Citation: YU Yan-Yan, GUAN Yun-Feng, CONG Ye, YUAN Xiu-Lan, LI Xuan-Ke, ZHANG Jiang. Preparation and Supercapacitive Performances of SiC-CDCs[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 853-859. doi: 10.11862/CJIC.2017.085 shu

Preparation and Supercapacitive Performances of SiC-CDCs

YU Yan-Yan ¹ ,
GUAN Yun-Feng ¹ ,
CONG Ye ^1,*,, ,
YUAN Xiu-Lan ¹ ,
LI Xuan-Ke ^1,2,*,, ,
ZHANG Jiang ¹

1.
Wuhan University of Science and Technology, College of Chemistry and Chemical Engineering, Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan 430081, China
2.
Hunan University, College of Materials Science and Engineering, Changsha 410082, China

Corresponding author: CONG Ye, congye626@126.com LI Xuan-Ke, xkli8524@sina.com
Received Date: 18 December 2016
Revised Date: 13 March 2017

Figures(9)

Silicon carbide precursors were synthesized by pyrolysis of polycarbosilane (PCS) at higher temperature. Subsequently, silicon carbide-derived carbons (SiC-CDCs) were obtained via chlorination of the SiC precursors at 1 000℃. The microstructure and morphology of the SiC-CDCs were characterized by X-ray diffraction pattern (XRD), Raman spectra, Transmission electron microscope (TEM) and N₂ adsorption-desorption method. The effects of pyrolysis temperature on the crystal phase, morphology, pore size and distribution of the SiC-CDCs were investigated and the electrochemical performances as the electrode of supercapacitors were evaluated. The results show that SiC-CDCs with larger specific surface areas and sub-nanometer pores can be successfully prepared by chlorination of SiC precursors. Meanwhile, the SiC-CDCs exhibit better specific capacitances and supercapacitive performances at different current densities.
- polycarbosilane,
- pyrolysis,
- chlorine etching,
- silicon carbide-derived carbons,
- pore structure,
- supercapacitor
1. [1]
  Zhang Y X, Huang M, Li F, et al. J. Power Sources, 2014, 246(3):449-456
2. [2]
  Atwater T B, Cygan P J, Leung F C. J. Power Sources, 2000, 91(1):27-36 doi: 10.1016/S0378-7753(00)00484-5
3. [3]
  Chen H S, Cong T N, Yang W. Prog. Nat. Sci., 2009, 19(3):291-312 doi: 10.1016/j.pnsc.2008.07.014
4. [4]
  JIN Li, SUN Dong, ZHANG Jian-Rong. Chinese J. Inorg. Chem., 2012, 28(6):1084-1090
5. [5]
  Liu Y, Zhao W, Zhang X. Electrochim. Acta, 2008, 53(8):3296-3304 doi: 10.1016/j.electacta.2007.11.022
6. [6]
  Zhang L L, Gu Y, Zhao X S. J. Mater. Chem., 2013, 1(33):9395-9408 doi: 10.1039/c3ta11114h
7. [7]
  XIN De-Qiong, ZHU Xiao-Hong, HE Xiao-Xing, et al. Chemistry, 2013, 76(4):319-325
8. [8]
  MA Yan-Wen, XIONG Chuan-Yin, HUANG Wen, et al. Chinese J. Inorg. Chem., 2012, 28(3):546-550
9. [9]
  Ariyanto T, Laziz A M, Glsel J, et al. Chem. Eng. J., 2016, 283:676-681 doi: 10.1016/j.cej.2015.08.007
10. [10]
  Nikitin A, Gogotsi Y. Encycl. Nanosci. Nanotechnol., 2004, 7:553-574
11. [11]
  Nijkamp M G, Raaymakers J EM J, van Dillen A J V, et al. Appl. Phys. A, 2001, 72(5):619-623 doi: 10.1007/s003390100847
12. [12]
  Lee S M, Kaneko K. Carbon, 2003, 41(2):374-376 doi: 10.1016/S0008-6223(02)00361-5
13. [13]
  Ariyanto T, Zhang G R, Riyahi F, et al. Carbon, 2017, http://dx.doi.org/10.1016/j.carbon.2017.01.032
14. [14]
  DU Xue-Lian, CONG Ye, JIANG Lu. et al. Acta. Phys.-Chim. Sin., 2015, 31(3):583-588 doi: 10.3866/PKU.WHXB201501212
15. [15]
  Yachamaneni S, Yushin G, Yeon S, et al. Biomaterial, 2010, 31(18):4789-4794 doi: 10.1016/j.biomaterials.2010.02.054
16. [16]
  Dash R K, Nikitin A, Gogotsi Y. Microporous Mesoporous Mater., 2004, 72(s1-3):203-208
17. [17]
  Dash R K, Yushin G, Gogotsi Y. Microporous Mesoporous Mater., 2005, 86(1):50-57
18. [18]
  Hoffman E N, Yushin G N, Barsoum M W, et al. Chem. Mater., 2005, 17(9):2317-2322 doi: 10.1021/cm047739i
19. [19]
  Cheng G, Long D H, Liu X J, et al. Carbon, 2010, 48(3):243-250
20. [20]
  Dyatkin B, Gogotsi O, Malinovskiy B, et al. J. Power Sources, 2016, 306:32-41 doi: 10.1016/j.jpowsour.2015.11.099
21. [21]
  Urbonaite S, Wachtmeister S, Mirguet C, et al. Carbon, 2007, 45(10):2047-2053 doi: 10.1016/j.carbon.2007.05.022
22. [22]
  Kormann M, Gerhard H, Popovska N. Carbon, 2009, 47(1):242-250 doi: 10.1016/j.carbon.2008.10.002
23. [23]
  GENG Shu-Ya, WANG-Chen, DONG Li-Min, et al. Rare Metal Mater. Eng., 2015, 44(1):597-599
24. [24]
  Presser V, Heon M, Gogotsi Y. Adv. Funct. Mater., 2011, 21(5):810-833 doi: 10.1002/adfm.201002094
25. [25]
26. [26]
  JIANG Lu, CONG Ye, DU Xue-Lian, et al. Funct. Mater., 2015, 24(46):24127-24132
27. [27]
  Ariyanto T, Laziz A M, Gläsel J, et al. Chem. Eng. J., 2016, 283:676-681 doi: 10.1016/j.cej.2015.08.007
28. [28]
  ZHANG Yi-Qiang, DONG Zhi-Jun, ZUO Xiao-Hua, et al. J. Wuhan University of Sci. Technol., 2012, 35(4):289-292
29. [29]
  ZHANG Chang-Rui. Ceramic Matrix Composite. Changsha:National University of Defense Technology Press, 2001:278-281
30. [30]
  Saha A, Raj R. J. Am. Ceram. Soc., 2007, 90(2):578-583 doi: 10.1111/jace.2007.90.issue-2
31. [31]
  Ferrari A C, Robertson J. Phys. Rev. B:Condens. Matter, 2000, 61(20):14095-14107 doi: 10.1103/PhysRevB.61.14095
32. [32]
  Ma Y, Wang S, Chen Z. Ceram. Int., 2010, 36(8):2455-2459 doi: 10.1016/j.ceramint.2010.08.003
33. [33]
  Wang Q, Yan J, Fan Z. Energy Environ. Sci., 2015, 9(3):729-762
34. [34]
  Gogotsi Y, Simon P. Science, 2011, 334(6058):917-918 doi: 10.1126/science.1213003
35. [35]
  Yan J, Wang Q, Lin C, et al. Adv. Energy Mater., 2014, 4(13):1294-1305
36. [36]
  Itoi H, Nishihara H, Kogure T, et al. J. Am. Chem. Soc., 2011, 133(133):1165-1167
37. [37]
  Jiang H, Lee P S, Li C Z. Energy Environ. Sci., 2013, 6:41-53 doi: 10.1039/C2EE23284G
38. [38]
  Wang S, Wang T, Liu P, et al. Mater. Res. Bull., 2017, 88:62-68 doi: 10.1016/j.materresbull.2016.11.039
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
6. [6]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
7. [7]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
8. [8]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
9. [9]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
10. [10]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
11. [11]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
12. [12]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
13. [13]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
14. [14]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
15. [15]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
16. [16]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
17. [17]
  Yajun Jian , Quanguo Zhai , Quan Gu , Shengli Gao . Reconstruction and Practice of the Teaching Content of “Carbon Group Elements” in Inorganic Chemistry to Reflect Comprehensive Education Function. University Chemistry, 2024, 39(11): 96-107. doi: 10.12461/PKU.DXHX202403006
18. [18]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
19. [19]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
20. [20]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1072)
HTML views(156)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142