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Citation: GAO Xi-Feng, LIU Jing-Song, YANG Pei-Pei, LIU Yan-Ming, ZHANG Xi-Qi, ZHU Jian-Hua. Syntheses, Crystal Structures and Magnetic Properties of Fe(Ⅲ), Co(Ⅲ) and Mixed Valence Mn(Ⅱ)/Mn(Ⅲ) Complexes Based on a Schiff Base Ligand Derived From Salicylaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 630-636. doi: 10.11862/CJIC.2017.074 shu

Syntheses, Crystal Structures and Magnetic Properties of Fe(Ⅲ), Co(Ⅲ) and Mixed Valence Mn(Ⅱ)/Mn(Ⅲ) Complexes Based on a Schiff Base Ligand Derived From Salicylaldehyde

  • 1.

    Shandong Institute for Food and Drug Control, Jinan 250101, China

  • 2.

    Qilu Pharmaceutical Co., LTD., Jinan 250101, China

  • 3.

    Department of Chemical Engineering, Huaibei Normal University, Huaibei, Anhui 235000, China

Figures(8)

  • The Schiff base hmmpH2 (hmmpH2=2-[(2-hydroxyethylimino) methyl]-6-methoxyphenol) was synthesized by o-vanillin and ethanolamine. Complexes[Fe2(hmmp)2(hmmpH)2]·1.5CH3CN·0.5H2O (1) and[Co2Na ((hmmp)2(N3)2(CH3O)(CH3OH)2] (2) were synthesized by using hmmpH2 ligand. The Schiff base hmdbrpH2 (hmdbrpH2=2-[(2-hydroxyethylimino) methyl]-4, 6-dibromophenol) was synthesized by 3, 5-dibromosalicylaldehyde and ethanolamine. Complex[Mn(Ⅱ) Mn(Ⅲ)2(hmdbrp)2(O2CPh)4(CH3OH)2]·2CH3CN·2CH3OH (3) was synthesized by using hmdbrpH2 ligand. These complexes were fully characterized by elemental analysis and X-ray single crystal diffraction, and complexes 1 and 3 were also studied by magnetic investigation. The structural analysis indicates that in complex 1 two six-coordinated Fe(Ⅲ) ions are bridged by two alcoholic hydroxyl atoms to form a dimer structure. In complex 2, Co(Ⅲ) is six-coordinated with an octahedral coordination environment and the two Co(Ⅲ) ions are bridged by two O atoms from CH3OH constructing a binuclear complex. The complex 3 is a mixed valence trinuclear structure, with three Mn ions in linear array. Magnetic study indicates that the antiferromagnetic interaction exist between Fe(Ⅲ) ions in complex 1, and in complex 3 antiferromagnetic interactions exist between the Mn(Ⅱ) and Mn(Ⅲ) ions in the trinuclear manganese unit.
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  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

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