Citation: GU Yan, LIU Guan-Ting, ZOU Cheng-Heng, ZHANG Zhen, LIU Juan, SUN Ming, CHENG Gao, YU Lin. Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 787-795. doi: 10.11862/CJIC.2017.102 shu

Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄

Guangdong University of Technology, School of Chemical Engineering and Light Industry, Guangzhou 510006, China

Corresponding author: YU Lin, gych@gdut.edu.cn
Received Date: 22 December 2016
Revised Date: 22 March 2017

Figures(10)

The Au/Fe₃O₄ catalyst was successfully prepared by the simple ultrasonic method and in-situ reduction method. Au was immobilized on the surface of Fe₃O₄ using APTES as an organic bridging bond to obtain monodisperse magnetic Au/Fe₃O₄. Au⁰ could not agglomerated in the condition of NH³⁺, so that it had high catalytic activity and stability. The results of XRD, HRTEM, EDS and XPS showed that Au/Fe₃O₄ has been prepared successfully. It was used to catalyze the reduction of 4-nitrophenols to 4-aminophenols, which showed high catalytic activity with rate constant of 0.225 6 min^-1. The repeatability test showed that the catalyst had good stability. After 9 cycles of reaction, the conversion rate of the reaction was still 94%.
- Au nanoparticles,
- Fe₃O₄,
- 4-nitrophenols,
- catalytic reduction
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Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe3O4

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Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄