Citation: ZHANG Lan-He, GAO Wei-Wei, CHEN Zi-Cheng, ZHOU Jing, WANG Xu-Ming, ZHANG Hai-Feng. CoAl₂O₄/Ceramic Honeycomb Catalyst: Preparation and Performance on Catalytic Ozonation in Wastewater Treatment[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 985-992. doi: 10.11862/CJIC.2017.115 shu

CoAl₂O₄/Ceramic Honeycomb Catalyst: Preparation and Performance on Catalytic Ozonation in Wastewater Treatment

1.
School of Chemical Engineering, Northeast Electric Power University, Jilin, Jilin 132012, China
2.
Beijing Agro-Biotechnology Research Center, Beijing 100089, China

Corresponding author: ZHANG Lan-He, zhanglanhe@163.com
Received Date: 18 December 2016
Revised Date: 18 March 2017

Figures(10)

CoAl₂O₄/ceramic honeycomb catalyst was prepared by coated method and was characterized by X-ray diffraction, N₂ adsorption-desorption and transmission electron microscope. Catalytic ozonation of hydroquinone was conducted to evaluate its catalytic activity. The results showed that the crystal phase of CoAl₂O₄/ceramic honeycomb belonged to a typical spinel structure with a large specific surface area of 77 m²·g^-1, pore volume of 0.001 7 cm³·g^-1 and pore size of 3.9 nm. The removal efficiencies of hydroquinone and COD during ozonation of O₃-CoAl₂O₄/ceramic honeycomb were 81.2% and 47.7%, respectively. The degradation efficiency of hydroquinone decreased significantly after the addition of tert-butanol, and the ozonation of CoAl₂O₄/ceramic honeycomb catalyst should follow a hydroxyl radical mechanism.
- catalytic ozonation,
- hydroquinone,
- CoAl₂O₄/ceramic honeycomb,
- hydroxyl radical
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

CoAl₂O₄/Ceramic Honeycomb Catalyst: Preparation and Performance on Catalytic Ozonation in Wastewater Treatment