Citation: LIAO Bei-Ling, YANG Ge-Ge, LI Shi-Xiong, JIANG Yi-Min, YIN Xiu-Ju. Syntheses, Structures and Magnetic Analysis of Co(Ⅱ) Coordination Polymer Based on N-(Pyridine-3-sulfonyl amino) Acetate[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1843-1848. doi: 10.11862/CJIC.2017.189 shu

Syntheses, Structures and Magnetic Analysis of Co(Ⅱ) Coordination Polymer Based on N-(Pyridine-3-sulfonyl amino) Acetate

LIAO Bei-Ling ^1,2 ,
YANG Ge-Ge ² ,
LI Shi-Xiong ^1,2,3,, ,
JIANG Yi-Min ^2,, ,
YIN Xiu-Ju ^1,2

1.
College of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi 546300, China
2.
School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi 541004, China
3.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China

Corresponding author: LI Shi-Xiong, lsx1324@163.com JIANG Yi-Min, 790223684@qq.com
Received Date: 1 April 2017
Revised Date: 26 May 2017

Figures(4)

The reaction of Co(OAc)₂·2H₂O, 4, 4'-azopyridine(4, 4'-azpy) with N-(pyridine-3-sulfonyl amino) acetate (H₂L) in ethanol and water leads to the formation of one mononuclear cobalt polymer {[Co(L)(4, 4'-azpy)(H₂O)]·2H₂O}_n (1). The structure of 1 was analyzed by elemental analysis, IR, TG and single crystal X-ray diffraction. The results show that complex 1 belongs to monoclinic system and P2₁/n space groups. The TGA shows that the structure of 1 remains unchanged during the loss of coordination water molecules and free water molecules, and begins to decompose at 238℃, indicating 1 has good stability. The magnetic investigation shows that there is antiferromagnetic interactions between Co(Ⅱ) ions in polymer 1.
- polymer,
- N-(pyridine-3-sulfonyl amino) acetate,
- structure,
- magnetic
1. [1]
  Zhang S H, Zhang Y D, Zou H H, et al. Inorg. Chim. Acta, 2013, 396:119-125 doi: 10.1016/j.ica.2012.10.032
2. [2]
  Zhang S H, Zhao R X, Li G, et al. RSC Adv., 2014, 4(97):54837-54846 doi: 10.1039/C4RA09687H
3. [3]
  Xiao Y, Liu Y Q, Li G, et al. Supramol. Chem., 2015, 27(3):161-166 doi: 10.1080/10610278.2014.918268
4. [4]
  Wang J, Feng C, Ge C M, et al. J. Clust. Sci., 2016, 27(6):2001-2011 doi: 10.1007/s10876-016-1064-1
5. [5]
  Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013, 113:5110-5129 doi: 10.1021/cr400018q
6. [6]
  Zhang S H, Huang Q P, Zhang H Y, et al. J. Coord. Chem., 2014, 67(19):3155-3166 doi: 10.1080/00958972.2014.964221
7. [7]
  Liao B L, Li S X, Guo J J, et al. Russ. J. Coord. Chem., 2016, 42(4):285-291 doi: 10.1134/S1070328416040035
8. [8]
  廖蓓玲, 李石雄, 银秀菊, 等.无机化学学报, 2016, 32(7):1255-1260
9. [9]
  Jia J J, Zhang L K, Li S X, et al. Chin. J. Struct. Chem., 2017, 36(2):266-272
10. [10]
  Limas N G, Manz T A. RSC Adv., 2016, 6(51):45727-45747 doi: 10.1039/C6RA05507A
11. [11]
  Liddle S T, van Slageren J. Chem. Soc. Rev., 2015, 44(19):6655-6669 doi: 10.1039/C5CS00222B
12. [12]
  Aubin S M J, Wemple M W, Adams D M, et al. J. Am. Chem. Soc., 1996, 118(33):7746-7754 doi: 10.1021/ja960970f
13. [13]
  Zhang S H, Wang J, Zhang H, et al. Dalton Trans., 2017, 46(2):410-419 doi: 10.1039/C6DT04059D
14. [14]
  Wang J M, Zhang C, Zhang X Q, et al. Inorg. Nano-Metal. Chem., 2017, 47(6):893-896 doi: 10.1080/15533174.2016.1228674
15. [15]
  李欢, 陈云舟, 王艳君, 等.无机化学学报, 2016, 32(12):2198-2204
16. [16]
  Miyasaka H, Yamashita M. Dalton Trans., 2007, 4:399-406
17. [17]
  Li S X, Liao B L, Yang G G, et al. Synth. React. Inorganic Met.-Org. Chem., 2015, 45(6):926-929 doi: 10.1080/15533174.2013.843563
18. [18]
  Jia J J, Li S X, Yin X J, et al. Russ. J. Inorg. Chem., 2017, 62(1):63-71 doi: 10.1134/S0036023617010181
19. [19]
  史黎黎, 秦凡.江汉大学学报:自然科学版, 2007, 35:44-46
20. [20]
  Sheldrick G M. SHELXL-97, University of Göttingen, Germany, 1997.
21. [21]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112-122
22. [22]
  Zhao R X, Hai H, Li G, et al. J. Clust. Sci., 2014, 25(6):1541-1552 doi: 10.1007/s10876-014-0750-0
23. [23]
  Li G, Wang W, Zhang S H, et al. J. Clust. Sci., 2014, 25(6):1589-1597 doi: 10.1007/s10876-014-0758-5
24. [24]
  Xu X X, Liu X X, Zhang X, et al. Polyhedron, 2009, 28(14):2997-3004 doi: 10.1016/j.poly.2009.07.043
25. [25]
  Hu B W, Zhao J P, Yang Q, et al. J. Solid State Chem., 2009, 182(10):2918-2923 doi: 10.1016/j.jssc.2009.07.059
26. [26]
  Han Y F, Li M, Wang T W, et al. Inorg. Chem. Commun., 2008, 11(9):945-947 doi: 10.1016/j.inoche.2008.04.028
27. [27]
  Sengupta O, Song Y, Mukherjee P S. Dalton Trans., 2009(46):10343-10352 doi: 10.1039/b916878h
28. [28]
  Zhu L N, Liang M, Wang Q L, et al. J. Mol. Struct., 2003, 657(1):157-163
1. [1]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
2. [2]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
3. [3]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
4. [4]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
5. [5]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
6. [6]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
7. [7]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
8. [8]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
9. [9]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
10. [10]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
11. [11]
  Huimin Gao , Zhuochen Yu , Xuze Zhang , Xiangkun Yu , Jiyuan Xing , Youliang Zhu , Hu-Jun Qian , Zhong-Yuan Lu . A mini review of the recent progress in coarse-grained simulation of polymer systems. Chinese Journal of Structural Chemistry, 2024, 43(5): 100266-100266. doi: 10.1016/j.cjsc.2024.100266
12. [12]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
13. [13]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
14. [14]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
15. [15]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
16. [16]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
17. [17]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
18. [18]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
19. [19]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
20. [20]
  Yuanzhe Lu , Yuanqin Zhu , Linfeng Zhong , Dingshan Yu . Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes. Chinese Journal of Structural Chemistry, 2024, 43(3): 100249-100249. doi: 10.1016/j.cjsc.2024.100249

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(291)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142