Citation: ZHAO Feng-Ming, WEN Gang, KONG Li-Yao, CHU You-Qun, MA Chun-An. Electrochemical Performance of Titanium Nitride Nanotubes as Negative Electrode in a Static Vanadium Battery Towards V (Ⅱ)/V (Ⅲ) Redox Couple[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 501-508. doi: 10.11862/CJIC.2017.053 shu

Electrochemical Performance of Titanium Nitride Nanotubes as Negative Electrode in a Static Vanadium Battery Towards V (Ⅱ)/V (Ⅲ) Redox Couple

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310032, China

Corresponding author: MA Chun-An, science@zjut.edu.cn
Received Date: 17 October 2016
Revised Date: 24 December 2016

Figures(7)

In this study, titanium nitride nanotubes (TiN NTs) film is directly prepared on a Ti substrate through anodic oxidation process and subsequent nitridation in ammonia atmosphere. The prepared TiN NTs film is proposed as a novel catalyst towards V (Ⅱ)/V (Ⅲ) redox couple for the negative electrode in a static vanadium redox battery. Scanning electron microscopy (SEM) results confirm that TiN NTs retain its parental morphology of TiO₂ NTs. X-ray diffraction (XRD) pattern show that TiO₂ is transformed into TiN and Ti₂N. X-ray photoelectron spectroscopy (XPS) spectra reveal that the surface of TiN NTs is composed of Ti-N-O, Ti-N, Ti-O chemical states. Electrochemical properties of TiN NTs were characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The higher peak current values and more symmetrical peak shape for V (Ⅱ)/V (Ⅲ) redox couple suggest the excellent electrochemical activity and reversibility of TiN NTs. EIS analysis revealed that the charge and mass transfer processes were accelerated at the TiN NTs electrode interface, which could be ascribed to the large electrochemical real surface area and fast transfer channel.
- titanium nitride nanotube,
- vanadium redox battery,
- V (Ⅱ)/V (Ⅲ),
- electrochemical performance
1. [1]
  Poullikkas A. Renewable Sustainable Energ Rev., 2013, 27: 778-788 doi: 10.1016/j.rser.2013.07.017
2. [2]
  Wang G, Chen J W, Wang X Q, et al. J. Energy Chem., 2014, 23:73-81 doi: 10.1016/S2095-4956(14)60120-0
3. [3]
  Parasuraman A, Lim T M, Menictas C, et al. Electrochim. Acta, 2013, 101:27-40 doi: 10.1016/j.electacta.2012.09.067
4. [4]
  Qian P, Zhang H M, Chen J, et al. J. Power Source, 2008, 175:613-620 doi: 10.1016/j.jpowsour.2007.09.006
5. [5]
  Mayrhuber I, Dennison C R, Kalra V, et al. J. Power Sources, 2014, 260:251-258 doi: 10.1016/j.jpowsour.2014.03.007
6. [6]
  Li B, Gu M, Nie Z M, et al. Nano Lett., 2013, 13:1330-1335 doi: 10.1021/nl400223v
7. [7]
  Yue L, Li W S, Sun F Q, et al. Carbon, 2010, 48:3079-3090 doi: 10.1016/j.carbon.2010.04.044
8. [8]
  Wei G L, Fan X Z, Liu J G, et al. J. Power Sources, 2015, 281:1-6 doi: 10.1016/j.jpowsour.2015.01.161
9. [9]
  Sun C N, Delnick F M, Baggetto L, et al. J. Power Sources, 2014, 248:560-564 doi: 10.1016/j.jpowsour.2013.09.125
10. [10]
  He Z X, Chen Z S, Meng W, et al. J. Energy Chem., 2016, 25:720-726 doi: 10.1016/j.jechem.2016.04.002
11. [11]
  LIU Su-Qin, SHI Xiao-Hu, HUANG Ke-Long, et al. Chinese J. Inorg. Chem., 2008, 24(7):1079-1083
12. [12]
  Men Y, Sun T. Int. J. Electrochem. Sci., 2012, 7:3482-3488
13. [13]
  Wang W H, Wang X D. Electrochim. Acta, 2007, 52:6755-6762 doi: 10.1016/j.electacta.2007.04.121
14. [14]
  Tseng T M, Huang R H, Huang C Y, et al. J. Electrochem. Soc., 2013, 160(8):A1269-A1275 doi: 10.1149/2.082308jes
15. [15]
  Yao C, Zhang H M, Liu T, et al. J. Power Sources, 2012, 218:455-461 doi: 10.1016/j.jpowsour.2012.06.072
16. [16]
  He Z X, Dai L, Liu S Q, et al. Electrochim. Acta, 2015, 176: 1434-1440 doi: 10.1016/j.electacta.2015.07.067
17. [17]
  Wu X X, Xu H F, Lu L. J. Power Sources, 2014, 250:274-278 doi: 10.1016/j.jpowsour.2013.11.021
18. [18]
  He Z X, He Y Y, Chen C, et al. Ionics, 2014, 20:949-955 doi: 10.1007/s11581-013-1051-6
19. [19]
  Liu H J, Xu Q, Yan C W, et al. Electrochim. Acta, 2011, 56: 8783-8790 doi: 10.1016/j.electacta.2011.07.083
20. [20]
  Shen J X, Liu S Q, He Z, et al. Electrochim. Acta, 2015, 151:297-305 doi: 10.1016/j.electacta.2014.11.060
21. [21]
  Kaskel S, Schlichte K, Kratzke T. J. Mol. Catal. A-Chem., 2004, 208:291-298 doi: 10.1016/S1381-1169(03)00545-4
22. [22]
  Lemme M C, Efavi J K, Mollenhauer T, et al. Microelectron. Eng., 2006, 83:1551-1554 doi: 10.1016/j.mee.2006.01.161
23. [23]
  Ponon N K, Appleby D J R, Arac E, et al. Thin Solid Films, 2015, 578:31-37 doi: 10.1016/j.tsf.2015.02.009
24. [24]
  Yazdani A, Soltanieh M, Aghajani H, et al. Vacuum, 2011, 86:131-139 doi: 10.1016/j.vacuum.2011.04.020
25. [25]
  Ningthoujam R S, Gajbhiye N S. Prog. Mater. Sci., 2015, 70: 50-154 doi: 10.1016/j.pmatsci.2014.11.004
26. [26]
  Kakinuma K, Wakasugi Y, Uchida M, et al. Electrochim. Acta, 2012, 77:279-284 doi: 10.1016/j.electacta.2012.06.001
27. [27]
  Wang G Q, Liu S M. Mater. Lett., 2015, 161:294-296 doi: 10.1016/j.matlet.2015.08.110
28. [28]
  Xie Y B, Fang X Q. Electrochim. Acta, 2014, 120:273-283 doi: 10.1016/j.electacta.2013.12.103
29. [29]
  Yang C M, Wang H N, Lu S F, et al. Electrochim. Acta, 2015, 182:834-840 doi: 10.1016/j.electacta.2015.09.155
30. [30]
  Kumar K K, Raole P M, Rayjada P A, et al. Surf. Coat. Technol., 2011, 205:S187-S191 doi: 10.1016/j.surfcoat.2011.04.093
31. [31]
  Yu H J, Tan T Y, Wu W, et al. Curr. Appl. Phys., 2012, 12: 152-154 doi: 10.1016/j.cap.2011.05.025
32. [32]
  Peng X, Huo K F, Fu J J, et al. Chem. Commun., 2013, 49: 10172-10174 doi: 10.1039/c3cc45997g
33. [33]
  Lu X H, Wang G M, Zhai T, et al. Nano Lett., 2012, 12: 5376-5381 doi: 10.1021/nl302761z
34. [34]
  Balogun M S, Yu M H, Li C, et al. J. Mater. Chem. A, 2014, 2:10825-10829 doi: 10.1039/c4ta00987h
35. [35]
  Han Y J, Yue X, Jin Y S, et al. J. Mater. Chem. A, 2016, 4: 3673-3677 doi: 10.1039/C5TA09976E
36. [36]
  Chan M H, Lu F H. Thin Solid Films, 2009, 517:5006-5009 doi: 10.1016/j.tsf.2009.03.100
37. [37]
  Zhao F M, Yan F, Qian Y, et al. J. Electroanal. Chem., 2013, 698:31-38 doi: 10.1016/j.jelechem.2013.03.014
38. [38]
  HUANG Fei, WANG Gui-Xin, YAN Kang-Ping, et al. Chinese J. Inorg. Chem., 2012, 28(5):898-904
1. [1]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
2. [2]
  Haohao Sun , Wenxuan Wang , Yuli Xiong , Zelang Jian , Wen Chen . Boosting the electrochromic properties by large V₂O₅ nanobelts interlayer spacing tuned via PEDOT. Chinese Chemical Letters, 2024, 35(9): 109213-. doi: 10.1016/j.cclet.2023.109213
3. [3]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
4. [4]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
5. [5]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
6. [6]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
7. [7]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
8. [8]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
9. [9]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
10. [10]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
11. [11]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
12. [12]
  Tsegaye Tadesse Tsega , Jiantao Zai , Chin Wei Lai , Xin-Hao Li , Xuefeng Qian . Earth-abundant CuFeS2 nanocrystals@graphite felt electrode for high performance aqueous polysulfide/iodide redox flow batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100192-100192. doi: 10.1016/j.cjsc.2023.100192
13. [13]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
14. [14]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
15. [15]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
16. [16]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
17. [17]
  Jiqing Liu , Qi Dang , Liting Wang , Dejin Wang , Liang Tang . Applications of flexible electrochemical electrodes in wastewater treatment: A review. Chinese Chemical Letters, 2024, 35(8): 109277-. doi: 10.1016/j.cclet.2023.109277
18. [18]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
19. [19]
  Feng Cui , Fangman Chen , Xiaochun Xie , Chenyang Guo , Kai Xiao , Ziping Wu , Yinglu Chen , Junna Lu , Feixia Ruan , Chuanxu Cheng , Chao Yang , Dan Shao . Scalable production of mesoporous titanium nanoparticles through sequential flash nanocomplexation. Chinese Chemical Letters, 2024, 35(4): 108681-. doi: 10.1016/j.cclet.2023.108681
20. [20]
  Haijing Cui , Weihao Zhu , Chuning Yue , Ming Yang , Wenzhi Ren , Aiguo Wu . Recent progress of ultrasound-responsive titanium dioxide sonosensitizers in cancer treatment. Chinese Chemical Letters, 2024, 35(10): 109727-. doi: 10.1016/j.cclet.2024.109727

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(946)
HTML views(147)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142