Citation: LUO Di-Di, TIAN Jian-Hua, ZHU Xi, WANG Zhao-Dong, SHAN Zhong-Qiang. Effect of Carbon and Graphene on Performance of LiMnPO₄ Material[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1000-1006. doi: 10.11862/CJIC.2017.129 shu

Effect of Carbon and Graphene on Performance of LiMnPO₄ Material

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

Corresponding author: SHAN Zhong-Qiang, shanzq@tju.edu.cn
Received Date: 26 December 2016
Revised Date: 10 March 2017

Figures(6)

LiMnPO₄ was synthesized by solvothermal method. LiMnPO₄/carbon/graphene composites with different amount of pyrolytic carbon and graphene were prepared using sucrose and graphene as carbon sources. The effect of pyrolytic carbon and graphene on the performance of material was investigated. The morphology of the material was characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). Pyrolytic carbon coating can enhance the surface electronic conductivity of LiMnPO₄ nanoplates, which plays a major role in improving the performances of the material. Graphene can enhance the electronic and ionic conductivity between nanoplates, and then improve the electrochemical properties of the material. Electrochemical measurements indicate that LiMnPO₄ electrode with 4% pyrolytic carbon and 2% graphene exhibits better electrochemical performances. The specific capacity is 139.1 mAh·g^-1 at 0.5C and the capacity retention is 93.6% after 100 cycles. Compared with single carbon and single graphene LiMnPO₄ electrode, the specific capacity at 0.5C of LMP-C(4)-G(2) electrode is increased by 35.0% and 48.6%.
- lithium manganese phosphate,
- carbon coating,
- graphene,
- electrochemical performance
1. [1]
  Croguennec L, Palacin M R. J. Am. Chem. Soc., 2015, 137(9):3140-3156 doi: 10.1021/ja507828x
2. [2]
  Herrera J O, Camacho-Montes H, Fuentes L E, et al. J. Mater. Sci. Chem. Eng., 2015, 3(05):54-64
3. [3]
  HU Guo-Rong, PENG Qing-Yuan, PENG Zhong-Dong, et al. Chinese J. Inorg. Chem., 2015, 31(6):1153-1158
4. [4]
  Aravindan V, Gnanaraj J, Lee Y S, et al. J. Mater. Chem. A, 2013, 1(11):3518-3539 doi: 10.1039/c2ta01393b
5. [5]
  Jiang Y, Liu R, Xu W, et al. J. Mater. Res., 2013, 28(18):2584-2589 doi: 10.1557/jmr.2013.235
6. [6]
  WAN Yang, ZHENG Qiao-Ji, LIN Dun-Min. Acta Chim. Sinica, 2014, 72(5):537-551
7. [7]
  Qin Z, Zhou X, Xia Y, et al. J. Mater. Chem., 2012, 22(39):21144-21153 doi: 10.1039/c2jm30821e
8. [8]
  Voepel P, Suchomski C, Hofmann A, et al. CrystEngComm, 2016, 18(2):316-327 doi: 10.1039/C5CE01946J
9. [9]
  Zhao M, Fu Y, Xu N, et al. J. Mater. Chem. A, 2014, 2(36):15070-15077 doi: 10.1039/C4TA03311F
10. [10]
  Choi D, Wang D, Bae I T, et al. Nano Lett., 2010, 10(8):2799-2805 doi: 10.1021/nl1007085
11. [11]
  Su L, Sha Y, Jiang J, et al. J. Nanomater., 2015, 16(1):212(8 pages)
12. [12]
  Yi H, Hu C, He X, et al. Ionics, 2015, 21(3):667-671 doi: 10.1007/s11581-014-1238-5
13. [13]
  Huo Z Q, Cui Y T, Wang D, et al. J. Power Sources, 2014, 245:331-336 doi: 10.1016/j.jpowsour.2013.06.148
14. [14]
  Liu J, Liu X, Huang T, et al. J. Power Sources, 2013, 229:203-209 doi: 10.1016/j.jpowsour.2012.11.093
15. [15]
  Li L, Liu J, Chen L, et al. RSC Adv., 2013, 3(19):6847-6852 doi: 10.1039/c3ra22862b
16. [16]
  Zhang Y, Feng H, Wu X, et al. Electrochim. Acta, 2009, 54(11):3206-3210 doi: 10.1016/j.electacta.2008.11.033
17. [17]
  LIN Zi-Xia, WANG Gang, ZHENG Ming-Bo, et al. Chinese J. Inorg. Chem., 2013, 29(7):1465-1470
18. [18]
  Gong D, Wang B, Zhu J, et al. Adv. Eng. Mater., 2017, 7(3):201601885
19. [19]
  Zhu J, Childress A S, Karakaya M, et al. Adv. Mater., 2016, 28(33):7185-7192 doi: 10.1002/adma.201602028
20. [20]
  GENG Kai-Ming, WU Jun-Jie, GENG Hong-Bo, et al. Chinese J. Inorg. Chem., 2016, 32(9):1495-1502
21. [21]
  Yang X, Tu J, Lei M, et al. Electrochim Acta, 2016, 193:206-215 doi: 10.1016/j.electacta.2016.02.068
22. [22]
  Yang Y, Wang B, Zhu J, et al. ACS Nano, 2016, 10(5):5516-5524 doi: 10.1021/acsnano.6b02036
23. [23]
  Yang S T, Zhao N H, Dong H Y, et al. Electrochim. Acta, 2005, 51(1):166-171 doi: 10.1016/j.electacta.2005.04.013
24. [24]
  Su C, Bu X, Xu L, et al. Electrochim. Acta, 2012,64:190-195 doi: 10.1016/j.electacta.2012.01.014
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
3. [3]
  Vanita Vanita , Roland Schoch , Pascal Puphal , Hasan Yilmaz , Matthias Bauer , Oliver Clemens . Structural and electrochemical behaviour of bilayer manganite LaSr₂Mn₂O_6.96 cathode for all-solid-state fluoride ion batteries. Acta Physico-Chimica Sinica, 2026, 42(3): 100181-0. doi: 10.1016/j.actphy.2025.100181
4. [4]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
5. [5]
  Hailang JIA , Yujie LU , Pengcheng JI . Preparation and properties of nitrogen and phosphorus co-doped graphene carbon aerogel supported ruthenium electrocatalyst for hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2327-2336. doi: 10.11862/CJIC.20250021
6. [6]
  Yuanchun Pan , Xinyun Lin , Leyi Yang , Wenya Hu , Dekui Song , Nan Liu . Artificial Intelligence Science Practice: Preparation of Electronic Skin by Chemical Vapor Deposition of Graphene. University Chemistry, 2025, 40(11): 272-280. doi: 10.12461/PKU.DXHX202412052
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
9. [9]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 100026-0. doi: 10.3866/PKU.WHXB202405002
10. [10]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-0. doi: 10.3866/PKU.WHXB202310024
11. [11]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
12. [12]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
13. [13]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
16. [16]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
17. [17]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-0. doi: 10.3866/PKU.WHXB202406014
18. [18]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441
19. [19]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
20. [20]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1485)
HTML views(245)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Carbon and Graphene on Performance of LiMnPO4 Material

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Carbon and Graphene on Performance of LiMnPO₄ Material