Citation: LI Zhi-Hua, LIU Hong, SONG Ling-Yong, HUANG Tian-Hui. Synthesis of Dual-Metal Functionalized MOF-74 and its Adsorption Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 237-242. doi: 10.11862/CJIC.2017.042 shu

Synthesis of Dual-Metal Functionalized MOF-74 and its Adsorption Properties

Technology Center, China Tobacco Guangxi Industrial Co., Ltd., Nanning 530001, China

Corresponding author: HUANG Tian-Hui, thhuang_guangxi@163.com
Received Date: 10 August 2016
Revised Date: 3 December 2016

Figures(4)

Dual-metal incorporated MOF-74 network structure was prepared by one-pot synthesis with Mn (Ⅱ)and Co (Ⅱ)uniformly distributed in the metal sites of the inorganic building blocks. The resulting frameworks functionalized by two kinds of metal ions with various ratios retain the same structure and channel compared to the single-metal MOF-74. Co (Ⅱ)coordinates with the linker and crystallizes faster than Mn (Ⅱ), resulting in higher ratio of Co (Ⅱ)in the crystals compared to the precursor solutions. Furthermore, incorporating two metals with distinct ion sizes have introduced more local defects in the single crystals, contributing to the porosity enhancement of 10% compared to the single-metal MOF-74.
- metal-organic framework,
- gas adsorption,
- crystal engineering,
- dual-metal structure,
- functionalization
1. [1]
  Li H, Eddaoudi M, O'Keeffe M, et al. Nature, 1999, 402(6759):276-279 doi: 10.1038/46248
2. [2]
  Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004, 43(18):2334-2375 doi: 10.1002/(ISSN)1521-3773
3. [3]
  Ferey G. Chem. Soc. Rev., 2008, 37(1):191-214 doi: 10.1039/B618320B
4. [4]
  Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112(2):1001-1033 doi: 10.1021/cr200139g
5. [5]
  Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009, 38(5):1477-1504 doi: 10.1039/b802426j
6. [6]
  Lee J Y, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38(5):1450-1459 doi: 10.1039/b807080f
7. [7]
  WANG Lei, GU Xiao-Min, YE Dan-Dan, et al. Chinese J. Inorg. Chem., 2016, 32(4):691-698 doi: 10.11862/CJIC.2016.054
8. [8]
  Burrows A D. CrystEngComm, 2011, 13(11):3623-3642 doi: 10.1039/c0ce00568a
9. [9]
  Brozek C K, Dinc M. Chem. Sci., 2012, 3(6):2110-2113 doi: 10.1039/c2sc20306e
10. [10]
  Fei H, Cahill J F, Prather K A, et al. Inorg. Chem., 2013, 52(7):4011-4016 doi: 10.1021/ic400048g
11. [11]
  Fu H, Xu Z X, Zhang J. Chem. Mater., 2015, 27(1):205-210 doi: 10.1021/cm503767r
12. [12]
  Yang H, He X W, Wang F, et al. J. Mater. Chem., 2012, 22(41):21849-21851 doi: 10.1039/c2jm35602c
13. [13]
  Botas J A, Calleja G, Sánchez-Sánchez M, et al. Langmuir, 2010, 26(8):5300-5303 doi: 10.1021/la100423a
14. [14]
  YANG Dai-Shen, XU Li-Hua, CHEN Hui, et al. Chinese J. Inorg. Chem., 2015, 31(3):565-570
15. [15]
  Das S, Kim H, Kim K. J. Am. Chem. Soc., 2009, 131(11):3814-3815 doi: 10.1021/ja808995d
16. [16]
  Kim M, Cahill J F, Fei H, et al. J. Am. Chem. Soc., 2012, 134(43):18082-18088 doi: 10.1021/ja3079219
17. [17]
  BAI Ya-Dong, ZHENG Jia-Jun, FAN Bin-Bin. Chinese J. Inorg. Chem., 2015, 31(8):1505-1510
18. [18]
  Zeng M H, Wang B, Wang X Y, et al. Inorg. Chem., 2006, 45(18):7069-7076 doi: 10.1021/ic060520g
19. [19]
  Cui Y, Xu H, Yue Y, et al. J. Am. Chem. Soc., 2012, 134(9):3979-3982 doi: 10.1021/ja2108036
20. [20]
  Dietzel P D C, Morita Y, Blom R, et al. Angew. Chem. Int. Ed., 2005, 44(39):6354-6358 doi: 10.1002/(ISSN)1521-3773
21. [21]
  Rosi N L, Kim J, Eddaoudi M, et al. J. Am. Chem. Soc., 2005, 127(5):1504-1518 doi: 10.1021/ja045123o
22. [22]
  Wang L J, Deng H, Furukawa H, et al. Inorg. Chem., 2014, 53(12):5881-5883 doi: 10.1021/ic500434a
23. [23]
  Sun D, Sun F, Deng X, et al. Inorg. Chem., 2015, 54(17):8639-8643 doi: 10.1021/acs.inorgchem.5b01278
24. [24]
  Chen S, Xue M, Li Y, et al. J. Mater. Chem. A, 2015, 3(40):20145-20152 doi: 10.1039/C5TA02557E
25. [25]
  Wu D, Guo Z, Yin X, et al. Adv. Mater., 2014, 26(20):3258-3262 doi: 10.1002/adma.v26.20
26. [26]
  Deng H, Doonan C J, Furukawa H, et al. Science, 2010, 327(5967):846-850 doi: 10.1126/science.1181761
27. [27]
  Zhang Y B, Furukawa H, Ko N, et al. J. Am. Chem. Soc., 2015, 137(7):2641-2650 doi: 10.1021/ja512311a
28. [28]
  Barin G, Krungleviciute V, Gutov O, et al. Inorg. Chem., 2014, 53(13):6914-6919 doi: 10.1021/ic500722n
29. [29]
  Wu H, Chua Y S, Krungleviciute V, et al. J. Am. Chem. Soc., 2014, 135(28):10525-10532
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