Citation: LIU Zan, LIU Ying-Ying, CHENG Zhi-Lin. HNTs-Templated Preparation of Carbon Nanorods by Hydrothermal Nanocasting Method[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 679-684. doi: 10.11862/CJIC.2017.032 shu

HNTs-Templated Preparation of Carbon Nanorods by Hydrothermal Nanocasting Method

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Corresponding author: CHENG Zhi-Lin, zlcheng224@126.com
Received Date: 19 October 2016
Revised Date: 6 December 2016

Figures(6)

A novel method to prepare carbon nanorods through hydrothermal nanocasting method was presented using halloysite nanotubes (HNTs) as the template and polyvinyl alcohol (PVA) as the carbon source. This method involved in three steps, i.e. nanocasting PVA in HNTs, carbonization and etching removal of template. A series of characterization, such as XRD, FT-IR, SEM, TEM, Raman, XPS, SAED and N₂ adsorption-desorption were used to detect the formation and structure of the as-prepared carbon nanorods (CNRs). The CNRs with a 1D rod-like structure were of high specific surface area (408 m²·g^-1) and possessed typical mesoporous characterization.
- carbon materials,
- nanorods,
- halloysite nanotubes,
- nanocasting
1. [1]
  Patsalas P. Thin Solid Films, 2011, 519:3990-3996 doi: 10.1016/j.tsf.2011.01.202
2. [2]
  Wang J, Chen Y, Zhang Y, et al. J. Mater. Chem., 2011, 21:18195-18198 doi: 10.1039/c1jm13796d
3. [3]
  Fan Y R, Zhao Z B, Zhou Q, et al. Carbon, 2013, 58:128-133 doi: 10.1016/j.carbon.2013.02.040
4. [4]
  Liu Y Q, Hu W P, Wang X B, et al. Chem. Phys. Lett., 2000, 331:31-34 doi: 10.1016/S0009-2614(00)01143-X
5. [5]
  Thien-Nga L, Hernadi K, Forro L. Adv. Mater., 2001, 13:148-150 doi: 10.1002/(ISSN)1521-4095
6. [6]
  Kleitz F, Choi S H, Ryoo R. Chem. Commun., 2003, 9:2136-2137
7. [7]
  Chen K, Wu C, Hwang J S, et al. J. Phys. Chem. Solids, 2001, 62:1561-1565 doi: 10.1016/S0022-3697(01)00095-6
8. [8]
  Lou Z, He M, Zhao D, et al. J. Alloys Compd., 2010, 507:38-41 doi: 10.1016/j.jallcom.2010.07.097
9. [9]
  Zou G, Lu J, Wang D, et al. Inorg. Chem., 2004, 43:5432-5435 doi: 10.1021/ic049812c
10. [10]
  Tang W, Li J, Wu X, et al. Catal. Today, 2015, 258:148-155 doi: 10.1016/j.cattod.2015.04.023
11. [11]
  Barrera D, Dávila M, Cornette V, et al. Microporous Meso-porous Mater., 2013, 180:71-78 doi: 10.1016/j.micromeso.2013.06.028
12. [12]
  Yah W O, Xu H, Soejima H, et al. J. Am. Chem. Soc., 2012, 134:12134-12137 doi: 10.1021/ja303340f
13. [13]
  Lvov Y M, Shchukin D G, Möhwald H, et al. ACS Nano, 2008, 2:814-820 doi: 10.1021/nn800259q
14. [14]
  Abdullayev E, Price R, Shchukin D, et al. ACS Appl. Mater. Interface, 2009, 1:1437-1443 doi: 10.1021/am9002028
15. [15]
  Zhai R, Zhang B, Liu L, et al. Catal. Commun., 2010, 12:259-263 doi: 10.1016/j.catcom.2010.09.030
16. [16]
  Yuan P, Southon P, Liu Z, et al. J. Phys. Chem. C, 2008, 112:15742-15751
17. [17]
  Abdullayev E, Lvov Y. J. Mater. Chem., 2010, 20:6681-6687 doi: 10.1039/c0jm00810a
18. [18]
  Zhai H, Sun D, Wang H. J. Nanosci. Nanotechnol., 2006, 6:1968-1792 doi: 10.1166/jnn.2006.320
19. [19]
  Lin C, Danaie M, Liu Y, et al. J. Nanosci. Nanotechnol., 2009, 9:4985-4987 doi: 10.1166/jnn.2009.1213
20. [20]
  Mu B, Wang W, Zhang J, et al. RSC Adv., 2014, 4:39439-39445 doi: 10.1039/C4RA05892E
21. [21]
  Abdullayev E, Sakakibara K, Okamoto K, et al. ACS Appl. Mater. Interface, 2011, 3:4040-4046 doi: 10.1021/am200896d
22. [22]
  Du Y, Zheng P. Korean J. Chem. Eng., 2014, 31:2051-2056 doi: 10.1007/s11814-014-0162-8
23. [23]
  Lee I W, Li J, Chen X, et al. J. Appl. Polym. Sci., 2015, 133:42900-42911
24. [24]
  Zheng R, Mo Z, Liao S, et al. Carbon, 2014, 69:132-141 doi: 10.1016/j.carbon.2013.11.075
25. [25]
  Wang L, Chen J, Ge L, et al. Energy Fuels, 2011, 25:3408-3416 doi: 10.1021/ef200719v
26. [26]
  Swapna V P, Selvin T P, Suresh K I, et al. Int. J. Plast. Technol., 2015, 19:124-136 doi: 10.1007/s12588-015-9106-3
27. [27]
  Yu H. J. Mater. Chem. A, 2013, 1:12198-12205 doi: 10.1039/c3ta12722b
28. [28]
  Sha J, Li G, Chen X, et al. Polym. Compos., 2016, 37:870-880 doi: 10.1002/pc.v37.3
29. [29]
  Wei Y, Ling X, Zou L, et al. Colloids Surf. A, 2015, 482:507-513 doi: 10.1016/j.colsurfa.2015.07.005
30. [30]
  Zhang Z, Pfefferle L, Lhaller G. Chin. J. Catal., 2014, 35(6):856-863 doi: 10.1016/S1872-2067(14)60123-6
31. [31]
  Kucukayan G, Ovali R, Ilday S, et al. Carbon, 2011, 49:508-517 doi: 10.1016/j.carbon.2010.09.050
32. [32]
  Xu X, Lu Z, Hima H I, et al. Appl. Clay Sci., 2009, 42:405-409 doi: 10.1016/j.clay.2008.04.004
33. [33]
  Jiang J, Chen Z, Duanmu C, et al. Mater. Lett., 2014, 132:425-427 doi: 10.1016/j.matlet.2014.06.135
34. [34]
  Wang A, Kang F, Huang Z. Microporous Mesoporous Mater., 2008, 108:318-324 doi: 10.1016/j.micromeso.2007.04.021
1. [1]
  Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796
2. [2]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
3. [3]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
4. [4]
  Zhanheng Yan , Weiqing Su , Weiwei Xu , Qianhui Mao , Lisha Xue , Huanxin Li , Wuhua Liu , Xiu Li , Qiuhui Zhang . Carbon-based quantum dots/nanodots materials for potassium ion storage. Chinese Chemical Letters, 2025, 36(4): 110217-. doi: 10.1016/j.cclet.2024.110217
5. [5]
  Min Huang , Ru Cheng , Shuai Wen , Liangtong Li , Jie Gao , Xiaohui Zhao , Chunmei Li , Hongyan Zou , Jian Wang . Ultrasensitive detection of microRNA-21 in human serum based on the confinement effect enhanced chemical etching of gold nanorods. Chinese Chemical Letters, 2024, 35(9): 109379-. doi: 10.1016/j.cclet.2023.109379
6. [6]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
7. [7]
  Jundi Qin , Dezhong Hu , Dong Xiang , Xiongwu Kang . CuMoRuFeW high entropy alloy surfaced nanorods: Superior electrochemical CO2 reduction to ethylene. Chinese Journal of Structural Chemistry, 2025, 44(5): 100571-100571. doi: 10.1016/j.cjsc.2025.100571
8. [8]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
9. [9]
  Yunqing Zhu , Kaiyue Wen , Xuequan Wan , Gaigai Dong , Junfeng Niu . High efficiency conversion of low concentration nitrate boosted with amorphous Cu⁰ nanorods prepared via in-situ reconstruction. Chinese Chemical Letters, 2025, 36(6): 110399-. doi: 10.1016/j.cclet.2024.110399
10. [10]
  Xinyun Liu , Long Yuan , Xiaoli Peng , Shilan Li , Shengdong Jing , Shengjun Lu , Hua Lei , Yufei Zhang , Haosen Fan . MOF derived phosphorus doped cerium dioxide nanorods modified separator as efficient polysulfide barrier for advanced lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(10): 110369-. doi: 10.1016/j.cclet.2024.110369
11. [11]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
12. [12]
  Xin Dai , Tong Liu , Ye Du , Jie-Yu Cao , Zhong-Juan Wang , Jie Li , Peng Zhou , Heng Zhang , Bo Lai . Synergistic effect in enhancing treatment of micro-pollutants by ferrate and carbon materials: A review. Chinese Chemical Letters, 2025, 36(8): 110548-. doi: 10.1016/j.cclet.2024.110548
13. [13]
  Yusheng Lu , Chaofeng Huang , Zhigang Lei , Mingyuan Zhu . Catalytic effects of structural design in N-modified carbon materials for the hydrochlorination of acetylene. Chinese Chemical Letters, 2025, 36(8): 110583-. doi: 10.1016/j.cclet.2024.110583
14. [14]
  Siling Chen , Yang Hu , Sijia Zhang , Xuesong Liu , Zhuqun Shi , Chuanxi Xiong , Weiwei Wu , Ruizhi Ning , Quanling Yang . Enhancing the electroactivity of supercapacitors through nitrogen doping on cellulose-derived carbon materials. Chinese Chemical Letters, 2026, 37(2): 111301-. doi: 10.1016/j.cclet.2025.111301
15. [15]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
16. [16]
  Bo-Ran Chang , Lin Deng , Qing-Lian Wu , Wan-Qian Guo , Hui-Ying Xue . A review: Carbon-based materials as effective additives in anaerobic fermentation, focusing on microbial chain elongation and medium chain fatty acids production. Chinese Chemical Letters, 2025, 36(7): 110411-. doi: 10.1016/j.cclet.2024.110411
17. [17]
  Xinyu Wu , Jianfeng Lu , Zihao Zhu , Suijun Liu , Herui Wen . Recent advances of metal-organic frameworks and MOF-derived materials based on p-block metal for the electrochemical reduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(7): 110151-. doi: 10.1016/j.cclet.2024.110151
18. [18]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
19. [19]
  Fengshun Wang , Huachao Ji , Zefei Wu , Kang Chen , Wenqi Gao , Chen Wang , Longlu Wang , Jianmei Chen , Dafeng Yan . The advanced development of one-dimensional transition metal dichalcogenide nanotubes: From preparation to application. Chinese Chemical Letters, 2025, 36(5): 109898-. doi: 10.1016/j.cclet.2024.109898
20. [20]
  Jing Guo , Chunhui Luo , Peng Li , Mao Ye , Zhihua Qiao , Yubo Wu , Huiqin Hu , Xubiao Luo , Liming Yang , Yulin Cai , Pengwei Li , Kai Zhu , Cheng Fu , Bing Yu , Yueying Chen , Shichang Wang , Ting Wang , Chongchong Qi , Zirou Liu , Dongmei Huang , Zengxi Wei , Fangxin Mao , Yi Wei , Caining Wen , Chao Han , Bo Weng , Han Feng , Junming Hong , Jing Wu , Yu Xiao , Guang Liu , Linlin Song , Rongzheng Ren , Zhenhua Wang , Long Kong , Huaifang Shang , Lihua Wang , Yongzhi Chen , Changjie Ou , Huijun Yang , Xiaoyu Liu , Jin Yi , Siwu Li , Chuang Yu , Yanhui Cao , Zhong Wu , Yida Deng , Wenbin Hu , Jianjian Zhong , Xiong Zhang , Yanwei Ma , Jianmin Ma . Roadmap on sustainable materials and technologies. Chinese Chemical Letters, 2026, 37(2): 112116-. doi: 10.1016/j.cclet.2025.112116

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1177)
HTML views(116)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142