Citation: HU Peng, GAO Yuan-Yuan, XIAO Feng-Yi, DENG Xiao-Juan, HUANG Guo-Hong, ZHANG Miao, SU Feng, WANG Li-Na. Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 33-40. doi: 10.11862/CJIC.2017.019 shu

Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties

1.
College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
2.
College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China
3.
Obstetrics and Gynecology Hospital of Fudan University, Shanghai 200011, China

Corresponding author: GAO Yuan-Yuan, gaoyuanyuan@imut.edu.cn;michellexiao2014@163.com
Received Date: 13 August 2016
Revised Date: 9 November 2016

Figures(6)

Three lanthanide-nitronyl nitroxide radical compounds[Ln (hfac) ₃ (NIT-Ph-4-Br) ₂] (Ln=Gd (1) , Tb (2) , Dy (3) , hfac=hexafluoroacetylacetonate, NIT-Ph-4-Br=2- (4'-bromide) -4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) have been successfully prepared and characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analyses. Single crystal X-ray crystallographic analyses reveal that all these three compounds are isostructural and crystallize in the P2₁/c space group, which are composed of one Ln (hfac) ₃ unit and two NIT-Ph-4-Br radicals. Magnetic studies reveal that ferromagnetic interactions and antiferromagnetic interactions coexist in Gd complex and there are very weak ferromagnetic interactions between Ln (III) ions and the coordinated nitronyl nitroxide in Tb complex and Dy complex. CCDC:1496095, 1; 1496096, 2; 1496097, 3.
- nitronyl nitroxide radical,
- lanthanides,
- crystal structure,
- magnetic properties
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