Citation: ZHAO Da-Wei, XU Yue, SUN Bao-Chuan, WANG Zhi-Hong, TANG Liang-Fu. Synthesis and Reactivity of ortho-Isopropylthiobenzoyl and Phenylthiomethyl Iron Derivatives[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1547-1554. doi: 10.11862/CJIC.2017.192 shu

Synthesis and Reactivity of ortho-Isopropylthiobenzoyl and Phenylthiomethyl Iron Derivatives

State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: TANG Liang-Fu, lftang@nankai.edu.cn
Received Date: 22 June 2017
Revised Date: 20 July 2017

Figures(5)

Reaction of isopropylthiobenzene with n-BuLi, and subsequently with iron carbonyl and iodine gave a dimeric ortho-isopropylthiobenzoyl iron derivative[(o-ⁱPrS)C₆H₄COFe(CO)₂I]₂ through two iodide bridges, while similar reaction of thioanisole only yielded mononuclear phenylthiomethyl iron complex C₆H₅SCH₂Fe(CO)₃I. These two complexes show significantly different reactivities upon treatment with various nucleophiles. For example, reaction of[(o-ⁱPrS)C₆H₄COFe(CO)₂I]₂ with sodium 2-pyridinethiolate (PySNa) give mononuclear complex (o-ⁱPrS)C₆H₄COFe(CO)₂(SPy), while reaction of C₆H₅SCH₂Fe(CO)₃I with PySNa results in the decomposition of the starting material. On the other hand, reaction of C₆H₅SCH₂Fe(CO)₃I with PPh₃ give complex C₆H₅SCH₂Fe(CO)₂(PPh₃)I, but no characterizable product is obtained from the similar reaction of[(o-ⁱPrS)C₆H₄COFe(CO)₂I]₂. All these newly synthesized compounds have been characterized by physico-chemical and spectroscopic methods, and their structures were unambiguously determined by X-ray crystallography.CCDC: 1545834, 1; 1545835, 2A; 1545836, 3; 1545837, 4.
- thioether,
- iron carbonyl,
- metal-acyl complex,
- pyridine,
- phosphine ligand
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