Citation: XIANG Ying-Qiao, LI Tian-Tian, XU Qing-Hong. Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 615-622. doi: 10.11862/CJIC.2017.078 shu

Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: XU Qing-Hong, xuqh@mail.buct.edu.cn
Received Date: 9 December 2016
Revised Date: 9 February 2017

Figures(9)

SiO₂ microspheres with different diameters were prepared by Stober method, and the SiO₂ microspheres were uniformly coated with ZrO₂ by adsorption and hydrolysis of ZrOCl₂. The ZrO₂ hollow microspheres were then obtained after SiO₂ was removed by hydrofluoric acid, and Au@ZrO₂ hollow microspheres were finally prepared by deposition-precipitation (DP) method. Catalytic properties of Au@ZrO₂ hollow microspheres in reduction of paranitroaniline were studied carefully. The research results indicate that the SiO₂ microspheres have regular shape and good dispersity. The sizes and the surface areas of the ZrO₂ hollow microspheres could be controlled effectively by the diameters of SiO₂ microspheres. Compared to the solid microsphere Au@ZrO₂, the Au@ZrO₂ hollow microspheres showed good catalytic performance in reduction of p-nitroaniline, and p-nitroaniline was completely reduced to p-phenylenediamine in 7 min at 45℃.
- Au@ZrO₂ hollow microsphere,
- deposition-precipitation method,
- p-nitroaniline,
- catalysis,
- reduction
1. [1]
  Elmalem E, Saunders A E, Costi R, et al. Adv. Mater., 2008, 20:4312-4317 doi: 10.1002/adma.v20:22
2. [2]
  Zhai C Y, Zhu M S, Pang F Z, et al. ACS Appl. Mater. Interfaces, 2016, 8:5972-5980 doi: 10.1021/acsami.5b10234
3. [3]
  Zhai C Y, Zhu M S, Duan B, et al. J. Power Sources, 2015, 275:483-488 doi: 10.1016/j.jpowsour.2014.11.030
4. [4]
  Zhu M S, Zhai C Y, Sun M J, et al. Appl. Catal. B:Environ., 2017, 203:108-115 doi: 10.1016/j.apcatb.2016.10.012
5. [5]
  Wang X, Perret N, Keane M A. Appl. Catal. A:Gen., 2013, 467:575-584 doi: 10.1016/j.apcata.2013.07.061
6. [6]
  Kuroda K, Ishida T, Haruta M. J. Mol. Catal. A:Chem., 2009, 298(1):7-11
7. [7]
  Ismail A A, Hakki A, Bahnemann D W. J. Mol. Catal. A:Chem., 2012, 358(6):145-151
8. [8]
  Evangelista V, Acosta B, Miridonov S, et al. Appl. Catal. B:Environ., 2015, 166-167:518-528 doi: 10.1016/j.apcatb.2014.12.006
9. [9]
  Zhu J, Zoltan Kónya, Puntus V F, et al. Langmuir, 2003, 19(10):4396-4401
10. [10]
  Tuzovskaya I, Bogdanchikova N, Simakov A, et al. Chem. Phys., 2007, 338(1):23-32 doi: 10.1016/j.chemphys.2007.07.026
11. [11]
  Zanella R, Rodríguezgonzález V, Arzola Y, et al. ACS Catal., 2011, 2(1):1-11
12. [12]
  Smolentseva E, Kusema B T, Beloshapkin S, et al. Appl. Catal. A:Gen., 2011, 392(1/2):69-79
13. [13]
  Sandoval A, Aguilar A, Louis C, et al. J. Catal., 2011, 281(1):40-49 doi: 10.1016/j.jcat.2011.04.003
14. [14]
  WANG Jing, XU Ji-Tai, GONG Nian. Bull. Chinese Ceram. Soc., 2013, 32(5):936-940
15. [15]
  Wang C, Le Y, Cheng B J. Ceram. Int., 2014, 40(7):10847-10856 doi: 10.1016/j.ceramint.2014.03.078
16. [16]
  Xiao M, Li Y G, Lu Y F, et al. J. Mater. Chem. A, 2015, 3(6):2701-2706 doi: 10.1039/C4TA05931J
17. [17]
  Yang X, Zhao N, Zhou Q, et al. J. Mater. Chem. C, 2013, 1(1):3359-3366
18. [18]
  Lin Y F, Liang F L. CrystEngComm, 2015, 17:678-685 doi: 10.1039/C4CE02037E
19. [19]
  Kumar P N. RSC Adv., 2014, 4:29946-29956 doi: 10.1039/C4RA02441A
20. [20]
  YANG Shu-Mei, DENG Shu-Hua, HUANG Hui-Min, et al. Ind. Catal., 2003, 11(10):39-43
21. [21]
  Lin F Q, Dong W S, Liu C L, et al. J. Colloid Interface Sci., 2008, 323(2):365-71 doi: 10.1016/j.jcis.2008.04.030
22. [22]
  JIANG Feng, LI Sa, PENG Zhi-Jian. Bull. Chinese Ceram. Soc., 2014, 42(9):1087-1091
23. [23]
  CHEN Guo-Hong, ZHOU Fang-Ling, LI Qiao-Ling, et al. Chinese J. Inorg. Chem., 2015, 31(11):2181-2187
24. [24]
  WANG Wen-Juan, ZHANG Hai-Peng, HAN Yu-Xiang, et al. Chinese J. Inorg. Chem., 2014, 30(12):2726-2732
25. [25]
  Tahir M N, Ragg R, Natalio F, et al. J. Mater. Chem. B, 2015, 3(11):2371-2377 doi: 10.1039/C4TB01959H
26. [26]
  MA Tian, YANG Jin-Long, ZHANG Li-Ming, et al. Chinese J. Inorg. Chem., 2004, 20(2):121-127
27. [27]
  Guo C, Hu P, Yu L, et al. J. Mater. Lett., 2009, 63(12):1013-1015 doi: 10.1016/j.matlet.2008.12.053
28. [28]
  Jiang Y, Yang S, Ding X, et al. J. Mater. Chem., 2005, 15(20):2041-2046 doi: 10.1039/b415664a
29. [29]
  Kuroda Y, Sakamoto Y, Kuroda K. J. Am. Chem. Soc., 2012, 134(20):8684-8692 doi: 10.1021/ja3026054
30. [30]
  Guo D, Lu Y, Zhao Y, et al. RSC Adv., 2015, 5(16):11738-11744 doi: 10.1039/C4RA16024J
31. [31]
  Zhu S, Xue Y, Guo J, et al. ACS Catal., 2016, 6(3):2035-2042 doi: 10.1021/acscatal.5b02882
32. [32]
  Ma J, Guo S, Guo X, et al. Ceram. Int., 2015, 41(9):705-708
1. [1]
  Guodong Xu , Chengcai Sheng , Xiaomeng Zhao , Tuojiang Zhang , Zongtang Liu , Jun Dong . Reform of Comprehensive Organic Chemistry Experiments in the Context of Emerging Engineering Education: A Case Study on the Improved Preparation of Benzocaine. University Chemistry, 2024, 39(11): 286-295. doi: 10.12461/PKU.DXHX202403094
2. [2]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
3. [3]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
4. [4]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
5. [5]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
8. [8]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
9. [9]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
10. [10]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
11. [11]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
12. [12]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
13. [13]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
14. [14]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
15. [15]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
16. [16]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
17. [17]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
18. [18]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
19. [19]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
20. [20]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(878)
HTML views(143)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Catalytic Properties of Au@ZrO2 Hollow Microspheres

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Catalytic Properties of Au@ZrO₂ Hollow Microspheres