Citation: MA Feng-Yan, Yang YANG, LI Na, YANG Qi-Lin, LI Shang-Jin, SHEN Lu-Yan. Comparison of Photocatalytic Activity of Bi₂WO₆/TiO₂ Nanotubes Heterostructures Composite under Multimode[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1656-1666. doi: 10.11862/CJIC.2017.199 shu

Comparison of Photocatalytic Activity of Bi₂WO₆/TiO₂ Nanotubes Heterostructures Composite under Multimode

MA Feng-Yan ^1,, ,
Yang YANG ¹ ,
LI Na ¹ ,
YANG Qi-Lin ¹ ,
LI Shang-Jin ² ,
SHEN Lu-Yan ²

1.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China
2.
College of Materials Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: MA Feng-Yan, mafengyan989@163.com
Received Date: 18 April 2017
Revised Date: 18 July 2017

Figures(9)

Bi₂WO₆/TiO₂ nanotubes (Bi₂WO₆/TiO₂-NTs) heterostructures composite were synthesized by multicom-ponent assembly approach combined with hydrothermal treatment employed TiO₂ nanotubes as template. Multiple techniques such as X-ray powder diffraction (XRD), X-ray photo-electron spectroscopy (XPS), N₂ adsorption-desorption, scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and UV-Vis diffused absorption spectra (UV-Vis DRS) were applied to investigate the composition, structures, morphologies, optical and electronic properties of as-prepared samples. The heterostructures were formed with Bi₂WO₆ nanoflakes or nanoparticles attached on the surface of TiO₂ nanotubes. The photocatalytic activity of Bi₂WO₆/TiO₂-NTs heterostructures was evaluated sufficiently by photodegradation of rhodamine B (RhB) under multimode including UV, visible and microwave-assisted photocatalysis. Compared to TiO₂ nanotubes and Bi₂WO₆, Bi₂WO₆/TiO₂-NTs-35 shows the highest photocatalytic activity under multimode. In contrast with UV, visible mode, the Bi₂WO₆/TiO₂-NTs-35 shows the highest activity toward RhB degradation under microwave-assisted photocatalytic mode. This enhanced photocatalytic activity is due to the more efficient separation of the e^--h⁺ pairs, originating from the introduction of Bi₂WO₆ modified TiO₂-NTs, the nanotubular geometries, and degradation mode. The main active species of the degradation process are proven to be h⁺, ·OH, and ·O₂^- radicals. Moreover, more ·OH and ·O₂^- radicals were generated under microwave-assisted photocatalytic mode.
- TiO₂ nanotubes,
- Bi₂WO₆,
- multimode degradation,
- photocatalysis
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Comparison of Photocatalytic Activity of Bi₂WO₆/TiO₂ Nanotubes Heterostructures Composite under Multimode