Citation: ANG Lin-Lin, JING Xu, HE Cheng, DUAN Chun-Ying. Photocatalytic Hydrogen Production Based on Cobalt-Thiosemicarbazone Complex with the Xanthene Dye Moiety[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 913-922. doi: 10.11862/CJIC.2017.126 shu

Photocatalytic Hydrogen Production Based on Cobalt-Thiosemicarbazone Complex with the Xanthene Dye Moiety

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: HE Cheng, hecheng@dlut.edu.cn
Received Date: 21 December 2016
Revised Date: 25 April 2017

Figures(6)

Two cobalt complexes containing NSP (nitrogen-sulphur-phosphor) chelator prepared from thiose-micarbazone ligands with different terminal functional groups and triphenylphosphine moiety have been synthesized in high yield and characterized. Their photocatalytic activity for hydrogen evolution under visible light irradiation was investigated. The photocatalyst [Co(L2)(L2')](BF₄)_2.5·H₂O·0.5C₂H₅OH (2) (L2=2-(diphenylphosphino)benzylidene-2-(3, 6-bis(ethylamino)-2, 7-dimethyl-9H-xanthen-9-yl)benzothiohydrazide, L2'=2-(diphenylphosphinooxide)benzylidene-2-(3, 6-bis(ethylamino)-2, 7-dimethyl-9H-xanthen-9-yl) benzothiohydrazide) containing rhodamine groups exhibited activity in light driven hydrogen evolution with the TON and initial TOF reaching to 2 800 mol_H₂·mol_cat^-1 and 930 mol_H₂·mol_cat^-1·h^-1, respectively, which is much higher than that of complex [Co(L1)(L1')](BF₄)·0.5H₂O (1) (L1=2-(diphenylphosphino)benzylidene hydrazinecarbodithionate, L1'=2-(diphenyl-phosphinooxide)benzylidene hydrazinecarbodithionate) under similar conditions. The higher catalytic activity was attributed to the potential intermolecular π-π stack interactions between the catalyst 2 and photosensitizer fluorescein (Fl) benefiting the photoinduced electron transfer between the photosensitizer and the photocatalyst.CCDC:1523357;1, 1523358, 2.
- photoinduced electron transfer,
- cobalt,
- thiosemicarbazone,
- light driven H₂ production
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