Citation: LI Yu-Xiang, DENG Sheng-Yu, FAN Ya-Lei, WANG De-Qiang. Spectroscopic Properties of Tm³⁺/Er³⁺/Ho³⁺ Co-doped SiO₂-Bi₂O₃-AlF₃-BaF₂ Glasses[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 801-808. doi: 10.11862/CJIC.2017.106 shu

Spectroscopic Properties of Tm³⁺/Er³⁺/Ho³⁺ Co-doped SiO₂-Bi₂O₃-AlF₃-BaF₂ Glasses

School of Material Science and Technology, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: WANG De-Qiang, derek_wang@ecust.edu.cn
Received Date: 9 October 2016
Revised Date: 1 March 2017

Figures(9)

The Tm³⁺, Er³⁺ and Ho³⁺ co-doped bismuth silicate glasses 50SiO₂-40Bi₂O₃-5AlF₃-5BaF₂ were prepared by high-temperature melt-quenching method. The spectroscopic properties of Tm³⁺, Er³⁺ and Ho³⁺ co-doped bismuth silicate at 2 060 nm exited by 808 nm Laser Diode were investigated. Thermal stability of the glasses, absorption spectra and fluorescence spectra of the Tm³⁺, Er³⁺ and Ho³⁺ co-doped glass samples were measured. According to the absorption spectrum and Judd-Oflet theory, the Judd-Oflet intensity parameters of Ho³⁺ Ω_t(t=2, 4, 6), absorption cross sections of Tm³⁺, Er³⁺ and Ho³⁺ were calculated, respectively. The measured fluorescence spectra manifest that the maximal emission intensity of Ho³⁺:⁵I₇→⁵I₈ at 2 060 nm can be achieved at the concentration of 0.75% Tm₂O₃, 1.0% Er₂O₃ and 0.5% Ho₂O₃ in bismuth silicate glasses. Besides the spectroscopic properties of Tm³⁺, Er³⁺ and Ho³⁺ separately and possible energy transfer mechanisms among Tm³⁺, Er³⁺ and Ho³⁺ were analyzed and discussed in detail. The maximal absorption and emission cross sections of Ho³⁺ are 9.08×10^-21 cm² at 1 953 nm and 1.168×10^-20 cm² at 2 060 nm, respectively, with a lifetime of 2.75 ms, while large σ_emτ achieved (3.212×10^-20 cm²·ms) suggesting its efficient application in 2 μm fiber lasers.
- optics,
- 2.0 μm emission,
- Tm³⁺/Er³⁺/Ho³⁺co-doped,
- bismuth silicate glass
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沈阳化工大学材料科学与工程学院沈阳 110142

Spectroscopic Properties of Tm3+/Er3+/Ho3+ Co-doped SiO2-Bi2O3-AlF3-BaF2 Glasses

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通讯作者: 陈斌, bchen63@163.com

Spectroscopic Properties of Tm³⁺/Er³⁺/Ho³⁺ Co-doped SiO₂-Bi₂O₃-AlF₃-BaF₂ Glasses