Citation: WU Qi, SU Zhi, WANG Hong-Yan, DONG Yi-Li, HU Jiong-Sheng, LIU Dong-Ju, WU Chang, XU Yun, YING Ao, FANG Min, LIU Hong-Ke. Syntheses, Crystal Structures and Fluorescence of Cadmium(Ⅱ) and Zinc(Ⅱ) Complexes Based on Flexible Tripodal Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1889-1895. doi: 10.11862/CJIC.2017.196 shu

Syntheses, Crystal Structures and Fluorescence of Cadmium(Ⅱ) and Zinc(Ⅱ) Complexes Based on Flexible Tripodal Ligands

WU Qi ¹ ,
SU Zhi ¹ ,
WANG Hong-Yan ¹ ,
DONG Yi-Li ¹ ,
HU Jiong-Sheng ¹ ,
LIU Dong-Ju ¹ ,
WU Chang ¹ ,
XU Yun ¹ ,
YING Ao ¹ ,
FANG Min ^1,, ,
LIU Hong-Ke ^1,2,,

1.
College of Chemistry and Materials Science, Jiangsu Key Laboratory of Biofunctional Materials, Nanjing Normal University, Nanjing 210023, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: FANG Min, liuhongke@njnu.edu.cn LIU Hong-Ke, fangmin@njnu.edu.cn
Received Date: 2 May 2017
Revised Date: 8 June 2017

Figures(4)

Two new coordination polymers, {[Cd₃(SO₄)₄(TITMB)₂(H₂O)₄] [Cd(H₂O)₆]·2CH₃OH}_n (1) and {[Zn(TTTMB) (HCOO)₂]·CH₃OH}_n (2), based on the flexible tripodal ligands 1, 3, 5-tris(imidazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (TITMB) and 1, 3, 5-tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (TTTMB), have been synthesized and character-ized by single-crystal XRD analyses, IR spectra, solid state photoluminescence studies, thermogravimetric analyses, and elemental analyses. Single-crystal X-ray diffraction reveals that both complexes 1 and 2 are two-dimensional layers, and extended to three-dimensional structure by hydrogen bonds. In complex 1, inorganic chains constructed by SO₄^2- and Cd(Ⅱ) are linked by ligand TITMB to the 2D networks, where the[Cd(H₂O)₆]²⁺ units locate in the cavity between two adjacent 2D layers by hydrogen bonds to neutralize the charge. Complex 2 owns typical 6³ 2D topological networks. The thermal stability and photoluminescence property were also studied. Both complexes show high thermal stabilities and display blue fluorescent emissions in the solid state at room temperature.
- flexible tripodal ligand,
- coordination polymers,
- luminescence property
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