Citation: WANG Ying, MI Kan, XIONG Sheng-Lin. Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 243-248. doi: 10.11862/CJIC.2017.048 shu

Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries

1.
Shandong Yuhuang New Energy Technology Co., LTD, Heze, Shandong 274000, China
2.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China

Corresponding author: XIONG Sheng-Lin, chexsl@sdu.edu.cn
Received Date: 1 September 2016
Revised Date: 17 November 2016

Figures(5)

Uniform Mn₂O₃ hollow spheres were synthesized by using carbon spheres as the hard template and were used as holder for Li-S batteries. The Mn₂O₃-S composites showed a high specific capacity, good cycling stability and rate performance. The final reversible capacity can remain at 657 mA·g^-1 after 100 cycles at the current density of 0.9 A·g^-1 with the 51% sulfur loading, which demonstrates that Mn₂O₃ hollow spheres could be a promising matrix for Li-S batteries.
- electrochemistry,
- hollow spheres,
- manganic oxide,
- Li-S batteries
1. [1]
  Chen L, Shaw L L. J. Power Sources., 2014, 267:770-783 doi: 10.1016/j.jpowsour.2014.05.111
2. [2]
  ZHOU Lan, YU Ai-Shui. J. Electrochem., 2015, 21(3):211-220
3. [3]
  Lin Z, Liang C. J. Mater. Chem. A, 2015, 3:936-958 doi: 10.1039/C4TA04727C
4. [4]
  Manthiram A, Fu Y, Chung, et al. Chem. Rev., 2014, 114:11751-11787 doi: 10.1021/cr500062v
5. [5]
  Pope M A, Aksay I A. Adv. Energy Mater., 2015, 5:1500124 doi: 10.1002/aenm.201500124
6. [6]
  DIAO Yan, XIE Kai, HONG Xiao-Bin, et al. Acta Chim. Sinica, 2013, 7(4):508-548
7. [7]
  WAN Wen-Bao, PU Wei-Hua. Prog. Chem., 2013, 25(11):1830-1841
8. [8]
  He G, Evers S, Liang, et al. ACS Nano, 2013, 7:10920-10930 doi: 10.1021/nn404439r
9. [9]
  Jayaprakash N, Shen J, Moganty S S, et al. Angew Chem. Int. Ed., 2011, 50:5904-5908 doi: 10.1002/anie.v50.26
10. [10]
  Qu Y, Zhang Z, Wang, et al. J. Mater. Chem. A, 2013, 1:14306 doi: 10.1039/c3ta13306k
11. [11]
  Jung D S, Hwang T H, Lee, et al. Nano Lett., 2014, 14:4418-4425 doi: 10.1021/nl501383g
12. [12]
  Wang M, Zhang H, Wang, et al. ACS Appl. Mater. Interfaces, 2015, 7:3590-3599 doi: 10.1021/am5075562
13. [13]
  徐晶晶, 李斌, 李松梅, 等.无机化学学报, 2015, 31(10):2030-2036
14. [14]
  Mi K, Jiang Y, Feng J, et al. Adv. Funct. Mater., 2016, 26:1571-1579 doi: 10.1002/adfm.v26.10
15. [15]
  Ahn W, Lee D U, Song, et al. RSC Adv., 2015, 5:29370-29374 doi: 10.1039/C5RA02548F
16. [16]
  Duan X, Han Y, Huang L W, et al. J. Mater. Chem. A, 2015, 3:8015-8021 doi: 10.1039/C4TA06097K
17. [17]
  MAO Yan, ZHANG Chuan-Hui, ZHANG Yang, et al. Chinese J. Inorg. Chem., 2013, 29(5):889-895
18. [18]
  Li J, Ding B, Xu G, et al. Nanoscale, 2013, 5:5743-5746 doi: 10.1039/c3nr01393f
19. [19]
  Wei S Z, Li W Y, Cha J J, et al. Nat. Commun., 2013, 4:1331 doi: 10.1038/ncomms2327
20. [20]
  Choi Y J, Jung B S, Lee, et al. B. Phys. Scr., 2007, T129:62-65 doi: 10.1088/0031-8949/2007/T129/014
21. [21]
  Li W, Hicks-Garner J, Wang J, et al. Chem. Mater., 2014, 26:3403-3410 doi: 10.1021/cm500575q
22. [22]
  Liang X, Hart C, Pang Q, et al. Nat. Commun., 2015, 6:5682 doi: 10.1038/ncomms6682
23. [23]
  Wang X, Li G, Li J, et al. Energy Environ. Sci., 2016, 9:2533-2538 doi: 10.1039/C6EE00194G
24. [24]
  Sun X, Li Y. Angew. Chem. Int. Ed., 2004, 43:597-601 doi: 10.1002/(ISSN)1521-3773
25. [25]
  Bongu C S, Karuppiah S, Nallathamby K, et al. J. Mater. Chem. A, 2015, 3:23981-23989 doi: 10.1039/C5TA07876H
26. [26]
  Kolathodi M S, Rao S N H, Natarajan T S, et al. J. Mater. Chem. A, 2016, 4:7883-7891 doi: 10.1039/C6TA01948J
1. [1]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
2. [2]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
3. [3]
  Long Li , Kang Yang , Chenpeng Xi , Mengchao Li , Borong Li , Gui Xu , Yuanbin Xiao , Xiancai Cui , Zhiliang Liu , Lingyun Li , Yan Yu , Chengkai Yang . Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries. Chinese Chemical Letters, 2024, 35(6): 108814-. doi: 10.1016/j.cclet.2023.108814
4. [4]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
5. [5]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
6. [6]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
7. [7]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
8. [8]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
9. [9]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
10. [10]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
11. [11]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
12. [12]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
13. [13]
  Zhenqiang Guo , Huicong Yang , Qian Wei , Shengjun Xu , Guangjian Hu , Shuo Bai , Feng Li . Dual-additives enable stable electrode-electrolyte interfaces for long life Li-SPAN batteries. Chinese Chemical Letters, 2024, 35(5): 108622-. doi: 10.1016/j.cclet.2023.108622
14. [14]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
15. [15]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
16. [16]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390
17. [17]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
18. [18]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
19. [19]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
20. [20]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(636)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Immobilizing Sulfur in Mn2O3 Hollow Spheres for Lithium-Sulfur Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Immobilizing Sulfur in Mn₂O₃ Hollow Spheres for Lithium-Sulfur Batteries