Citation: DI Bao-Sheng, LUO Yan-Sheng, ZENG Xue-Hua, HE Li-Hua, CHEN Jing-Lin, LIAO Jin-Sheng, LIU Sui-Jun, WEN He-Rui. Effect of the Methylation on Mononuclear Gd(Ⅲ) Bipyridyl Tetrazolate Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 323-328. doi: 10.11862/CJIC.2017.031 shu

Effect of the Methylation on Mononuclear Gd(Ⅲ) Bipyridyl Tetrazolate Complexes

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: CHEN Jing-Lin, gzchenjinglin@126.com
Received Date: 8 August 2016
Revised Date: 7 December 2016

Figures(3)

Two new mononuclear Gd (Ⅲ)complexes, [Gd (tbpy)₂ (DMF) (H₂O)₂]NO₃·2H₂O (1)and[Gd (tmbpy)₂ (DMF) (NO₃)]·DMF·THF (2), have been synthesized by using 6-(1H-tetrazole-5-yl)-2, 2'-bipyridyle (tbpyH)and 6-(1H-tetrazole-5-yl)-4, 4'-dimethyl-2, 2'-bipyridyle (tmbpyH). As revealed by single-crystal X-ray diffraction, each Gd (Ⅲ)ion has a distorted tricapped trigonal prism with two mono-anionic tridentate chelating ligands, originating from N-H deprotonation of the tetrazolyl ring, and the introduction of two methyl groups into the 2, 2'-bypridyl ring has a significant effect on the coordination environment of the Gd (Ⅲ)core, showing that two mono-coordinated H₂O molecules are displaced by one chelating nitrate. CCDC:1496645, 1; 1496646, 2.
- Gd(Ⅲ) complex,
- bipyridyl tetrazole,
- methylation,
- crystal structure
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