Citation: WANG Zhu-Mei, ZHU Xiao-Ling, LI Yue-Ming, LIAO Run-Hua, SHEN Zong-Yang. Effect of NaBF₄ Addition on the Preparation of TiO₂ Nanotubes Photocatalyst by Anodic Oxidation Method[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 970-976. doi: 10.11862/CJIC.2017.113 shu

Effect of NaBF₄ Addition on the Preparation of TiO₂ Nanotubes Photocatalyst by Anodic Oxidation Method

China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China

Corresponding author: LI Yue-Ming, lym6329@163.com
Received Date: 2 December 2016
Revised Date: 21 March 2017

Figures(10)

Visible light-active boron doped TiO₂ nanotube arrays (B/TNTs) were synthesized by adding NaBF₄ in anodic oxidation electrolyte. The photocatalytic properties to methylene blue(MB) solution were investigated under visible light irradiation. FE-SEM analysis showed that the morphology of B/TNTs was obviously different. EDS, XPS and FTIR analysis indicated that boron was incorporated into the TNTs lattice to form B-O-Ti bond. B doping could effectively promote the formation of active group Ti-OH on the surface of TiO₂, decrease the band gap energy and make the absorption edges of the samples red-shifting. Such effect became stronger with the increase of the B doping concentration. XRD analysis indicated that B doping promoted the growth of anatase grains. The doped TiO₂ nanotubes can form anatase phase as pure one when calcined at 550 ℃. The B/TNTs with an optimal photocatalytic activity were fabricated with the NaBF₄ concentration of 0.6%(w/w). The photocatalytic degradation rate of MB in 4 h increased from 39.90% for TNTs without NaBF₄ addition to 69% for B/TNTs, and their photocatalytic degradation ability is basically unchanged after using 10 times. The total organic carbon(TOC) removal rates indicated that the MB can be efficiently mineralized under visible light illumination.
- boron doping,
- TiO₂ nanotubes,
- visible light,
- photocatalytic activity
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Effect of NaBF₄ Addition on the Preparation of TiO₂ Nanotubes Photocatalyst by Anodic Oxidation Method