Citation: CHEN Man-Sheng, HUANG Xiu-Yu, CHEN Xiao-Li, LIU Qin, HE Xiang-Liang, ZENG Zhao-Jian. Syntheses, Crystal Structures and Properties of Two d¹⁰ Metal Complexes Constructed from 1, 5-bis(2-ethyl-imidazolyl)pentane(English)[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1090-1096. doi: 10.11862/CJIC.2017.128 shu

Syntheses, Crystal Structures and Properties of Two d¹⁰ Metal Complexes Constructed from 1, 5-bis(2-ethyl-imidazolyl)pentane(English)

1.
Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, College of Chemistry and Materials Science, Hengyang, Hunan 421008, China
2.
School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, Guangxi 541004, China

Corresponding author: CHEN Man-Sheng, cmsniu@163.com
Received Date: 19 March 2016
Revised Date: 28 April 2017

Figures(6)

Reaction of CdCl₂ or ZnCl₂·4H₂O, 5-hydroxyisophthalic acid (5-OHH₂IP) as well as 1, 5-bis(2-ethyl-imidazolyl)pentane(BEIP) results in formation of a 1D [Cd(BEIP)(Cl)₂]_n (1) and 2D [Zn(BEIP)(5-OHIP)]_n (2). X-ray diffraction crystal structure analysis shows that 1 crystallizes in orthorhombic system, space group Pca2₁, while 2 is of monoclinic, space group P2₁/n with β=100.542(4)°. In 1, the 1, 5-bis(2-ethyl-imidazolyl)pentane links all the Cd atoms into a 1D chain. In 2, the carboxylate group with μ₂-η¹:η¹ coordination mode links metal atoms to give a 1D zigzag chain structure, which forming the 2D layer through Zn-N interactions by BEIP ligands. Finally the 2D layers are further assembled into 3D framework by the H-bond interaction. In addition, the properties of complexes 1 and 2 have been investigated, which exhibit good fluorescence in the solid state at room temperature. And complex 2 shows good photocatalytic activity for the degradation of methyl orange solution. CCDC:1523229, 1; 1523230, 2.
- 1, 5-bis(2-ethyl-imidazolyl)pentane,
- crystal structure,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Crystal Structures and Properties of Two d10 Metal Complexes Constructed from 1, 5-bis(2-ethyl-imidazolyl)pentane(English)

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Crystal Structures and Properties of Two d¹⁰ Metal Complexes Constructed from 1, 5-bis(2-ethyl-imidazolyl)pentane(English)