussa N O, Ostrovskii D, Garcia V M, et al. Chem. Phys. Lett., 2009, 477: 156-159
25. [25]
  (a) Rotaru A, Molnár G, Salmon L, et al. Chem. Commun., 2012, 48: 4163-4165
  (b)Larionova J, Salmon L, Guari Y, et al. Angew. Chem. Int. Ed. , 2008, 120: 8360-8364
  (c)Gütlich P, Hauser A, Spiering H. Angew. Chem. Int. Ed. , 1994, 33: 2024-2054
26. [26]
  Wang Y X, Qiu D, Xi S F, et al. Chem. Commun., 2016, 52:8034-8037 doi: 10.1039/C6CC02334G
1. [1]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
2. [2]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
3. [3]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
4. [4]
  Yi Zhou , Wei Zhang , Rong Fu , Jiaxin Dong , Yuxuan Liu , Zihang Song , Han Han , Kang Cai . Self-assembly of two pairs of homochiral M₂L₄ coordination capsules with varied confined space using Tröger's base ligands. Chinese Chemical Letters, 2025, 36(2): 109865-. doi: 10.1016/j.cclet.2024.109865
5. [5]
  Xiaoyu YANG , Yejun ZHANG , Yu ZOU , Hongchao YANG , Jiang JIANG , Qiangbin WANG . Research progress of inorganic X-ray nanoscintillators. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 1929-1952. doi: 10.11862/CJIC.20250122
6. [6]
  Kun JIANG , Yutong XUE , Kelin LIU , Miao WANG , Tongming SUN , Yanfeng TANG . CeVO₄ hollow microspheres: Fabrication and adsorption performance for dyes. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2229-2236. doi: 10.11862/CJIC.20250223
7. [7]
  Fadeng Yang , Pengli Zhang , Jianbo Liu , Chuan Wan , Jinming Sun , Chuan Dai , Zhihong Liu , Yuhao An , Yujie Wu , Yun Xing , Feng Yin , Yuxin Ye , Wei Han , Zigang Li . Self-assembly of a cyclo-pentapeptide with a novel frame structure. Chinese Chemical Letters, 2025, 36(9): 110785-. doi: 10.1016/j.cclet.2024.110785
8. [8]
  Jing Guo , Jianzhong Ma , Junli Liu , Guanjie Huang , Xiaoting Zhou , Francesco Parrino , Riccardo Ceccato , Leonardo Palmisano , Boon-Junn Ng , Lutfi Kurnianditia Putri , Huaxing Li , Rongjie Li , Gang Liu , Yang Wang , Nikolay Kornienko , Shan-Shan Zhu , Zhenwei Zhang , Xiaoming Liu , Nur Atika Nikma Dahlan , Siang-Piao Chai , Jianmin Ma . Two-dimensional nanomaterials for environmental catalysis roadmap towards 2030. Chinese Chemical Letters, 2025, 36(9): 110988-. doi: 10.1016/j.cclet.2025.110988
9. [9]
  Changxing Yang , Guxia Wang , Shengwei Guo , Jianlin Sun . Potential and progress of two-dimensional nanomaterials in oil-based lubrication. Chinese Chemical Letters, 2025, 36(9): 111178-. doi: 10.1016/j.cclet.2025.111178
10. [10]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
11. [11]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
12. [12]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
13. [13]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
14. [14]
  Hao Zhang , Hao Liu , Ke Huang , Qingxiu Xia , Hongjie Xiong , Xiaohui Liu , Hui Jiang , Xuemei Wang . Ionic exchange based intracellular self-assembly of pitaya-structured nanoparticles for tumor imaging. Chinese Chemical Letters, 2025, 36(6): 110281-. doi: 10.1016/j.cclet.2024.110281
15. [15]
  Ming-Ming Gan , Zi-En Zhang , Xin Li , F. Ekkehardt Hahn , Ying-Feng Han . Hierarchical self-assembly of fluorinated poly-N-heterocyclic carbene pillarplexes with anions. Chinese Chemical Letters, 2025, 36(10): 110624-. doi: 10.1016/j.cclet.2024.110624
16. [16]
  Ying Zhao , Yao He , Jian-Xin Yang , Wen-Jie Liu , Dan Tian , Francisco Aznarez , Le-Le Gong , Li-Long Dang , Lu-Fang Ma . Controllable self-assembly and photothermal conversion of metalla[2]catenanes induced by synergistic effect of free radicals and stacking interactions. Chinese Chemical Letters, 2025, 36(12): 111460-. doi: 10.1016/j.cclet.2025.111460
17. [17]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
18. [18]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
19. [19]
  Hanhan Chen , Yahao Sun , Mingyang Zhang , Pengtao Ma , Jingping Wang , Jingyang Niu . Self-assembly of cis-trans Ta/W mixed-addendum POMs based on hexalacunary [H₂P₂W₁₂O₄₈]¹²⁻ building blocks. Chinese Chemical Letters, 2025, 36(9): 110329-. doi: 10.1016/j.cclet.2024.110329
20. [20]
  Yimin Guo , Yiting Luo , Shuwen Hua , Chuan-Fan Ding , Yinghua Yan . Application of magnetic nanomaterials in peptidomics: A review in the past decade. Chinese Chemical Letters, 2025, 36(6): 110070-. doi: 10.1016/j.cclet.2024.110070

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(564)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142