Citation: XIAO Bo-An, CHEN Shui-Sheng. Syntheses, Structures and Photoluminescence Properties of Two Zn(Ⅱ) Complexes Constructed from Mixed Carboxylate and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 347-353. doi: 10.11862/CJIC.2017.014 shu

Syntheses, Structures and Photoluminescence Properties of Two Zn(Ⅱ) Complexes Constructed from Mixed Carboxylate and N-Donor Ligands

XIAO Bo-An ¹ ,
CHEN Shui-Sheng ^2,,

1.
Zhengzhou Preschool Education College, Zhengzhou 450099, China
2.
College of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang, Anhui 236041, China

Corresponding author: CHEN Shui-Sheng, chenss@fync.edu.cn
Received Date: 5 September 2016
Revised Date: 6 November 2016

Figures(11)

Two Zn (Ⅱ)coordination polymers[Zn₂ (L)₂ (pbda)]_n (1)and[Zn₂ (L)₂ (mbda)]_n (2)were synthesized by reactions of ZnSO₄·7H₂O with rigid ligand 1-(1H-imidazol-4-yl)-4-(4H-tetrazol-5-yl)benzene (HL)and different carboxylic acids of 1, 4-benzenedicarboxylic acid (H₂pbda)or 1, 3-benzenedicarboxylic acid (H₂mbda). The complexes have characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy, photolu-minescence spectrum, TG and PXRD. Polymer 1 possesses[Zn₂ (L)₂]²⁺ sheets pillared by the pbda^2- ligand to form a 2-fold interpenetrating three-dimensional (3D)dmc net with point Schläfli symbol of (4·8²) (4·8⁵), while 2 exhibits a uninodal 6-connected 3D architecture with (4¹²·6³)-pcu topology based on the binuclear Zn (Ⅱ)secondary building units (SBUs). Solid state luminescent properties of 1 and 2 have been investigated. CCDC:1502275, 1; 1502276, 2.
- coordination polymer,
- synthesis,
- structure,
- photoluminescence property
1. [1]
  Cook T R, Zheng Y R, Stang P J, et al. Chem. Rev., 2013, 113:734-777 doi: 10.1021/cr3002824
2. [2]
  Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011, 47:4902-4904 doi: 10.1039/c1cc10899a
3. [3]
  Li X J, Jiang F L, Wu M Y, et al. Inorg. Chem., 2012, 51:4116-4122 doi: 10.1021/ic202373a
4. [4]
  Chen S S, Liu Q, Zhao Y, et al. Cryst. Growth Des., 2014, 14:3727-3741 doi: 10.1021/cg401811c
5. [5]
  Karmakar A, Martins L M D R S, Hazra S, et al. Cryst. Growth Des., 2016, 16:1837-1849 doi: 10.1021/acs.cgd.5b01178
6. [6]
  Chen S S, Wang P, Takamizawa S, et al. Dalton Trans., 2014, 43:6012-6020 doi: 10.1039/c3dt53388c
7. [7]
  Chen S S, Qiao R, Sheng L Q, et al. Z. Anorg. Allg. Chem., 2013, 639:1808-1814 doi: 10.1002/zaac.v639.10
8. [8]
  Xiao L, Li W D, Fang X, et al. Chin. J. Struct. Chem., 2016, 35:781-788
9. [9]
  Guo X Q, Wang M, Meng, F, et al. CrystEngComm, 2016, 18:5616-5619 doi: 10.1039/C6CE01164K
10. [10]
  Liu S J, Cao C, Xie C C, et al. Dalton Trans., 2016, 45:9209-9215 doi: 10.1039/C6DT01349J
11. [11]
  Maity D K, Halder A, Bhattacharya B, et al. Cryst. Growth Des., 2016, 16:1162-1167 doi: 10.1021/acs.cgd.5b01686
12. [12]
  Hu Z Y, Zhu J J, Chen S S, et al. Chin. J. Struct. Chem., 2015, 34:899-905
13. [13]
  Chen S S. CrystEngComm, 2016, 18:6543-6565 doi: 10.1039/C6CE01258B
14. [14]
  Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011, 47:752-754 doi: 10.1039/C0CC04085A
15. [15]
  Chen S S, Sheng L Q, Liu Z D, et al. Cryst. Growth Des., 2016, 16:229-241 doi: 10.1021/acs.cgd.5b01133
16. [16]
  Chen S S, Chen Z H, Fan J, et al. Cryst. Growth Des., 2012, 12:2315-2326 doi: 10.1021/cg2016275
17. [17]
  Chen S S, Zhao Y, Fan J, et al. CrystEngComm, 2012, 14:3564-3576 doi: 10.1039/c2ce06632g
18. [18]
  Qiao R, Chen S S, Sheng L Q, et al. J. Solid State Chem., 2015, 228:199-207 doi: 10.1016/j.jssc.2015.04.041
19. [19]
  Chen S S, Qiao R, Sheng L Q, et al. CrystEngComm, 2013, 15:5713-5725 doi: 10.1039/c3ce40150b
20. [20]
  Bruker 2000, SMART Ver. 5. 0, SAINT-plus Ver. 6, SHELXTL Ver. 6. 1 and SADABS Ver. 2. 03, Bruker AXS Inc., Madison, WI, 2000.
21. [21]
  Xie L X, Hou X W, Fan Y T, et al Cryst. Growth Des., 2012, 12:1282-1291 doi: 10.1021/cg201287t
22. [22]
  Blatov V A. TOPOS, A Multipurpose Crystallochemical Analysis with the Program Package, Samara State University, Russia, 2009.
23. [23]
  Blatov V A, Carlucci L, Ciani G, et al. CrystEngComm, 2004, 6:378-395
24. [24]
  Yang Q, Zhang X F, Zhao J P, et al. Cryst. Growth Des., 2011, 11:2839-2845 doi: 10.1021/cg1016615
25. [25]
  Kreno L E, Leong K, Farha O K, et al. Chem, Rev., 2012, 112:1105-1125 doi: 10.1021/cr200324t
26. [26]
  Meng F, Zhang M, Shen K, et al. Dalton Trans., 2015, 44:1412-1419 doi: 10.1039/C4DT02811B
27. [27]
  Hua J A, Zhao Y, Liu Q, et al. CrystEngComm, 2014, 16:7536-7546 doi: 10.1039/C4CE00835A
28. [28]
  Li Y W, Ma H, Chen Y Q, et al. Cryst. Growth Des., 2012, 12:189-196 doi: 10.1021/cg200926z
29. [29]
  Wan X Y, Jiang F L, Chen L, et al. CrystEngComm, 2015, 17:3829-3837 doi: 10.1039/C5CE00420A
30. [30]
  Song S Y, Song X Z, Zhao S N, et al. Dalton Trans., 2012, 41:10412-10421 doi: 10.1039/c2dt30826f
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