Citation: LI Fu-An, XU Fu, YANG Wei-Chun. Syntheses, Structures and Photoluminescent Properties of Two 3D Coordination Polymers Based on a Flexible and Angular Organic Aromatic Multi-carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1631-1638. doi: 10.11862/CJIC.2017.190 shu

Syntheses, Structures and Photoluminescent Properties of Two 3D Coordination Polymers Based on a Flexible and Angular Organic Aromatic Multi-carboxylate Ligand

College of Chemistry and Environmental Engineering, Pingdingshan University, Pingdingshan, Henan 467000, China

Corresponding author: LI Fu-An, lifuanpds@163.com
Received Date: 14 March 2017
Revised Date: 26 May 2017

Figures(6)

Two coordination polymers with 3D supramolecular network, {[Zn(L)(bpa)_0.5(H₂O)₂]·2.25H₂O}_n (1) and {[Cd(L)(H₂O)]·2H₂O}_n (2) (H₃LCl=5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid chloride, bpa=1, 2-bis(4-pyridyl)ethane) were hydrothermally synthesized and structurally characterized by X-ray diffraction analyses and further characterized by infrared spectra (IR), elemental analyses, and thermogravimetric (TG) analyses. Compound 1 exhibits a ladder-like chain structure, and such chains are further united together to generate a 3D supramolecular structure through the hydrogen bonding interactions. Compound 2 possesses a 2D coordination network with a 1D channel that run parallel to the coordination layers. Meanwhile, their luminescent properties have also been investigated in detail.CCDC:908522,1;908526,2.
- 5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid chloride,
- 1, 2-bis (4-pyridyl) ethane,
- zinc,
- cadmium
1. [1]
  Cao L H, Zang S Q, Li J B. Z. Anorg. Allg. Chem., 2011, 637:1427-1431 doi: 10.1002/zaac.v637.10
2. [2]
  Zhu H F, Fan J, Okamura T A, et al. Inorg. Chem., 2006, 45(10):3941-3948 doi: 10.1021/ic051925o
3. [3]
  Zhang L P, Ma J F, Yang J, et al. Cryst. Growth Des., 2009, 9(11):4660-4673 doi: 10.1021/cg900460k
4. [4]
  QIAO Yu, WEI Bing, WANG Lu-Yao, et al. Chinese J. Inorg. Chem., 2016, 32(7):1261-1266 doi: 10.11862/CJIC.2016.164
5. [5]
  Dong X Y, Zhang M, Pei R B, et al. Angew. Chem. Int. Ed., 2016, 55:2073-2077 doi: 10.1002/anie.201509744
6. [6]
  Pan C, Nan J P, Dong X L, et al. J. Am. Chem. Soc., 2011, 133(32):12330-12333 doi: 10.1021/ja2031568
7. [7]
  Han L, Valle H, Bu X H. Inorg. Chem., 2007, 46:1511-1513 doi: 10.1021/ic062015p
8. [8]
  Qi Y, Luo F, Batten S R, et al. Cryst. Growth Des., 2008, 8:2806-2813 doi: 10.1021/cg701061q
9. [9]
  Hu Y W, Li G H, Liu X M, et al. CrystEngComm, 2008, 10:888-893 doi: 10.1039/b800255j
10. [10]
  Li S L, Lan Y Q, Qin J S, et al. Cryst. Growth Des., 2009, 9:4142-4146 doi: 10.1021/cg900371k
11. [11]
  Li H Y, Cao L H, Wei Y L, et al. CrystEngComm, 2015, 17:6297-6307 doi: 10.1039/C5CE01008J
12. [12]
  Kuai H W, Fan J, Liu Q, et al. CrystEngComm, 2012, 14:3708-3716 doi: 10.1039/c2ce25062d
13. [13]
  Kuai H W, Hou C, Sun W Y. Polyhedron, 2013, 52:1268-1275 doi: 10.1016/j.poly.2012.06.020
14. [14]
  Ji C, Li B, Ma M L, et al. CrystEngComm, 2012, 14:3951-3958 doi: 10.1039/c2ce06720j
15. [15]
  Li J B, Dong X Y, Cao L H, et al. CrystEngComm, 2012, 14:4444-4453 doi: 10.1039/c2ce06705f
16. [16]
  Zang S Q, Cao L H, Liang R, et al. Cryst. Growth Des., 2012, 12:1830-1837 doi: 10.1021/cg2013733
17. [17]
  LI Fu-An, XU Fu, YANG Wei-Chun, et al. Chinese J. Inorg. Chem., 2016, 32(9):1683-1691
18. [18]
  SMART and SAINT, Area Detector Control and Integration Software, Siemens Analytical X-Ray Systems, Inc. , Madison, WI, 1996.
19. [19]
  Sheldrick G M. SADABS 2. 05, University of Göttingen, Germany, 1997.
20. [20]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, 1997.
21. [21]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112
22. [22]
  Bernstein J, Davis R E, Shimoni L, et al. Angew. Chem. Int. Ed., 1995, 34:1555-1573 doi: 10.1002/(ISSN)1521-3773
23. [23]
  Chang Z, Zhang A S, Hu T L, et al. Cryst. Growth Des., 2009, 9:4840-4846 doi: 10.1021/cg900659r
24. [24]
  Guo J, Ma J F, Liu B, et al. Cryst. Growth Des., 2011, 11:3609-3621 doi: 10.1021/cg200581w
25. [25]
  Zheng S L, Yang J H, Yu X L, et al. Inorg. Chem., 2004, 43:830-838 doi: 10.1021/ic034847i
26. [26]
  Fang S M, Zhang Q, Hu M, et al. Cryst. Growth Des., 2010, 10:4773-4785 doi: 10.1021/cg100645p
27. [27]
  Su Z, Fan J, Chen M, et al. Cryst. Growth Des., 2011, 11:1159-1169 doi: 10.1021/cg101365v
1. [1]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
2. [2]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
3. [3]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
4. [4]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
5. [5]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
6. [6]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
9. [9]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
10. [10]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
11. [11]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
12. [12]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
13. [13]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
14. [14]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
15. [15]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
16. [16]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
17. [17]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
18. [18]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
19. [19]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
20. [20]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(389)
HTML views(43)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142