Citation: CHEN Xiao, LI Yi-Ming, LIU Xiao-Jun, HE Yun-Qiu. Structures and Properties of Sb-Doped ZTO Transparent Conducting Films[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 435-445. doi: 10.11862/CJIC.2017.039 shu

Structures and Properties of Sb-Doped ZTO Transparent Conducting Films

CHEN Xiao ¹ ,
LI Yi-Ming ¹ ,
LIU Xiao-Jun ¹ ,
HE Yun-Qiu ^1,2,*,,

1.
School of Material Science and Engineering, Tongji University, Shanghai 201804, China
2.
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China

Corresponding author: HE Yun-Qiu, heyunqiu@tongji.edu.cn
Received Date: 15 September 2016
Revised Date: 21 December 2016

Figures(6)

Sb-doped ZTO (ZnSnO₃) transparent conducting films were synthesized by sol-gel spin-coating method. The structures and properties of Sb-doped ZTO films were characterized by XRD, SEM, XPS, UV-Vis and Hall effect measurements. Three Sb-doping methods, including the substitution of either Zn²⁺ or Sn⁴⁺, or both the two ions in ZnSnO₃ were adopted. The crystalline features, the lattice positions of Sb ion and the ratios of Sb⁵⁺ and Sb³⁺ in Sb-doped ZTO films prepared by different substitution methods were investigated. Followed by a comprehensive comparison of the amount of oxygen vacancy (V_O^··), interstitial zinc (Zn_i^··) and stannous ion (Sn_Sn″), the effects of Sb-doping concentrations on the crystal structure, the defects, and the electrical properties of the films in different methods were detected. Experimental results indicated that the perovskite structure of the ZnSnO₃ crystal has not been disturbed by Sb-doping. Moreover, the Sb ions successfully occupied the corresponding positions of the ZnSnO₃ lattice as expected, with varying molar ratios (n_Sb⁵⁺/n_Sb³⁺) among the methods. That is, the n_Sb⁵⁺/n_Sb³⁺ decreased with the increase of the doping concentration. It has been concluded that the carrier concentrations and mobility were influenced by both the substitution methods and the Sb-doping concentrations, resulting in the variation of the conductivity of the films. Among all films, the Sb_0.15Zn_0.35Sn_0.5O_1.5 film obtained a minimum resistivity of 0.423 Ω·cm. Finally, the transmittance of all the as-prepared films were higher than 78% within the 350~800 nm range being demonstrated.
- Sb-doping,
- ZTO films,
- sol-gel,
- defects,
- transparent,
- conductivity
1. [1]
  LI Shi-Tao, QIAO Xue-Liang, CHEN Jian-Guo. Laser Optoelectron. Prog., 2004, 40:53-59
2. [2]
3. [3]
  Hosono H, Kikuchi N, Ueda N, et al. J. Non-Cryst. Solids, 1996, 198:165-169
4. [4]
  Hosono H, Yasukawa M, Kawazoe H. J. Non-Cryst. Solids, 1996, 203:334-344 doi: 10.1016/0022-3093(96)00367-5
5. [5]
  Coutts T J, Young D L, Li X. MRS Bull., 2000, 25:58-65 doi: 10.1557/mrs2000.152
6. [6]
  Coutts T J, Young D L, Li X, et al. J. Vac. Sci. Technol. A, 2000, 18:2646-2660
7. [7]
  Ko J, Kim I, Kim D, et al. Appl. Surf. Sci., 2007, 253:7398-7403 doi: 10.1016/j.apsusc.2007.03.036
8. [8]
  Palmer G, Poeppelmeier K, Mason T. Chem. Mater., 1997, 9: 3121-3126 doi: 10.1021/cm9704037
9. [9]
  Perkins J, Del Cueto J, Alleman J, et al. Thin Solid Films, 2002, 411:152-160 doi: 10.1016/S0040-6090(02)00205-5
10. [10]
  HUANG Shu-Lai, MA-Jin, LIU Xiao-Mei, et al. J. Semicond., 2004, 25:56-59 doi: 10.3321/j.issn:0253-4177.2004.01.011
11. [11]
  Jeong Y, Song K, Jun T, et al. Thin Solid Films, 2011, 519: 6164-6168 doi: 10.1016/j.tsf.2011.04.030
12. [12]
  Palmer G, Poeppelmeier K, Mason T. J. Solid State Chem., 1997, 134:192-197 doi: 10.1006/jssc.1997.7576
13. [13]
  Kammler D, Mason T, Young D, et al. J. Appl. Phys., 2001, 90:5979-5985 doi: 10.1063/1.1410882
14. [14]
  Minami T, Sonohara H, Takata S, et al. Jpn. J. Appl. Phys., 1994, 33, L1693-L1696 doi: 10.1143/JJAP.33.L1693
15. [15]
  Minami T, Suzuki S, Miyata T. MRS Proc., doi:10.1557/PROC-666-F1.3,2001.
16. [16]
  Fu X, Clark L A, Yang Q, et al. Environ. Sci. Technol., 1996, 30:647-653 doi: 10.1021/es950391v
17. [17]
  Jain V K, Kumar P, Kumar M, et al. J. Alloys Compd., 2011, 509:3541-3546 doi: 10.1016/j.jallcom.2010.10.212
18. [18]
  Minami T. MRS Bull., 2000, 25:38-44
19. [19]
  JI Ling-Li, HE Yun-Qiu, SUN Fang-Fang. J. Mater. Sci. Eng., 2012, 30(1):63-70
20. [20]
  JI Ling-Li, HE Yun-Qiu, LI Le. Chinese J. Inorg. Chem., 2012, 28(3):437-444
21. [21]
  CHU Xiao-Fei, HE Yun-Qiu, LI Yi-Ming, et al. Chinese J. Inorg. Chem., 2014, 30(5):1212-1220
22. [22]
  Cai S Q, Li Y M, Chen X, et al. J. Mater. Sci.-Mater. Electron., 2016, 27, 6166-6174 doi: 10.1007/s10854-016-4544-z
23. [23]
  Terrier C, Chatelon J P, Berjoan R, et al. Thin Solid Films, 1995, 263(1):37-41 doi: 10.1016/0040-6090(95)06543-1
24. [24]
  Wang Y, Mu Q, Wang G, et al. Sens. Actuators B, 2010, 145(2):847-853 doi: 10.1016/j.snb.2010.01.070
25. [25]
  Kwoka M, Ottaviano L, Passacantando M, et al. Thin Solid Films, 2005, 490:36-42 doi: 10.1016/j.tsf.2005.04.014
26. [26]
  Fan J C., Goodenough J B. J. Appl. Phys., 1977, 48(8):3524-3531 doi: 10.1063/1.324149
27. [27]
  Biswas P K, De A, Dua L K, et al. Bull. Mater. Sci., 2006, 29(3):323-330
28. [28]
  Mar R W. J. Phys. Chem. Solids, 1972, 33(1):220-223 doi: 10.1016/S0022-3697(72)80071-4
29. [29]
  Uematsu K, Mizutani N, Kato M. J. Mater. Sci., 1987, 22(3): 915-918 doi: 10.1007/BF01103529
30. [30]
  YU Li, ZHENG Guang, HE Kai-Hua, et al. Acta Phys.-Chim. Sin., 2010, 26(3): 763-768
31. [31]
  Rim Y S, Kim D L, Jeong W H, et al. Appl. Phys. Lett., 2010, 97(23):233502(3 pages)
32. [32]
  GUO Rui, ZHANG Hua-Li. Sci. Technol. Eng., 2007, 7(3):360-363
33. [33]
  YANG Jian-Guang, TANG Mo-Tang, YANG Sheng-Hai, et al. Mater. Rev., 2004, 18(3):17-20
34. [34]
  SHI Xiao-Hui, XU Ke-Jing, XI Jin-Tao, et al. J. Shandong University of Technology:Nat. Sci. Ed., 2016, 30(4): 66-69
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