Citation: ZHENG Zhuo, HUA Wei-Bo, WU Zhen-Guo, XIANG Wei, ZHONG Ben-He, GUO Xiao-Dong. Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 307-314. doi: 10.11862/CJIC.2017.010 shu

Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries

1.
Polymer Research Institute, Sichuan University, Chengdu 610065, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China
3.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610065, China
4.
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong NSW 2522, Australia

Corresponding author: GUO Xiao-Dong, xiaodong2009@scu.edu.cn
Received Date: 12 August 2016
Revised Date: 15 October 2016

Figures(6)

The ultra-high rate nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ cathode is controllably prepared by the carbonate co-precipitation method through tailoring the amount of the NH₃·H₂O. The NH₃·H₂O has a great effect on morphology, particle size, crystal structure and electrochemical performance. Powder X-ray diffraction (XRD)and scanning electron microscopy (SEM)results indicate that the morphology of primary particle is changed from nano-plate to nano-sphere with the decreasing of the NH₃·H₂O, and the sample with ratio n_NH₃·H₂O: (n_Ni+n_Co+n_Mn)=1:2 has the well-ordered-NaFeO₂ structure and the lowest cation mixing (Li⁺/Ni²⁺). Electrochemical results also confirm that the sample with ratio n_NH₃·H₂O: (n_Ni+n_Co+n_Mn)=1:2 has the best cycling stability and ultra-high rate capability. Specifically, it delivers a discharge capacity of 119 mAh·g^-1 between 2.7 and 4.3 V at 1C after 300 cycles with outstanding capacity retention of 81%, and the mid-point potential retention is 97%. This sample can still deliver a high discharge capacity of 56 mAh·g^-1 even at the ultra-high rate 100C (18 mAh·g^-1), which has the prospect to be applied in high power lithium ion battery. This nNH₃·H₂O ratio could provide some valuable reference for synthesizing other high-rate and high-capacity anode/cathode oxides.
- lithium-ion battery,
- cathode material,
- carbonate co-precipitation method,
- ultra-high rate performance
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沈阳化工大学材料科学与工程学院沈阳 110142

Controllable Preparation of Ultra-High Rate LiNi1/3Co1/3Mn1/3O2 Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries

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Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries