Citation: ZHANG Li-Fang, XU Lu, JI Yu-Jie, NI Zhong-Hai. Syntheses, Crystal Structures and Magnetic Properties of Cyanide-and Phenolate-Bridged Two-Dimensional M(Ⅱ)-Mn(Ⅲ) (M=Ru and Os) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1051-1058. doi: 10.11862/CJIC.2017.124 shu

Syntheses, Crystal Structures and Magnetic Properties of Cyanide-and Phenolate-Bridged Two-Dimensional M(Ⅱ)-Mn(Ⅲ) (M=Ru and Os) Complexes

School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: NI Zhong-Hai, nizhonghai@cumt.edu.cn
Received Date: 6 December 2016
Revised Date: 18 April 2017

Figures(5)

Two new M(Ⅱ)-Mn(Ⅲ) complexes {[Mn(Ⅲ)(salen)]₄[Mn(Ⅲ)(salen)(H₂O)]₂[M(Ⅱ)(CN)₆]}(ClO₄)₂·2H₂O (M=Ru (1) and Os (2)) (salen^2-=N, N'-ethylenebis(salicylideneaminato)dianion) have been synthesized based on [Mn(Ⅲ)(salen)]⁺ segment and hexacyanide-containing building blocks [M(Ⅱ)(CN)₆]^4-. Single crystal X-ray diffraction analyses show that both complexes are isostructurally two-dimensional (2D) structures in which cyanide-bridged heptanuclear [Mn(Ⅲ)₆M(Ⅱ)]²⁺ units are linked together by double phenolate bridges. Magnetic studies show that they are abnormal antiferromagnetic through the double phenolate bridges with the magnetic coupling constant J=-0.340 cm^-1 for 1 and -0.561 cm^-1 for 2 based on the spin exchange Hamiltonian Ĥ=-2J_MnMnŜ_Mn1Ŝ_Mn2.
- dimetallic complex,
- cyanide-bridged,
- phenolate-bridged,
- antiferromagnetic coupling
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