Citation: ZHAO Hai-Yan, YANG Xiao-Dong, LI Na. Two Ni(Ⅱ) Complexes of Schiff Base Ligands Containing Benzimidazole Ring: Syntheses, Crystal Structures and Antibacterial Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 685-691. doi: 10.11862/CJIC.2017.064 shu

Two Ni(Ⅱ) Complexes of Schiff Base Ligands Containing Benzimidazole Ring: Syntheses, Crystal Structures and Antibacterial Properties

College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, China

Corresponding author: ZHAO Hai-Yan, hbhaiyanzh@163.com
Received Date: 7 November 2016
Revised Date: 4 February 2017

Figures(4)

Two complexes[Ni (L¹)₂]·2H₂O (1) and[Ni (L²)₂]·2H₂O (2) have been synthesized using the bezimidazole derived tridentate (NNO donor) potential Schiff base ligands HL¹ and HL², which are prepared from reaction of 2-aminoethyl-1H-benzimidazole with 5-chlorosalicylaldehyde and 5-bromosalicylaldehyde, respectively, and characterized by elemental analysis, FT-IR and UV-Vis spectroscopies and single crystal X-ray crystallography. In 1 and 2, each Ni(Ⅱ) has a distorted octahedral arrangement with a N₄O₂ donor set in trichelated fashion of the Schiff base ligands. Furthermore, the complex units in 1 and 2 are linked into 2D and 3D supramolecular networks by H-bonding in the solid state, respectively. The bioactivity studies showed that both the two complexes exhibit moderate to strong antibacterial activities against S. aureus (Gram-positive) and E. coli (Gram-negative) bacteria and were found more active than the corresponding Schiff base ligands.
- Schiff base,
- Ni(Ⅱ) complex,
- crystal structure,
- antibacterial activity
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