Citation: YANG Rong, LIU Xu-Wang, PENG Lu-Ming. Synthesis and Electrochemical Properties of Manganese Oxides/Carbon-Nitrogen Three-Dimensional Networks Composite as an Anode Material for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 210-218. doi: 10.11862/CJIC.2017.025 shu

Synthesis and Electrochemical Properties of Manganese Oxides/Carbon-Nitrogen Three-Dimensional Networks Composite as an Anode Material for Lithium Ion Batteries

1.
China Academy of Engineering Physics, Institute of Chemical Materials, Mianyang, Sichuan 621000, China
2.
Department of Chemistry, Nanjing University, Key Laboratory of Mesoscopic Chemistry of MOE, Nanjing 210093, China

Corresponding author: YANG Rong, yangrong@caep.cn PENG Lu-Ming, luming@nju.edu.cn
Received Date: 17 August 2016
Revised Date: 21 October 2016

Figures(9)

Sesquioxide coated on melamine foams (MF)were prepared by hydrothermal method using manganese nitrate and ethanol. After calcinating the resulting material at different temperatures in N₂ atmosphere, manganese oxides loaded on C-N three-dimensional networks were obtained. Due to the presence of C-N networks, the structure stability and conductivity of the materials have been increased. The pores and channels generated during the calcination processes facilitate the lithium ions transportation. The composites present excellent charge/discharge ability and cycling stability as anode materials for lithium ion batteries. Therefore, the specific capacity and cycling stability have been greatly enhanced. MnO/CNnws-500 can maintain a specific capacity of 590 mAh·g^-1 after 160 cycles which accounts for 78% of theoretical capacity (755 mAh·g^-1)of manganese monoxide (MnO).
- manganese oxide,
- melamine foams,
- C-N three-dimensional networks,
- lithium ion batteries,
- anode materials
1. [1]
  Poizot P, Laruelle S, Grugeon S, et al. Nature, 2000, 407:496-499 doi: 10.1038/35035045
2. [2]
  Wang B, Chen J S, Wu H B, et al. J. Am. Chem. Soc., 2011, 133:17146-17148 doi: 10.1021/ja208346s
3. [3]
  Cheng F, Liang J, Tao Z, et al. Adv. Mater., 2011, 23:1695-1715 doi: 10.1002/adma.201003587
4. [4]
  Gao J, Lowe M A, Abruna H D, et al. Chem. Mater., 2011, 23:3223-3227 doi: 10.1021/cm201039w
5. [5]
  Jiang H, Hu Y J, Guo S J, et al. ACS Nano, 2014, 8:6038-6046 doi: 10.1021/nn501310n
6. [6]
  Guo S M, Lu G X, Qiu S, et al. Nano Energy, 2014, 9:41-49 doi: 10.1016/j.nanoen.2014.06.025
7. [7]
  Reddy M V, Rao G V S, Chowdari B V R. Chem. Rev., 2013, 113:5364-5457 doi: 10.1021/cr3001884
8. [8]
  Jiao F, Bruce P G. Adv. Mater., 2007, 19:657-660 doi: 10.1002/(ISSN)1521-4095
9. [9]
  Xia Y, Xiao Z, Dou X, et al. ACS Nano, 2013, 7:7083-7092 doi: 10.1021/nn4023894
10. [10]
  LIU Mei-Pin, HU Yu-Xiang, DU Hong-Bin. Chinese J. Inorg. Chem., 2015, 31(12):2425-2431
11. [11]
  LIU Xiao-Feng, MI Chang-Huan, ZHANG Wen-Qing. Chinese J. Inorg. Chem., 2014, 30(2):242-250
12. [12]
  Luo W, Hu X L, Sun Y M, et al. ACS Appl. Mater. Interfaces, 2013, 6:1997-2003
13. [13]
  JI Wen-Xu, WU Di, YANG Rong, et al. Chinese J. Inorg. Chem., 2015, 31(4):659-665
14. [14]
  Ji W X, Shen R, Yang R, et al. J. Mater. Chem. A, 2014, 2:699-704 doi: 10.1039/C3TA13708B
15. [15]
  Lu G X, Qiu S, Lv H L, et al. Electrochim. Acta, 2014, 146:249-256 doi: 10.1016/j.electacta.2014.08.142
16. [16]
  Liu Y P, Huang K, Luo H, et al. RSC Adv., 2014, 4:17653-17659 doi: 10.1039/c4ra01080a
17. [17]
  Li Y M, Wang Z G, Lü X J. J. Mater. Chem. A, 2014, 2:15473-15479 doi: 10.1039/C4TA02890B
18. [18]
  CHEN Xu, HE Da-Ping, MU Shi-Chun. Prog. Chem., 2013, 25(8):1292-1301
19. [19]
  Liu M M, He S J, Chen W. Nanoscale, 2014, 6:11769-11776 doi: 10.1039/C4NR03043E
20. [20]
  Choi S, Jung D S, Choi J W. Nano Lett., 2014, 14:7120-7125 doi: 10.1021/nl503620z
21. [21]
  Strohmeier B R, Hercules D M. J. Phys. Chem., 1984, 88:4922-4929 doi: 10.1021/j150665a026
22. [22]
  Aoki A. Jpn. J. Appl. Phys., 1976, 15:305-311 doi: 10.1143/JJAP.15.305
23. [23]
  Sun B, Chen Z X, Kim H S, et al. J. Power Sources, 2011, 196:3346-3349 doi: 10.1016/j.jpowsour.2010.11.090
24. [24]
  Zhang X, Xing Z, Wang L L, et al. J. Mater. Chem., 2012, 22:17864-17869 doi: 10.1039/c2jm32421k
25. [25]
  Liu H, Li Z H, Liang Y R, et al. Carbon, 2015, 84:419-425 doi: 10.1016/j.carbon.2014.12.032
26. [26]
  Qiu S, Wang X Z, Lu G X, et al. Mater. Lett., 2014, 136:289-291 doi: 10.1016/j.matlet.2014.08.016
27. [27]
  Lu G X, Qiu S, Lü H L, et al. Electrochim. Acta, 2014, 146:249-256 doi: 10.1016/j.electacta.2014.08.142
28. [28]
  Wu D, Yang R, Sun Q X, et al. Electrochim. Acta, 2016, 211:832-841 doi: 10.1016/j.electacta.2016.06.107
1. [1]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100021-0. doi: 10.3866/PKU.WHXB202311005
2. [2]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
3. [3]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
4. [4]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
5. [5]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
8. [8]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
9. [9]
  Mengxiu Li , Jiahui Mao , Jiangfeng Ni , Liang Li . Three birds with one stone: modification of Li₅FeO₄ with thermal induction of Lewis acid. Acta Physico-Chimica Sinica, 2026, 42(4): 100189-0. doi: 10.1016/j.actphy.2025.100189
10. [10]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
11. [11]
  Wen Tang , Luyu Sui , Qian Chen , Jun Shao , Xinwen Peng , Jianwen Jiang , Shuiliang Chen . Project-based Teaching of “the Condensed State of Polymers”: Unveiling the Lithium-Ion Battery Separator. University Chemistry, 2025, 40(11): 115-126. doi: 10.12461/PKU.DXHX202412108
12. [12]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
13. [13]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
14. [14]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-0. doi: 10.3866/PKU.WHXB202408007
15. [15]
  Rongrong Wang , Chen Li , Xiang Ren , Keliang Zhang , Yu Sun , Xianzhong Sun , Kai Wang , Xiong Zhang , Yanwei Ma . Recent advances and challenges of eco-friendly Ni-rich cathode slurry systems in lithium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(4): 100222-0. doi: 10.1016/j.actphy.2025.100222
16. [16]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
17. [17]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
18. [18]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
19. [19]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
20. [20]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1615)
HTML views(149)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142