Citation: WANG Xin-Ping, LI Ying-Ying, LIU Yong, SUN Jing, LIU Kang, WANG Lei. Syntheses, Structures and Luminescence Properties of Coordination Polymers in Mixed-Ligand System[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 823-829. doi: 10.11862/CJIC.2017.104 shu

Syntheses, Structures and Luminescence Properties of Coordination Polymers in Mixed-Ligand System

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

Corresponding author: LIU Kang, liukang82@126.com
Received Date: 3 November 2016
Revised Date: 8 April 2017

Figures(6)

Three novel coordination polymers, formulated as[Cd₃(pic)₄(H₂bmimb)]_n (1), [Co₃(pic)₄(H₂bmimb)]_n (2), [Cd₂(1, 2-mbix)(pic)₂(H₂O)₂]_n (3) (H₂bmimb=1, 4-bis ((2-methyl-1H-imidazol-1-yl) methyl) benzene, 1, 2-mbix=1, 2-bis ((2-methyl-1H-imidazol-1-yl) methyl) benzene, pic=5-phenylisophthalic acid), were synthesized by self-assembly of mixed ligands with Cd (Ⅱ) and Co (Ⅱ) under solvothermal conditions and characterized by means of single-crystal X-ray diffraction, X-ray powder diffraction, infrared spectra, thermogravimetric analysis and fluorescence spectra. Single-crystal X-ray diffraction analysis revealed that complexes 1 and 2 possess 3D anionic frameworks, in which the protonated bis-imidazole ligands balance the charge of the frameworks. In complex 3, the Cd²⁺ ions are linked by pic and 1, 2-mbix ligands to generate a 1D chain structure. The adjacent chains are held together to form a 2D layer via π…π stacking and then a 3D supramolecular framework through hydrogen-bonding interactions. In addition, luminescence properties of complexes 1 and 3 in the solid state were characterized.
- solvothermal synthesis,
- coordination polymers,
- mixed-ligand,
- luminescence propreties
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