Citation: JI Qin, CHEN Li-Zhuang. Syntheses, Characterization and Fluorescence Properties Analysis of Two Lanthanide Coordination Polymers Based on Axial Chirality Ligand 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 874-880. doi: 10.11862/CJIC.2017.099 shu

Syntheses, Characterization and Fluorescence Properties Analysis of Two Lanthanide Coordination Polymers Based on Axial Chirality Ligand 2, 2'-Dinitro-4, 4'-biphenyldicarboxylic Acid

JI Qin ,
CHEN Li-Zhuang ^*,,

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: CHEN Li-Zhuang, clz1977@sina.com
Received Date: 14 November 2016
Revised Date: 9 March 2017

Figures(7)

Two lanthanide coordination polymers, La (nbpdc)(phen)(FA) (1), Eu (nbpdc)(phen)(FA) (2) (FA=formic acid ion) based on bridging ligand 2, 2'-dinitro-4, 4'-biphenyldicarboxylic acid (H₂nbpdc) and 1, 10-Phenanthroline monohydrate (phen), have been synthesized by the hydrothermal method and characterized by IR, single-crystal X-ray structure analysis, thermogravimetric analysis, luminescent properties, circular dichroism (CD) analysis and dielectric properties. Complexes 1 and 2 exhibited a rare three-interlude 3D structure with the same topology structure of (4⁴·6²). In addition, the two complexes exhibit fluorescent emissions in the solid state at room temperature. Fluorescent analysis of complexes 1 and 2 showed an intense emission band at 606 nm (λ_ex=495 nm) and 615.5 nm (λ_ex=395.5 nm), respectively. Moreover, the circular dichroism analysis of complexes 1 and 2 was measured with chirality.
- coordination polymer,
- hydrothermal condition,
- fluorescence,
- chirality
1. [1]
  Delgado S, Sanz miguel P J, Priego J L, et al. Inorg. Chem., 2008, 47:9128-9130 doi: 10.1021/ic801314s
2. [2]
  Thallapally P K, Tian J, Motkuri R K, et al. J. Am. Chem. Soc., 2008, 130:16842-16843 doi: 10.1021/ja806391k
3. [3]
  Wang P, Ma J P, Dong Y B, et al. J. Am. Chem. Soc., 2007, 129:10620-10621 doi: 10.1021/ja072442h
4. [4]
  Cai S L, Zheng S R, Fan J, et al. J. Solid State Chem., 2011, 184:3172-3178 doi: 10.1016/j.jssc.2011.09.006
5. [5]
  Hu S, He K H, Zeng M H, et al. Inorg. Chem., 2008, 47:5218-5224 doi: 10.1021/ic800050u
6. [6]
  Eddaoudi M, Moler D B, Li H, et al. Acc. Chem. Res., 2001, 43:319-330
7. [7]
  Evans O R, Lin W. Acc. Chem. Res., 2002, 35:511-522 doi: 10.1021/ar0001012
8. [8]
  Rosi N L, Kim J, Eddaoudi M, et al. J. Am. Chem. Soc., 2005, 127:1504-1518 doi: 10.1021/ja045123o
9. [9]
  Chen L Z, Wang F M, Shu H. J. Coord. Chem., 2012, 65:439-452 doi: 10.1080/00958972.2012.654786
10. [10]
  Farha O K, Hupp J T. Acc. Chem. Res., 2010, 43:1166-1175 doi: 10.1021/ar1000617
11. [11]
  Peng R, Li M, Li D. Coord. Chem. Rev., 2010, 254:1-18 doi: 10.1016/j.ccr.2009.10.003
12. [12]
  Zhou H C, Long J, Yaghi O M. Chem. Rev., 2012, 112:673-674 doi: 10.1021/cr300014x
13. [13]
  Zhao H, Qu Z R, Ye H Y, et al. Chem. Soc. Rev., 2008, 37:84-100 doi: 10.1039/B616738C
14. [14]
  Xu G, Guo G C, Wang M S, et al. Angew. Chem. Int. Ed., 2007, 46:3249-3251 doi: 10.1002/(ISSN)1521-3773
15. [15]
  Zhang W, Xiong R G. Chem. Rev., 2012, 112:1163-1195 doi: 10.1021/cr200174w
16. [16]
  Xu G C, Zhang W, Ma X M, et al. J. Am. Chem. Soc., 2011, 113:14948-14951
17. [17]
  CHEN Li-Zhuang, CAO Xing-Xing, WANG Fang-Ming, et al. Chinese J. Inorg. Chem., 2012, 28(6):1291-1297
18. [18]
  HUANG Deng-Deng, CHEN Li-Zhuang. Chinese J. Inorg. Chem., 2015, 31(2):377-384
19. [19]
  McGehee M D, Bergstedt T, Zhang C, et al. Adv. Mater., 1999, 11:1349-13549 doi: 10.1002/(ISSN)1521-4095
20. [20]
  Piguet C, Bunzli J C G, Bernardinelli G, et al. J. Am. Chem. Soc., 1993, 115:8197-8206 doi: 10.1021/ja00071a032
21. [21]
  Zhao B, Chen X Y, Chen P, et al. J. Am. Chem. Soc., 2004, 126:15394-15395 doi: 10.1021/ja047141b
22. [22]
  Sun L N, Zhang H J, Meng Q G, et al. J. Phys. Chem. B, 2005, 109:6174-6182
23. [23]
  Chen L Z, Huang Y, Xiong R G, et al. J. Mol. Struct., 2010, 963:16-21 doi: 10.1016/j.molstruc.2009.09.038
24. [24]
  Chen L Z, Huang D D. Chin. Chem. Lett., 2014, 25:279-282 doi: 10.1016/j.cclet.2013.11.031
25. [25]
  Chen L Z, Pan Q J, Cao X X, et al. CrystEngComm, 2016, 18:1944-1952 doi: 10.1039/C5CE02426A
26. [26]
  Wu R F, Zhang T L, Qiao X J. Chin. Chem. Lett., 2010, 21:1007-1010 doi: 10.1016/j.cclet.2010.02.006
27. [27]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
28. [28]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
29. [29]
  Spek A L. Acta Crystallogr. Sect. C, 2015, C71:9-18
30. [30]
  Blatov V, Shevchenko A, Serezhkin V, et al. J. Appl. Crystallogr., 2000, 33:1193 doi: 10.1107/S0021889800007202
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