Citation: SONG Qiang, Li LI, LUO Hong-Xiang, LIU Yue, YANG Chang-Long. Hierarchical Nanoflower-Ring Structure Bi₂O₃/(BiO)₂CO₃ Composite for Photocatalytic Degradation of Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1161-1171. doi: 10.11862/CJIC.2017.139 shu

Hierarchical Nanoflower-Ring Structure Bi₂O₃/(BiO)₂CO₃ Composite for Photocatalytic Degradation of Rhodamine B

SONG Qiang ^1,2 ,
Li LI ^1,2,3,, ,
LUO Hong-Xiang ² ,
LIU Yue ² ,
YANG Chang-Long ¹

1.
College of Materials Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China;
2.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China;
3.
College of Heilongjang Province Key Laboratory of Fine Chemicals, Qiqihar, Heilongjiang 161006, China

Corresponding author: Li LI, qqhrll@163.com
Received Date: 20 December 2016
Revised Date: 16 March 2017

Figures(12)

Hierarchical nanoflower-ring structure Bi₂O₃/(BiO)₂CO₃(BO/BCO) composite was successfully synthesized by the temperature-programmed hydrothermal treatment.X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis/DRS), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM) and N₂ adsorption-desorption tests were employed to characterize the crystalline phase, chemical composition, optical absorption properties, morphology and surface physicochemical properties of as-synthetized material.The results showed that the crystalline phase of (BiO)₂CO₃ was tetragonal phase, and the crystalline phase of Bi₂O₃ was the monoclinic phase in as-composite Bi₂O₃/(BiO)₂CO₃ which had both as-crystal structures.Moreover, with the introduction of OH^- and reaction time increasing in synthesis process, the intensity of characteristics diffraction peak of (BiO)₂CO₃ was gradually decreased, meanwhile, that of Bi₂O₃ was gradually increased, showing that the proportions of Bi₂O₃ were increased in the sample with reaction time increased.The results of UV-Vis/DRS analysis showed that the absorption edge of as-synthetized composite BO/BCO had shift compared to pure Bi₂O₃ and pure (BiO)₂CO₃, and the absorption was effectively increased in the visible light region with the introduction of Bi₂O₃.At the same time, (BiO)₂CO₃ nanolayer was changed to the hierarchical nanoflower-ring structure BO/BCO-0.5 composite, and the formation of special morphology leads to narrowed band gap and change the reflection and scattering of photoelectrons, which were conducive to the absorption efficiency of light and transfering of photogenerated charges.In addition, the photocatalytic activities of as-composites BO/BCO were studied by degradation photocatalytic experiments of RhB as the model molecule under different light irradiation, the cycle experiment and the capture experiment.The results of photocatalytic activity experiment showed that the activity of BO/BCO-0.5 was significantly higher than that of other systems (Bi₂O₃ and P25), and the photocatalytic activity of BO/BCO-0.5 was kept even after three cycles.Meanwhile, according to the capture experimental results, the possible photocatalytic reaction mechanism of BO/BCO composite was speculated.
- temperature-programmed hydrothermal treatment,
- bismuth oxide,
- bismuth subcarbonate,
- hierarchical nanoflower-ring structure,
- photocatalytic degradation,
- rhodamine B
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Hierarchical Nanoflower-Ring Structure Bi2O3/(BiO)2CO3 Composite for Photocatalytic Degradation of Rhodamine B

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Hierarchical Nanoflower-Ring Structure Bi₂O₃/(BiO)₂CO₃ Composite for Photocatalytic Degradation of Rhodamine B