Citation: ZHANG Yao-Jun, ZHANG Ke, KANG Le, ZHANG Li. An Eco-friendly Fly Ash-Based Geopolymer: Synthesis and Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 16-25. doi: 10.11862/CJIC.2017.011 shu

An Eco-friendly Fly Ash-Based Geopolymer: Synthesis and Photocatalytic Properties

College of Materials and Mineral Resources, Xi'an University of Architecture and Technology, Xi'an 710055, China

Corresponding author: ZHANG Yao-Jun, zhangyaojun@xauat.edu.cn
Received Date: 10 August 2016
Revised Date: 1 November 2016

Figures(11)

The fly ash-based geopolymer with regulable pore structure was firstly synthesized by using urotropine as pore forming agent. Meanwhile, a kind of In₂O₃ and NiO co-loaded fly ash-based geopolymer was firstly synthesized by the coupling design of semiconductors. The composition, structure and properties of catalysts were characterized by XRF, TG/DSC, FESEM, XRD, FT-IR and UV-Vis. Furthermore, degradation activities of simulated dyeing wastewater, mechanism and reaction dynamics were studied. The results indicated that the pore structure, BET specific surface area and mesopore volume of geopolymer were remarkably improved by adding pore forming agent. The highest degradation rate (95.65%) of magenta green crystals over the 5% In₂O₃ and 1% NiO co-loaded catalyst should ascribe to the semiconductor coupling system of p-n junction generated from In₂O₃ and NiO as well as strong interaction produced between In₂O₃ and PAFAG so that the separation efficiencies of photogenerated electron-hole pairs were improved and the photocatalytic degradation activities of dye were enhanced.
- aluminosilicates,
- semiconductors,
- photocatalysis,
- fly ash-based geopolymer,
- dye degradation
1. [1]
  China's National Development and Reform Commission.. Annual Report of China Resources Comprehensive Utilization, 2014:1-39
2. [2]
  Zhiyan Consulting Group.. China's Solid Waste Treatment Equipment Market Research and Investment Strategy Research Report of 2015-2020, 2015:1-221
3. [3]
  FU Peng-Yan.. Ready-mixed Concr., 2016,6:31
4. [4]
  CAO Jun, FANG Ying, FAN Ren-Dong, et al.. Inorg. Chem. Ind., 2015,47(8):10-13
5. [5]
  SUN Shu-Jing, LIU Xue-Min.. Fly Ash Compr. Util., 2015,3:45-48
6. [6]
  Singh B, Ishwarya G, Gupta M, et al.. Constr. Build. Mater., 2015,85:78-90 doi: 10.1016/j.conbuildmat.2015.03.036
7. [7]
  Inada M, Tsujimoto H, Eguchi Y, et al.. Fuel, 2005,84(12/ 13):1482-1486
8. [8]
  Davidovits J.. J. Therm. Anal., 1991,37:1633-1656 doi: 10.1007/BF01912193
9. [9]
  Gunasekara C, Law D W, Setunge S, et al.. Constr. Build. Mater., 2015,95:592-599 doi: 10.1016/j.conbuildmat.2015.07.175
10. [10]
  Ryu G S, Lee Y B, Koh K T, et al.. Constr. Build. Mater., 2013,47:409-418 doi: 10.1016/j.conbuildmat.2013.05.069
11. [11]
  Bakharev T.. Cem. Concr. Res., 2005,35:1224-1232 doi: 10.1016/j.cemconres.2004.06.031
12. [12]
  Law D W, Adam A A, Molyneaux T K, et al.. Mater. Struct., 2015,48:721-731 doi: 10.1617/s11527-014-0268-9
13. [13]
  Chindaprasirt P, Rattanasak U, Taebuanhuad S.. Mater. Struct., 2013,46:375-381 doi: 10.1617/s11527-012-9907-1
14. [14]
  Temuujin J, Minjigmaa A, Lee M, et al.. Cem. Concr. Compos., 2011,33:1086-1091 doi: 10.1016/j.cemconcomp.2011.08.008
15. [15]
  Chindaprasirt P, Chalee W.. Constr. Build. Mater., 2014,63: 303-310 doi: 10.1016/j.conbuildmat.2014.04.010
16. [16]
  Komnitsas K, Zaharaki D.. Miner. Eng., 2007,20(14):1261-1277 doi: 10.1016/j.mineng.2007.07.011
17. [17]
  Al-Zboon K, Al-Harahsheh M S, Hani F B.. J. Hazard. Mater., 2011,188:414-421 doi: 10.1016/j.jhazmat.2011.01.133
18. [18]
  Zhang Y J, Liu L C.. Particulogy, 2013,11:353-358 doi: 10.1016/j.partic.2012.10.007
19. [19]
  Dong C, Li Q, Chen G, et al.. Sens. Actuators B:Chem., 2015, 220:171-179 doi: 10.1016/j.snb.2015.05.056
20. [20]
  Zhang Y J, Kang L, Liu L C, et al.. Appl. Surf. Sci., 2015, 331:399-406 doi: 10.1016/j.apsusc.2015.01.090
21. [21]
  Duxson P, Fernandez-Jimenez A, Provis J L, et al.. J. Mater. Sci., 2007,42:2917-2933 doi: 10.1007/s10853-006-0637-z
22. [22]
  Barbosa V F F, MacKenzie K J D, Thaumaturgo C.. Int. J. Inorg. Mater., 2000,2:309-317 doi: 10.1016/S1466-6049(00)00041-6
23. [23]
  Salahuddin M B M, Norkhairunnisa M, Mustapha F.. Ceram. Int., 2015,41:4273-4281 doi: 10.1016/j.ceramint.2014.11.119
24. [24]
  Zhang Y J, Zhao Y L, Li H H, et al.. J. Mater. Sci., 2008,43: 7141-7147 doi: 10.1007/s10853-008-3028-9
25. [25]
  Palomo A, Grutzeck M W, Blanco M T.. Cem. Concr. Res., 1999,29:1323-1329 doi: 10.1016/S0008-8846(98)00243-9
26. [26]
  Timakul P, Rattanaprasit W, Aungkavattana P.. Ceram. Int., 2016,42:6288-6295 doi: 10.1016/j.ceramint.2016.01.014
27. [27]
  Komnitsas K A.. Procedia Eng., 2011,21:1023-1032 doi: 10.1016/j.proeng.2011.11.2108
28. [28]
  Lagergren S.. Kungliga Svenska Vetenskapsakademiens Han-dlingar, 1898,24(4):1-39
29. [29]
  Ho Y S, McKay G.. Process Biochem., 1999,34:451-465 doi: 10.1016/S0032-9592(98)00112-5
30. [30]
  Crank G.. The Mathematics of Diffusion. London, New York: Clarendon Press, 1933..
31. [31]
  FENG Li-Li, ZHAO Wei, LIU Yang, et al.. Acta Phys.-Chim. Sin., 2009,25(7): 1347-1351
32. [32]
  Yang L, Wang F Z, Hakki A, et al.. Appl. Surf. Sci., 2016, 392:687-696
33. [33]
  Yang Z M, Hou S C, Huang G F, et al.. Mater. Lett., 2014, 133:109-122 doi: 10.1016/j.matlet.2014.06.169
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