Citation: ZHAO Feng-Ming, WEN Gang, KONG Li-Yao, CHU You-Qun, MA Chun-An. Electrochemical Performance of Titanium Nitride Nanotubes as Negative Electrode in a Static Vanadium Battery Towards V (Ⅱ)/V (Ⅲ) Redox Couple[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 501-508. doi: 10.11862/CJIC.2017.053 shu

Electrochemical Performance of Titanium Nitride Nanotubes as Negative Electrode in a Static Vanadium Battery Towards V (Ⅱ)/V (Ⅲ) Redox Couple

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310032, China

Corresponding author: MA Chun-An, science@zjut.edu.cn
Received Date: 17 October 2016
Revised Date: 24 December 2016

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In this study, titanium nitride nanotubes (TiN NTs) film is directly prepared on a Ti substrate through anodic oxidation process and subsequent nitridation in ammonia atmosphere. The prepared TiN NTs film is proposed as a novel catalyst towards V (Ⅱ)/V (Ⅲ) redox couple for the negative electrode in a static vanadium redox battery. Scanning electron microscopy (SEM) results confirm that TiN NTs retain its parental morphology of TiO₂ NTs. X-ray diffraction (XRD) pattern show that TiO₂ is transformed into TiN and Ti₂N. X-ray photoelectron spectroscopy (XPS) spectra reveal that the surface of TiN NTs is composed of Ti-N-O, Ti-N, Ti-O chemical states. Electrochemical properties of TiN NTs were characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The higher peak current values and more symmetrical peak shape for V (Ⅱ)/V (Ⅲ) redox couple suggest the excellent electrochemical activity and reversibility of TiN NTs. EIS analysis revealed that the charge and mass transfer processes were accelerated at the TiN NTs electrode interface, which could be ascribed to the large electrochemical real surface area and fast transfer channel.
- titanium nitride nanotube,
- vanadium redox battery,
- V (Ⅱ)/V (Ⅲ),
- electrochemical performance
1. [1]
  Poullikkas A. Renewable Sustainable Energ Rev., 2013, 27: 778-788 doi: 10.1016/j.rser.2013.07.017
2. [2]
  Wang G, Chen J W, Wang X Q, et al. J. Energy Chem., 2014, 23:73-81 doi: 10.1016/S2095-4956(14)60120-0
3. [3]
  Parasuraman A, Lim T M, Menictas C, et al. Electrochim. Acta, 2013, 101:27-40 doi: 10.1016/j.electacta.2012.09.067
4. [4]
  Qian P, Zhang H M, Chen J, et al. J. Power Source, 2008, 175:613-620 doi: 10.1016/j.jpowsour.2007.09.006
5. [5]
  Mayrhuber I, Dennison C R, Kalra V, et al. J. Power Sources, 2014, 260:251-258 doi: 10.1016/j.jpowsour.2014.03.007
6. [6]
  Li B, Gu M, Nie Z M, et al. Nano Lett., 2013, 13:1330-1335 doi: 10.1021/nl400223v
7. [7]
  Yue L, Li W S, Sun F Q, et al. Carbon, 2010, 48:3079-3090 doi: 10.1016/j.carbon.2010.04.044
8. [8]
  Wei G L, Fan X Z, Liu J G, et al. J. Power Sources, 2015, 281:1-6 doi: 10.1016/j.jpowsour.2015.01.161
9. [9]
  Sun C N, Delnick F M, Baggetto L, et al. J. Power Sources, 2014, 248:560-564 doi: 10.1016/j.jpowsour.2013.09.125
10. [10]
  He Z X, Chen Z S, Meng W, et al. J. Energy Chem., 2016, 25:720-726 doi: 10.1016/j.jechem.2016.04.002
11. [11]
  LIU Su-Qin, SHI Xiao-Hu, HUANG Ke-Long, et al. Chinese J. Inorg. Chem., 2008, 24(7):1079-1083
12. [12]
  Men Y, Sun T. Int. J. Electrochem. Sci., 2012, 7:3482-3488
13. [13]
  Wang W H, Wang X D. Electrochim. Acta, 2007, 52:6755-6762 doi: 10.1016/j.electacta.2007.04.121
14. [14]
  Tseng T M, Huang R H, Huang C Y, et al. J. Electrochem. Soc., 2013, 160(8):A1269-A1275 doi: 10.1149/2.082308jes
15. [15]
  Yao C, Zhang H M, Liu T, et al. J. Power Sources, 2012, 218:455-461 doi: 10.1016/j.jpowsour.2012.06.072
16. [16]
  He Z X, Dai L, Liu S Q, et al. Electrochim. Acta, 2015, 176: 1434-1440 doi: 10.1016/j.electacta.2015.07.067
17. [17]
  Wu X X, Xu H F, Lu L. J. Power Sources, 2014, 250:274-278 doi: 10.1016/j.jpowsour.2013.11.021
18. [18]
  He Z X, He Y Y, Chen C, et al. Ionics, 2014, 20:949-955 doi: 10.1007/s11581-013-1051-6
19. [19]
  Liu H J, Xu Q, Yan C W, et al. Electrochim. Acta, 2011, 56: 8783-8790 doi: 10.1016/j.electacta.2011.07.083
20. [20]
  Shen J X, Liu S Q, He Z, et al. Electrochim. Acta, 2015, 151:297-305 doi: 10.1016/j.electacta.2014.11.060
21. [21]
  Kaskel S, Schlichte K, Kratzke T. J. Mol. Catal. A-Chem., 2004, 208:291-298 doi: 10.1016/S1381-1169(03)00545-4
22. [22]
  Lemme M C, Efavi J K, Mollenhauer T, et al. Microelectron. Eng., 2006, 83:1551-1554 doi: 10.1016/j.mee.2006.01.161
23. [23]
  Ponon N K, Appleby D J R, Arac E, et al. Thin Solid Films, 2015, 578:31-37 doi: 10.1016/j.tsf.2015.02.009
24. [24]
  Yazdani A, Soltanieh M, Aghajani H, et al. Vacuum, 2011, 86:131-139 doi: 10.1016/j.vacuum.2011.04.020
25. [25]
  Ningthoujam R S, Gajbhiye N S. Prog. Mater. Sci., 2015, 70: 50-154 doi: 10.1016/j.pmatsci.2014.11.004
26. [26]
  Kakinuma K, Wakasugi Y, Uchida M, et al. Electrochim. Acta, 2012, 77:279-284 doi: 10.1016/j.electacta.2012.06.001
27. [27]
  Wang G Q, Liu S M. Mater. Lett., 2015, 161:294-296 doi: 10.1016/j.matlet.2015.08.110
28. [28]
  Xie Y B, Fang X Q. Electrochim. Acta, 2014, 120:273-283 doi: 10.1016/j.electacta.2013.12.103
29. [29]
  Yang C M, Wang H N, Lu S F, et al. Electrochim. Acta, 2015, 182:834-840 doi: 10.1016/j.electacta.2015.09.155
30. [30]
  Kumar K K, Raole P M, Rayjada P A, et al. Surf. Coat. Technol., 2011, 205:S187-S191 doi: 10.1016/j.surfcoat.2011.04.093
31. [31]
  Yu H J, Tan T Y, Wu W, et al. Curr. Appl. Phys., 2012, 12: 152-154 doi: 10.1016/j.cap.2011.05.025
32. [32]
  Peng X, Huo K F, Fu J J, et al. Chem. Commun., 2013, 49: 10172-10174 doi: 10.1039/c3cc45997g
33. [33]
  Lu X H, Wang G M, Zhai T, et al. Nano Lett., 2012, 12: 5376-5381 doi: 10.1021/nl302761z
34. [34]
  Balogun M S, Yu M H, Li C, et al. J. Mater. Chem. A, 2014, 2:10825-10829 doi: 10.1039/c4ta00987h
35. [35]
  Han Y J, Yue X, Jin Y S, et al. J. Mater. Chem. A, 2016, 4: 3673-3677 doi: 10.1039/C5TA09976E
36. [36]
  Chan M H, Lu F H. Thin Solid Films, 2009, 517:5006-5009 doi: 10.1016/j.tsf.2009.03.100
37. [37]
  Zhao F M, Yan F, Qian Y, et al. J. Electroanal. Chem., 2013, 698:31-38 doi: 10.1016/j.jelechem.2013.03.014
38. [38]
  HUANG Fei, WANG Gui-Xin, YAN Kang-Ping, et al. Chinese J. Inorg. Chem., 2012, 28(5):898-904
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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